Chm II Drill: Calculate the mass of (NH4)2SO4 in mg produced when 1.12 mL NH3 gas reacts is excess H2SO4 in the following rxn: NH3 + H2SO4 (NH4)2SO4 Review Drill & Stoichiometry Test Water of Crystalization Lab Due Tomorrow Chm II Homework •Review PP-11 •Complete the worksheet attached to the Poly website. Are there any questions on previous material? Kinetic Theory •All matter is made up of tiny particles •The particles are in constant motion •All collisions are elastic Pressure •Force per unit area •Caused by collisions against a surface •Gas measured in pressure Units of Pressure •kPa: kilopascal (Std Unit) •Pascal: newton/sq. meter •Atmosphere (Atm): •mm Hg: Standard Pressure •101.3 kPa (to be changed) •1.00 Atm •760 mm Hg or Torrs •30.0 inches Hg •1013 millibars Gas Laws State the Following Laws • Boyle’s Law • Charles’ Law • Gay Lussac’s Law • Dalton’s Law • Graham’s Law Boyle’s Law •The pressure & volume of a gas at constant temperature are inversely proportioned P1V1 = P2V2 = K Charles’ Law • The volume and temperature of a gas at constant pressure are directly proportioned V 1 V2 = =K T1 T 2 Guy Lussac’s Law • The pressure and temp. of a gas at constant volume are directly proportioned P1 P 2 = =K T1 T 2 Combined Gas Law •Combination of the three formulas P1V1 P2V2 = T1 T2 Common Sense •A gas’s volume is directly proportioned to its number of moles V1 V2 = =K n1 n2 New Combination P1V1/n1T1 = P2V2/n2T2 = K New Combination P1V1 P2V2 = =K n1 T1 n2T2 Ideal Gas Law PV = nRT Dalton’s Law •The total pressure = the sum of the partial pressures PT = P1 + P2 + etc Graham’s Law • The velocities of particles are inversely proportioned to the square root of their masses v1 M2 = v2 M1 Calculate the new volume of 5.0 L of gas when its pressure is doubled and its temperature is tripled: Calculate the volume of a gas at STP when it occupies 150.0 mL o at 227 C under 303.9 kPa pressure: Calculate the volume of 3.0 moles of gas at o -23 C under 83.1 kPa pressure. Drill: Calculate the volume of a gas at STP when it occupies 80.0 o mL at 273 C under 303.9 kPa pressure: Drill: Calculate the number of moles of gas occupying 831 mL under 250 kPa at o 227 C & Pass in Lab Review & Collect Drill & HW CHM II HW •Review PP 11 •Complete the attached worksheet Are there any questions on previous material? Calculate the volume of a gas at STP when it occupies 80.0 mL at o 273 C under 303.9 kPa pressure: Calculate the ratio of the velocities of He gas to HCl gas: Calculate the mass of CO2 occupying 83.1 mL under 25 GPa at o 227 C Calculate the molecular mass of 5.0 g of gas occupying 831mL under 250 o MPa at 227 C Ideal Gas Law PV = nRT Related Formulas m D or r = V m/n MW = MW = m/n n = m/MW PV = nRT PV = MW = mRT MW mRT PV Drill: Calculate the volume in mL of 4.0 g bromine gas o at 127 C under 83.1 kPa pressure. Review & Collect Drill & HW CHM II HW • Review PP 11 • Complete the attached assignment & turn it in tomorrow Are there any questions on previous material? Discuss Lab Calculate the density of carbon o dioxide at 27 C under 83.1 kPa pressure Other Integrated Formulas D= MW = m V mRT PV D= MW = m V m RT V P MW D= DRT = P MW P RT The total pressure of a system is 120.0 kPa. The partial pressure of gas A is 112.0 kPa. Determine the pressure of gas B Drill: Calculate the ratio of the velocities of He gas to HCl gas: Calculate the mass of 831 mL o of CO2 at 27 C under 150 kPa pressure: Drill:Calculate the volume of 4.0 moles of gas under 83.1 kPa o pressure at 127 C: Review & Collect Drill & HW Are there any questions on previous material? Calculate the volume of a gas at STP when it occupies 80.0 mL at o 127 C under 303.9 kPa pressure: 5 Calculate the volume of 4.0 moles of gas under 83.1 kPa o pressure at 127 C: Calculate the molecular mass of 50 g of gas occupying 831mL under 250 o MPa at 227 C Calculate the mass of 831 mL o of CO2 at 167 C under 150 kPa pressure: The total pressure of a system is 120.0 kPa. The partial pressure of gas A is 112.0 kPa. Determine the pressure of gas B The total pressure of a system is 150.0 kPa. The system contains 50 % A, 30 % B, & 20 % C. Determine the pressure of each gas. Drill: Calculate the mass of CO2 occupying 83.1 mL under 25 MPa at o 477 C Calculate the density of carbon o dioxide at 27 C under 83.1 kPa pressure Calculate the velocity HBr when the velocity Be is 270 m/s: Calculate the final volume that 3.0 L of gas will obtain when the absolute temperature is tripled & the pressure is halved. Calculate the mass of CO occupying o 831 kL at 227 C under 2.50 Mpa pressure. Calculate the volume of o H2 formed at 27 C under 150 kPa when 6.8 mg NH3 decomposes making N2 & H2.