CH 115 Fall 2014 Mock Exam 1 Multiple Choice 1. Which of the following represents an invalid set of quantum numbers? a). (15, 3, 0, ½) b). (1, 1, 0, -1/2) c). (4, 3, -1, ½) d). (2, 1, -1, -1/2) 2. The energy of a photon of light is halved. What will happen to the wavelength and the frequency of this light, respectively? a). halved, halved b). quadrupled, halved c). doubled, halved d). halved, doubled 3. How many protons, neutrons, and electrons (respectively) are present in 160Au? a). 79, 81, 79 b). 81, 79, 81 c). 80, 80, 80 d). 79, 81, 81 4. Which of the following is not an expected common monatomic ion? a). O2b). N3+ c). Na1+ d). Se25. Which of the following represents the ground-state electron configuration for the neutral atom Zr? a). 1s22s22p63s23p64s24d104p65s25d2 b). 1s22s22p63s23p64s23d104p6 c). 1s22s22p63s23p64s23d104p65s24d2 d). 1s22s22p63s23p64s23d104p65s14d3 6. Select all of the atoms that have the same number of neutrons. 37Cl and 40Ca I. 42Sc and 43Ti II. 41Sc and 39K III. a). I only b). II only c). I and II only d). I and III only e). I, II, and III CH 115 Fall 2014 Mock Exam 1 7. Which of the following contains a halogen, an alkali metal, and a metalloid in that order? a). Kr, Na, B b). Br, Cs, Si c). Cl, Ba, Zn d). F, Be, Si 8. What is the formula for the ionic compound that forms between barium and chloride? a). Ba2Cl b). BaCl c). Ba2Cl2 d). BaCl2 9. Indicate the correct set of four quantum numbers for the electron of highest energy in the ground-state configuration of Na. a). (2, 1, 1, -1/2) b). (3, 1, 0, ½) c). (3, 0, 0, ½) d). (3, 1, 1, ½) 10. What is the correct name for CCl4? a). carbon tetrachloride b). carbon (IV) chloride c). monocarbon tetrachloride d). carbon chlorate 11. Which of the following elements does not have 5 valence electrons? a). As b). B c). N d). Sb 12. The atomic weight of copper is 63.55 amu. In a sample of the element, 69.17% of copper is present as Cu-63 with an atomic mass of 62.939 amu. What is the atomic mass of the other isotope and how many neutrons does it contain? a). 64.92 amu, 29 neutrons b). 64.92 amu; 36 neutrons c). 45.9 amu; 17 neutrons d). 63.55 amu; 36 neutrons 13. Select the correct noble gas electron configuration for molybdenum (Mo). a). [Kr]5s24d4 b). [Xe]5s24d4 c). [Xe]5s14d5 CH 115 Fall 2014 Mock Exam 1 d). [Kr]5s14d5 14. Order the following elements from highest to lowest ionization energy: Sr, Be, Mg, Ca, Ba. a). Ba, Sr, Ca, Mg, Be b). Be, Mg, Ca, Sr, Ba c). Be, Ca, Sr, Mg, Ba d). Be, Mg, Ca, Ba, Sr 15. Which of the following elements has the largest atomic radii? a). N b). B c). Li d). F 16. Which ion has the largest radius? a). Li+ b). Na+ c). Mg2+ d). Al3+ 17. Which of the following statements are true? I. Each set of d orbitals contains 7 orbitals. II. Each set of d orbitals can hold a maximum of 14 electrons. III. The first energy level contains only s and p orbitals. IV. The s orbital in any shell is always spherically symmetrical. a). I and II only b). I, III, and IV only c). IV only d). III only 18. In another universe, element X has 3 naturally occurring isotopes: 100X, 102X, and 105X. If the atomic weight of X is 100.73 amu, which isotope has the highest natural abundance? a). 100X b). 102X c). 105X d). It cannot be determined from the information given. 19. Consider two electron transitions. In the first case, an electron falls from n=4 to n=2, giving off a photon of light with a wavelength equal to 488 nm. In the second transition, an electron moved from n=3 to n=4. For this transition, we would expect that: a). energy is emitted, and the wavelength of the corresponding photon will be shorter than the first transition CH 115 Fall 2014 Mock Exam 1 b). energy is emitted, and the wavelength of the corresponding photon will be longer than the first transition c). energy is absorbed, and the wavelength of the corresponding photon will be shorter than the first transition d). energy is absorbed, and the wavelength of the corresponding photon will be longer than the first transition Short Answer 20. The atomic weight of boron is 10.8 amu. Assume that boron has two isotopes: 10B and 11B. Sketch a drawing of what the mass spectrum chart for boron would look like. What are the percent abundances of the two isotopes? Why is the atomic weight for boron (and most other elements) not a whole number value? 21. Complete the table below. Name Formula NO3 Ionic or Molecular? SCl4 22. Draw the Lewis structures for the following molecules and predict how many double bonds will be expected for each. a). NO3b). NF3