Chemical Quantities: Chapter 10 I. The Mole & Molar Conversions I II III IV A mole of paperclips Measure the length of a paper clip to the nearest 0.1cm. If a mole is 6.02x1023 items, how far will a mole of paper clips, placed end to end lengthwise, reach into space? How many light years (ly) would the paper clips extend into space? (1 ly = 9.46 x 1015 m). How does the distance you calculated compare with the following astronomical distances: nearest star (other than the sun) = 4.3 ly, center of our galaxy = 30,000 ly, nearest galaxy = 2 x 106 ly? A. What is the Mole? A counting number (like a dozen) Avogadro’s number (NA) 1 mol = 6.02 x 1023 items (atoms, molecules, formula units) 1 mol is the SI unit used to measure amount of a substance A large amount!!!! A. What is the Mole? 1 mole of hockey pucks would equal the mass of the moon! 1 mole of basketballs would fill a bag the size of the earth! 1 mole of pennies would cover the Earth 1/4 mile deep! B. Molar Mass Mass of 1 mole of an element or compound. Atomic mass tells the... atomic mass units per atom (amu) grams per mole (g/mol) Round to 2 decimal places B. Molar Mass Examples carbon 12.01 g/mol aluminum 26.98 g/mol zinc 65.39 g/mol B. Molar Mass Examples water H2O 2(1.01) + 16.00 = 18.02 g/mol sodium chloride NaCl 22.99 + 35.45 = 58.44 g/mol B. Molar Mass Examples sodium bicarbonate NaHCO3 22.99 + 1.01 + 12.01 + 3(16.00) = 84.01 g/mol sucrose C12H22O11 12(12.01) + 22(1.01) + 11(16.00) = 342.34 g/mol C. Molar Conversions molar mass 6.02 x 1023 MASS NUMBER MOLES IN GRAMS OF PARTICLES (g/mol) (particles/mol) C. Mole-Mass Conversions Your class bought jellybeans in bulk to sell by the dozen. It’s too much work to count out each dozen, so you decide to measure the jellybeans by mass. You find that 1 dozen jellybeans equals 35g. What mass of jellybeans should you measure if a customer wants 5 dozen jellybeans? Jellybean Problem C. Molar Conversion Examples How many moles of carbon are in 26 g of carbon? 26 g C 1 mol C 12.01 g C = 2.2 mol C C. Molar Conversion Examples You need 3.00 mol of manganese for a chemical reaction, how can you measure that amount? C. Mole-Particles Conversions You buy 3.5 dozen roses for your mom, how many roses did you buy? C. Molar Conversion Examples How many molecules are in 2.50 moles of C12H22O11? 6.02 x 1023 2.50 mol molecules 1 mol = 1.51 x 1024 molecules C12H22O11 C. Molar Conversion Examples Determine the number of atoms in 2.50 mol of Zn. C. Molar Conversion Examples Calculate the number of moles that contain 3.58x1023 formula units of ZnCl2? C. Mass-Moles- Particles Conversions If 550 grams of jellybeans are unsold from your class fundraiser, without counting can you determine how many jellybeans this is? (remember you determined that 1 dozen jellybeans = 35 g) Jellybean Problem 2 C. Molar Conversion Examples the mass of 2.1 1024 molecules of NaHCO3. Find 2.1 x 1024 molecules 1 mol 84.01 g 6.02 x 1023 1 mol molecules = 290 g NaHCO3 C. Molar Conversion Examples How many atoms are in 0.230 g of Pb? What is the mass in grams 1.50x1015 atoms N? Practice Problems How many marbles are in 0.200 mol of marbles? Practice Problems How many moles of magnesium is 1.25 x 1023 atoms of magnesium? Practice Problems How many atoms are in 2.12 mol of propane (C3H8)? Practice Problems How many moles are there in 4.65 x1024 molecules of NO2? D. Mole-Volume Conversions 1 mol of gas = 22.4 L at STP STP = standard temperature (0oC) & pressure (1 atm) D. Molar Conversion Examples Determine the volume, in liters, of 0.60 mol SO2 gas at STP. 0.6 mol SO2 22.4L SO2 = 13L SO2 1 mol SO2 D. Molar Conversion Examples Assuming STP, how many moles are in 0.880 L He? 3.93 x 10-2 mol He What is the volume at STP of 3.70 mol N2? 82.9 L N2 D. Molar Conversions The density of a gaseous compound containing carbon and oxygen is 1.964 g/L at STP. Determine the molar mass of the compound. 44.0 g/mol What is the density of krypton gas at STP? 3.74 g/L