Midterm Review Worksheet Solutions 1. List and describe the steps of the scientific method. 2. Problem – determine what you need an answer for Observations – observe the situation Scientific Hypothesis – make an educated guess based on your observations Test – perform an experiment Conclusion – determine if your hypothesis is correct Determine the number of significant figures in each of the following measurements: 2050 mL = 3 sig figs 0.010230 mm = 5 sig figs 0.0023032 g = 5 sig figs 200.400 mL = 6 sig figs 3. Calculate the following to the correct number of significant figures: 4. 12.0302 + 45.1 + 6.24 = 63.3702 = 63.4 625.23 – 52.32154 = 572.90846 = 572.91 4.82 * 6.1 = 29.402 = 29 625.214 / 12.2 = 51.24704918 = 51.2 Put the following numbers into scientific notation: 0.000032871 = 3.2871 x 10-5 998.227 = 9.98227 x 102 5. Use factor label to perform the following conversions (SHOW ALL WORK): 125 cm = ? m 1𝑚 125 𝑐𝑚 = 1.25 𝑚 100 𝑐𝑚 725 lb = ? ton 0.45 𝑘𝑔 725 𝑙𝑏 1 𝑙𝑏 0.001 𝑡𝑜𝑛 = 0.326 𝑡𝑜𝑛 1 𝑘𝑔 54000 µm = ? cm 1𝑚 54000µ𝑚 1,000,000 µ𝑚 25 mi/h = ? m/s 25 𝑚𝑖 5280 𝑓𝑡 1𝑚 ℎ 1 𝑚𝑖 3.281 𝑓𝑡 100 𝑐𝑚 = 5.4 𝑐𝑚 1𝑚 1ℎ 60 𝑚𝑖𝑛 1 𝑚𝑖𝑛 = 11 𝑚/𝑠 60 𝑠 6. What is the density of a diamond that has a volume of 0.35 mL and a mass of 1.14 g? 𝑀 1.14 𝑔 𝑔 𝐷= = = 3.3 (𝑖𝑛 𝑠𝑖𝑔 𝑓𝑖𝑔𝑠) 𝑉 0.35 𝑚𝐿 𝑚𝐿 7. If the accepted density for the sample in problem #6 is 3.28 g/mL, calculate the percent error for your calculation. 𝑎−𝑜 3.28 − 3.3 % 𝑒𝑟𝑟𝑜𝑟 = ∗ 100% = ∗ 100% = 0.61% 𝑎 3.28 Identify the type of energy contained in: 8. A. B. C. A baseball that has just been thrown: Kinetic A book hanging on the end of a shelf: Potential Light from a light bulb: Radiant List the distinguishing characteristics of solids, liquids, and gases: 9. 10. a. b. c. d. e. f. Solids: Definite volume, definite shape Liquids: Definite volume, indefinite shape Gases: Indefinite volume, indefinite shape Identify the following as a physical or chemical change: Tearing a piece of paper – Physical A plant converting sunlight to food – Chemical Burning wood in a fireplace – Chemical Melting snow – Physical Baking a cake – Chemical Crushing rock - Physical 11. Identify each as an element, compound, homogeneous mixture, or heterogeneous mixture: a) b) c) d) e) f) g) h) i) Alphabet soup – heterogeneous mixture Salt – compound Vegetable Oil – compound Air – homogeneous mixture Steel – homogeneous mixture Sugar – compound Pure water – compound Tap water – homogeneous mixture Sea water – heterogeneous mixture 12. What is the law of conservation of mass? 13. Describe the contributions of Aristotle and Democritus 14. Mass can neither be created nor destroyed in any chemical reaction Aristotle believed that there were four elements: Earth, Air, Fire, and Water Democritus believed that all matter was made up of tiny, indivisible particles Explain Dalton’s Atomic Theory and his model Postulates that explained what he believed about atoms Billiard ball model of the atom – solid sphere of uniform density 15. Describe Thomson’s model of the atom. What was it called? 16. Describe the experiment done by Rutherford. What was it called? What did it explain? Describe his model. 17. Thomson believed that there were negatively charged subatomic particles called electrons floating in a positive environment. His model is the plum pudding model. Gold Foil Experiment – proved that there was a large concentration of positive charge in the center of the atom – Rutherford called it the nucleus (Nuclear model) Define atomic number and mass number. Atomic number – the number of protons in an atom Mass number – sum of protons and neutrons in an atom 18. Define ion. Describe how atoms become positive or negative ions. What are each called? 19. Ion – atom that has lost or gained electrons and has an overall charge Positive ions lose electrons – Cations Negative ions gain electrons - Anions Determine the atomic number, mass number, number of protons, neutrons, and electrons in each of the following: Atomic # Mass # P+ N0 E- Calcium-44 20 44 20 24 20 13 27 13 14 13 8 18 8 10 8 34 78 34 44 34 17 35 17 18 18 27 𝐴𝑙 Oxygen-18 78 34𝑆𝑒 35 -1 17𝐶𝑙 20. Find the average atomic mass of magnesium: 𝐴𝐴𝑀 = 23.985 ∙ 0.7899 + 24.986 ∙ 0.100 + 25.983 ∙ 0.1101 = 24.31 amu 21. Write the nuclear equation for the alpha decay of gold-185 185 79𝐴𝑢 22. → 42𝛼 + 181 77𝐼𝑟 Write the nuclear equation for the beta decay of uranium-238 238 92𝑈 → 0 −1𝛽 + 238 93𝑁𝑝 23. A photon of visible light has a wavelength of 528 nm. Find the frequency of the light and the energy it contains. 1𝑚 528 𝑛𝑚 = 5.28𝑥10−7 𝑚 1,000,000,000 𝑛𝑚 𝑐 3.0𝑥108 𝑚/𝑠 14 𝐻𝑧 ν= = = 5.68𝑥10 λ 5.28𝑥10−7 𝑚 𝐸 = ℎν = 6.626𝑥10−34 𝐽 ∙ 𝑠 5.68𝑥1014 𝐻𝑧 = 3.76𝑥10−19 𝐽 24. A certain wave has 3.78x10-19 J of energy. Find the wavelength and frequency. 𝐸 = ℎ𝜈 ⇒ 3.78𝑥10−19 = (6.626𝑥10−34 )ν ⇒ 5.70𝑥1014 𝐻𝑧 25. 𝑐 3.0𝑥108 𝑚/𝑠 −7 𝑚 𝜆= = = 5.26𝑥10 ν 5.70𝑥1014 𝐻𝑧 Explain: Aufbau principle, Pauli Exclusion principle, and Hund’s Rule Aufbau principle – Orbitals fill from the lowest energy to the highest Pauli Exclusion principle- Any two electrons that occupy the same orbital must have opposing spins Hund’s Rule – electrons fill all empty orbitals within a sublevel 26. Draw the orbital diagram of Cadmium and write the full electron configuration. How many unpaired electrons are there? 1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 1s22s22p63s23p64s23d104p65s24d10 - Zero unpaired e27. Write the abbreviated (noble gas) configuration for Iodine. [Kr] 5s24d105p5 26. Write the full electron configuration for Se-2. 1s22s22p63s23p64s23d104p65s2 29. Give the contributions to the periodic table from each of the following scientists: Mendeleev: First Periodic Table Moseley: Discovery of atomic number/protons determining the identity of the element Dobereiner – Organized the elements into Triads Newlands – Organized the elements into Octaves 30. • • • • Tell the name of the group that each of the following elements belongs to: Calcium – alkaline earth metal Argon – noble gas Silicon – carbon group Iodine – halogen • • • • Cesium – alkali metal Sulfur – oxygen group Aluminum – boron group Antimony – nitrogen group 31. Identify each of the above elements as a metal, non-metal, or metalloid: Calcium – metal Argon – non metal Silicon – metalloid Iodine – non metal • • • • 32. What are the properties of metals? 33. • • • • 34. Cesium – metal Sulfur – non metal Aluminum – metal Antimony – metalloid • • • • Malleable, ductile, lustrous, conduct electricity Circle which element is smaller: Ca or Ga Be or Mg Br or I Tl or Pb • • • • Na or Na+ O or O2Br or its ion (Br1-) Sr or its ion (Sr2+) Circle which has a higher ionization energy: • K or Ca • P or Sb • Al or Si • Rb or Fr 37. Circle which element is more electronegative: • N or F • Al or Si • Rb or Sn • Ca or Ba • As or Bi