PhD of Industrial Engineering Research Activity on Energy Metal Foams For Energy Applications S.K. Balijepalli, G. Barbieri, G. Costanza, S. Kaciulis, G. Lapi, R. Montanari, M.E. Tata Metal Foams Applications Metal foams can be used for filtration and separation processes. For exaple the particulate emissions generated from a side-mounted 2.4 L gasoline direct injection engime were evaluated using a metal foam-type gasoline particulate filter and the number of sub-23 nm particles formed was reduced with 97% efficiency. Kim et. al., Journal of Aerosol Science, vol. 57 p.1, 2013. They can be used in thermal energy storage device in thermal energy applications in areas such as energy afficients buildings and solar thermal power plants. In the solid/liquid phase change process the paraffin wax RT58 is used as phase change material and the addiction of metal-foam can increase the overall heat transfer rate by 3 to 10 times, depending on the metal foam structures and materials. Lu et.al., Solar Energy, vol.84 p.1402, 2010. Metal Foams Applications Thermal transport in metal foams has received growing attention in both academic research and industrial applications. High porosity, open-celled metal foams have emerged as one of the most promising materials for thermal management applications where a large amount of heat needs to be transported over a small volume. The motivation is attributed to the high surface area to volume ratio as well as enhanced flow mixing due to the tortuosity of metal foams. Metal Foams Applications A new technology for continuous and high-efficiency alkali-catalyzed biodiesel synthesis using a metal foam reactor combined with a passive mixer has been developed. Metal foam reactors are developed to improve conversion efficiency and biodiesel yield per reactor with a homogeneous alkali-catalyzed biodiesel synthesis. Compared with conventional stirred reactors, the time for high methyl ester conversion can be shortened remarkably by the use of metal foam reactors. The results indicate the great potential of metal foam reactors in small-fuel biodiesel processing plants for distributive applications. Lead – Foams Electrodes “Experiences of Lead-Foam Production by Several Processing Routes” “Development of lead-foam electrodes for high-efficient batteries recycling scraps” M.E. Tata, G. Costanza Lead – foams could be used as electrodes in batteries instead of Pb bulk. Two techniques have been used to manufacturing Pb foams: replication process (RP) and sintering and dissolution process (SDP). The electrodes were immersed in sulfuric acid 31% and subjected to charge. After four hours the accumulator had a voltage of 2.2 V. A 3W-lamp, powered by the electrodes during discharge, remained alight for 30 minutes. The goal of this work is to produce microporous electrodes that can replace the standard ones, with improved performance and a weight reduction. Aluminium Foam Sandwiches Aluminium Foams, particularly Aluminium Foam Sandwiches (AFS), offer a great potential for applications in the automotive industry. AFS are light weight, energy absorbing and incombustible and have good sound absorbing properties. Aluminium Foam Sandwiches are composites comprising an aluminium alloy foam core and two dense metallic sheets firmly attached to the core. AFS Properties • Light weight • Energy absorbing • Incombustible • Sound absorbing AFS Applications Regarding their promising mechanical properties the aluminium foams can be used in car/vehicle industry. The breakthrough happened already in 2006: for a structural item of Audi Q7 car featured by energy absorption. In the Ferrari F430 To offset the loss of the roof, the Spider's chassis has been significantly reinforced. The sill members have been strengthened with extremely light, rigid aluminium foam inserts where they connect to the rear B-pillar chassis members. Teupen (Gronau, Germay) has developed a novel concept for the support structure of a telescope arm lifting a working platform. Using AFS the goal was to increase the current working height of 20m to 25m while keeping the total weight below 3500 Kg. AFS Production One way to manufacture AFS was developed at the FraunhoferInstitute. A three layer composite comprising a foamable aluminium alloy sheet as a core layer and two face sheets on both sedes is made by extrusion or powder rolling and various subsequent rolling operations, after which the core layer of the panel is expanded by heating to the foaming temperature. A pure metallic bonding is maintained that is less heat sensitive than an adhesive and can be used to manufacture heat resistant non-inflammable structures. Effects of Powder mix composition “Effect of Powder mix composition on Al foam morphology” G. Gusmano, R. Montanari et.al. The effect of mix composition on foam morphology has been examinated by image analysis carried out on metallographic sections of Al foams prepared by powder metallurgy. Samples have been prepared by using SiC particles with different mean size and different amounts of TiH2. SiC particles distribution on the internal walls of the bubbles has been investigated by SEM observations, which evidenced also the presence of particles of another phase, identified as Ti3Al by EDS. Artificial Neural Networks “Effect of Powder mix composition on Al foam morphology” G. Gusmano, R. Montanari et.al. Experimental data discuss in the previous work have been used for training two multi-layer feedforward artificial neural networks. The model represent useful tools for predicting morphologic features of foams for any given mix composition in the training range. Finite Element Model (FEM) “Numerical Simulation of Open-Cell Aluminium Foams Under Compression” F. Quadrini, D. Bellisario, D. Ferrari, L. Santo, A. Santarsiero The numerical simulation of the compression behavior of open-cell aluminium foams is a way to extract material prperty information. A bilinear isotropic model was implemented for the alloy base material whereas a parametric approach was used to build the finite element model of the foam structure. Compression tests were performed on commercial foams with different pore size and density, and the results of lower density foam were used for the model validation. Numerical results show a good agreement with experimental data in terms of foam deformation under compression and required loads. Sheet/Core metallic bonding MiSE – ENEA Ricerca di Sistema Elettrico Fe Al “Risparmio di energia nel settore dei trasporti” Has been studied the possibility of establishing a metallurgical bond between steel sheets and Al alloy core. The EDS analysis show the interdiffusion of Al and Fe through an interface of about 40 microns. EDS signal for Al. EDS signal for Fe. Sheet/Core metallic bonding Has been studied the possibility to reinforce extruded AA6060 with AlSi10 foam. The results show a good metallurgical bond and a lack of homogeneity in the foam due to an incorrect calibration of the temperature in the oven. Extruded profile in AA6060 AlSi10 Foam Hot pressing and extrusion. Automatic Foaming Oven. PSR2 Estruso 20 X 30 X 400 mm Parte finale collassata PSR1 RX digitali PSR2 Grazie per l’attenzione