saturated hydrocarbons
hydrocarbons that lack π bonds are called
Alkanes
are organic compounds that consist entirely of single bonded carbon and hydrogen atoms and lack any other functional groups
International Union of Pure and Applied Chemistry
→proposed a system of nomenclature for organic molecules
Locant
where are the substituents and functional groups
Prefix
what are the substituent s
Parent
how many carbons
Suffix
what is the primary functional group
Substituents
are the groups connected to the parent chain
Cyclo
is used to indicate the presence of a ring in the structure of an alkane
Hyphen
is used to separate numbers from letters
Commas
are used to separate two numbers from each other
Alkanes
paraffin-- slight affinity-- unreactive
Halogenation reaction
reaction with halogens (radical reaction)
Straight chain alkanes
increasing number of C, increasing BP and MP
increasing strength of IMF
increases molecular size thus
Branched chain alkanes
lower BP and MP compared to straight chain alkane counterpart
yes
why is BCA have lower BP and MP
Cracking
is a process by which C-C bonds of larger alkanes are broken, producing smaller alkanes gasoline.
Petroleum
Main source of alkanes
Thermal cracking
can be achieved at high temperature
Catalytic cracking
with the aid of catalysts
Alkenes
areunsaturated compounds with at least one carbon-to-carbon double bond
Elimination reactions
alkenes are prepared via
Alkenes
abundant in nature and an important precursor in the chemical industry
-cis
same side stereoisomers
-trans
opposite side stereoisomers
Zusammen
same side desgination
Entgegen
opposite side designation
Alkenes
Olefins
Soot (alkene)
is more smoky compare with alkane
Addition reaction
addition of two groups across a double bond
Hydrohalogenation
addition of H and X
Hydration
addition of H and OH
Hydrogenation
addition of H and H
Halogenation
addition of X and X
Halohydrin formation
addition of OH and X
Dihydroxylation
addition of OH and OH
Polymerization reaction
is a process of producing larger molecules from repeating units
Alkynes
areunsaturated compounds with at least one carbon-to-carbon triple bond C≡C
Alkynes
less common in nature than alkenes
Terminal alkynes
monosubstituted alkynes
Internal alkynes
disubstituted alkynes
Alkynes
acetylene
Alkynes
soot are relatively thicker than the alkenes