Operational Aspects Process, Energy and System Typical: Processes are designed & optimized based on given (fixed) data (flowrates, temperatures, pressures, etc.) But: Processes (and Heat Exchanger Networks) are: − often operated “off” design (above/below) − subject to disturbances − to be started up and shut down The Result: The Process Engineer will over-design before the Control Engineer adds new Units for Manipulation Various Topics for Heat Exchanger Networks T. Gundersen OPER 01 • Various Operational Aspects Controllability Process, Energy and System • • • • • • • Property of the Process, not the Control System Ability to handle operational Variations Flexibility Ability to cope with different Operating Conditions Start-Up and Shut-Down Starting up from “Cold” Conditions is challenging “Switchability” Change Operation from one Condition to another Environmental Aspects Safety Maintenance “RAMS” Reliability, Availability, Maintainability, Safety Various Topics for Heat Exchanger Networks T. Gundersen OPER 02 Two important Aspects of Operability • Controllability of Processes Process, Energy and System “Ability to handle Short Term Variations” Withstand (unwanted) Disturbances Stability Issues • Follow (wanted) Set-Point Changes On-line Optimization Flexibility of Processes “Ability to handle Long Term Variations” Undesirable Variations Fouling (or Scaling) in Heat Exchangers Deactivation of Catalysts Desirable Variations/Changes New Raw Materials and/or new Products Changes in Production Volume Various Topics for Heat Exchanger Networks T. Gundersen OPER 03 Similarities/Analogies between Synthesis of Processes and Control Systems Process, Energy and System Process Control Levels • Production Site • Process • Equipment • Optimizing • Advisory • Basic Control Structure • Choice of Units • Matching • Sequences • Manipulators • Pairing • Controller Types Parameters • Pressures • Temperatures • Flowrates • Gain • Integral Time • Derivative Time Various Topics for Heat Exchanger Networks T. Gundersen OPER 04 WS-1: Heat Integration Process, Energy and System Stream H1 H2 C1 Steam ΔH Ts Tt mCp °C °C kW/°C kW 300 100 200 100 50 250 280 280 Cooling Water 15 20 1.5 5.0 4.0 300 500 800 (var) (var) Specification: ΔTmin = 20°C Find: QH,min , QC,min Tpinch , Umin Umin,MER and Network Notice: 1) H1 and H2 provide as much heat as C1 needs (800 kW) 2) Ts (C1) < Tt (H1,H2) − 20° and Ts (H1) > Tt (C1) + 20° Heat Integration − Introduction T. Gundersen OPER 05 WS-1: What about Controllability? Process, Energy and System III I 300°C mCp (kW/°C) 200ºC 186.7ºC H1 100°C C 1.5 130 200°C II 100°C 5.0 H2 50°C 250°C H 130 217.5°C 180°C 150 55°C 500 C1 4.0 20 MER Design with QH = QH,min , QC = QC,min , U = Umin,MER Consider: Disturbance for H1 inlet T, while controlling H2 outlet T Heat Integration − Introduction T. Gundersen OPER 06 Flexibility in Heat Exchanger Networks Process, Energy and System mCp 310° 1.0 H1 1 450° 2.0 3.0 2.0 50° 290° 3 H2 2 280° 285° C 10 kW 120° 290° 1 20 kW 280° 40° 2 C1 240 kW 115° 3 C2 330 kW Various Topics for Heat Exchanger Networks T. Gundersen OPER 07 Flexibility in Heat Exchanger Networks Process, Energy and System mCp 310° 1.85 H1 1 450° 2.0 3.0 2.0 50° 179.7° 3 H2 2 280° 395.5° C 231 kW 120° 290° 1 241 kW 169.5° 40° 2 C1 240 kW 115° 3 C2 109 kW Various Topics for Heat Exchanger Networks T. Gundersen OPER 08 Flexibility in Heat Exchanger Networks Process, Energy and System mCp 310° 1.35 H1 1 50° 227.8° 2 450° 2.0 3.0 2.0 3 H2 280° 330.5° C 101 kW 120° 290° 1 111 kW 234.5° 40° 2 C1 240 kW 115° 3 C2 239 kW Various Topics for Heat Exchanger Networks T. Gundersen OPER 09 Flexibility in Heat Exchanger Networks Process, Energy and System In Summary: The Network Structure was Flexible (Resilient) for the Cases when mCp was 1.0 and 1.85 for Stream H1, but did not work when mCp was 1.35 even with infinite Heat Transfer Area. The Reason: The Problem is Non-Convex, which happens when: − the Pinch point changes − there is a change in Mass Flowrates Various Topics for Heat Exchanger Networks T. Gundersen OPER 10 WS-5: Design for Flexibility Q: How to handle Fouling ? Process, Energy and System U1 (W/m2K) 200° 1 1 170° 115° 2 155° 3 2 175° 1 175° H 90° 120 4 20° 84° 138° 134° Exchanger 1 has fouling above 125°C 3 2 3 73° 81 20° 4 4 6 12 Time (months) Ref.: Kotjabasakis and Linnhoff, Oil & Gas Jl., Sept. 1987 Various Topics for Heat Exchanger Networks T. Gundersen OPER 11 WS-5: Fouling in Heat Exchangers 1: The Traditional Approach Process, Energy and System 200° 1 170° 115° 2 1 155° 3 2 175° 1 175° H 90° 4 New Area: 148 m2 20° 84° 138° 134° 3 2 73° 4 3 Energy Usage: 20° Constant (the same) 4 Various Topics for Heat Exchanger Networks T. Gundersen OPER 12 WS-5: Fouling in Heat Exchangers 2: An alternative Solution Process, Energy and System 200° 170° 115° 2 1 1 155° 3 2 175° H 175° H 1 138° 134° 90° 4 New Unit: Heater on Stream 3 20° 84° 3 2 73° 4 3 Energy Usage: 20° From 1850 to 2140 kW 4 Various Topics for Heat Exchanger Networks T. Gundersen OPER 13 WS-5: Fouling in Heat Exchangers 3: Use Network Interactions Process, Energy and System 200° 1 170° 115° 2 1 155° 3 2 175° 1 175° H 90° 4 New Area: 103 m2 20° 84° 138° 134° 3 2 73° 4 3 Energy Usage: 20° 15% Reduction !! 4 Various Topics for Heat Exchanger Networks T. Gundersen OPER 14 WS-5: Fouling in Heat Exchangers Summary Process, Energy and System “Method/Approach” ΔArea ΔEnergy Traditional Approach 148 m2 0 Alternative Solution New Heater + 13% Network Interactions 103 m2 - 15% Best Result obtained by using a “Systems Approach” Various Topics for Heat Exchanger Networks T. Gundersen OPER 15 Summary of Operability Process, Energy and System • • • • • Plant Operation is often “Off-Design” • Process Integration has a Focus precisely on the Structural Aspects of Process Plants Controllability (Short Term Variations) Flexibility (Long Term Variations) A new Design Strategy for Fouling The importance of Topology (Flowsheet or Network Structure) has been proven Various Topics for Heat Exchanger Networks T. Gundersen OPER 16 Objectives Process, Energy and System from Energy Cost to Equipment Cost to Total Annualized Cost and also Operability, including Flexibility Controllability Switchability Expansions of PA & PI Start-up & Shut-down New Operating Conditions and finally Environment, including Emissions Reduction Waste Minimization Expansions of Process Integration T. Gundersen EXP 01 Scope Expansions of PA & PI Process, Energy and System from Heat Exchanger Networks to Separation Systems, especially Distillation and Evaporation (heat driven) to Reactor Systems to Heat & Power, including Steam & Gas Turbines and Heat Pumps to Utility Systems, including Steam Systems, Furnaces, Refrigeration Cycles to Entire Processes to Total Sites to Regions Expansions of Process Integration T. Gundersen EXP 02 Expansions Plants Process, Energy and System from Continuous to Batch and Semi-Batch of PA & PI Projects from New Design to Retrofit to Debottlenecking Thermodynamics from Simple 1st Law Considerations to Various 2nd Law Applications Exergy in Distillation and Refrigeration Expansions of Process Integration T. Gundersen EXP 03 Expansions Process, Energy and System Methods of PA & PI Pinch based Methodologies from Analogies from Heat Pinch for Heat Recovery and CHP in Thermal Energy Systems to Mass Pinch for Mass Transfer / Mass Exchange Systems to Water Pinch for Wastewater Minimization and Distributed Effluent Treatment Systems to Hydrogen Pinch for Hydrogen Management in Oil Refineries Other Schools of Methods was discussed on a previous slide Expansions of Process Integration T. Gundersen EXP 04 Process, Energy and System Expansions in Process Integration Process Integration is much more than Pinch Analysis for Heat Exchanger Networks Strategic Planning Heat Integration Conceptual Design Detailed Engineering Expansions of Process Integration T. Gundersen EXP 05 Stages and Analogies in Methods T Process, Energy and System Heat Pinch Heat Pinch Modeling Q Mass Pinch Data Extraction Graphical Diagrams Analysis Representations and Concepts Water Pinch Design Performance Targets ahead of Design Hydrogen Pinch Optimization Pinch Decomposition Expansions of Process Integration T. Gundersen EXP 06 Wastewater Minimization Process, Energy and System Topic: Efficient Use of Wastewater Reuse, Regeneration and Recycling - both Targets and Design Methods: Ref.: Water Pinch (discussed here) Mathematical Programming Wang and Smith “Wastewater Minimization”, Chem. Engng. Sci., vol. 49, pp 981-1006, 1994 Water Pinch Demonstration T. Gundersen EXP 07 Wastewater Minimization Process, Energy and System Graphical Representation T C mass/heat analogy Cpr,in Cout,max Cpr,out Cin,max 3 2 1 m H H = mCp ΔT Δm = mH2O C Water Pinch Demonstration T. Gundersen EXP 08 Main Results from Pinch Analysis QH,min Process, Energy and System T C Heat Pinch QC,min Water Pinch Watermin H m • The Concept of Composite Curves Applicable whenever an “Amount” has a “Quality” Heat & Temperature, Mass & Concentration, etc. • A Two Step Approach: Targets ahead of Design • A fundamental Decomposition at the Pinch Final Summary T. Gundersen SUM 01 Objectives for using Process Integration Process, Energy and System • Minimize Total Annual Cost by optimal Trade• • • • • • off between Energy, Equipment and Raw Material Within this trade-off: minimize Energy, improve Raw Material usage and minimize Capital Cost Increase Production Volume by Debottlenecking Reduce Operating Problems by correct rather than maximum use of Process Integration Increase Plant Controllability and Flexibility Minimize undesirable Emissions Add to the joint Efforts in the Process Industries and Society for a Sustainable Development Final Summary T. Gundersen SUM 02