AP Chemistry First Week Homework—This is the only time I’m going to type out your homework (our textbooks will be assigned on Friday). Monday 8/25/2014 1) A measurement is a quantitative observation involving both a number and a unit. a) What is a qualitative observation? ____________________________________________________ b) What are the SI units for mass, length, and volume? ______________________________________ 2) To determine the volume of a cube, a student measured one of the dimensions of the cube several times. If the true dimension of the cube is 10.62 cm, give an example of four sets of measurements that would illustrate the following. a) imprecise and inaccurate data _______________________________________________ b) precise but inaccurate data _______________________________________________ c) precise and accurate data _______________________________________________ 3) How many significant figures are there in each of the following values? a) 6.07 x 10-15 d) 300 b) 17.00 e) 301 c) 8 x 108 f) 300. 4) How many significant figures are in each of the following? a) 100 d) 0.00480 2 b) 1.0 x 10 e) 4.80 x 10-3 c) 0.0048 f) 4.800 x 10-3 5) Round off each of the following numbers to the indicated number of significant digits, and write the answer in standard scientific notation. a) 0.00034159 to three digits _______________________ 2 b) 103.351 x 10 to four digits _______________________ 6) Use exponential notation to express the number 385,500 to a) one significant figure _______________________ b) three significant figures _______________________ 7) Evaluate each of the following, and write the answer to the appropriate number of significant figures. a) 212.2 + 26.7 + 402.09 = ______________ b) 1.0028 + 0.221 + 0.10337 = ___________ c) 52.331 + 26.01 – 0.9981= ____________ 8) Perform the following mathematical operations, and express each result to the correct number of significant figures. 0.102 x 0.0821 x 273 a) = ______________________ 1.01 b) 0.14 x 6.022 x 1023 = ______________________ 2.00 x 106 c) = ______________________ 3.00 x 10−7 Tuesday 8/26/2014 (also prepare for safety “test” on Wednesday) 1) When a marble is dropped into a beaker of water, it sinks to the bottom. Which of the following is the best explanation? a) The surface area of the marble is not large enough to be held up by the surface tension of the water. b) The mass of the marble is greater than the mass of the water. c) The marble weighs more than an equivalent volume of water. d) The force from dropping the marble breaks the surface tension of the water. e) The marble has greater mass and volume than the water. Justify your choice. 2) Perform the following unit conversions. a) 908 oz = ______________ kilograms b) 12.8 L = ______________ gallons c) 4.48 lb = ______________ grams 3) Mercury poisoning is a debilitating disease that is often fatal. In the human body, mercury reacts with essential enzymes leading to irreversible inactivity of these enzymes. If the amount of mercury in a polluted lake is 0.4 μg Hg/mL, what is the total mass in kilograms of mercury in the lake? (The lake has a surface area of 100 mi2 and an average depth of 20 ft.) Show your work for credit. 4) Convert the following Kelvin temperatures to Celsius and Fahrenheit degrees. a) 233 K = _______ C = _______ F b) 4 K = _______ C = _______ F 5) The density of pure silver is 10.5 g/cm3 at 20°C. If 5.25 g of pure silver pellets is added to a graduated cylinder containing 11.2 mL of water, to what volume level will the water in the cylinder rise? 6) Classify each of the following mixtures as homogeneous or heterogeneous. a) Potting soil b) Window glass c) Granite 7) Classify each of the following as a mixture or a pure substance. a) Blood d) Brass b) The oceans e) Uranium c) Iron f) Leather g) Table salt Wednesday 8/27/2014 1) Dalton assumed that all atoms of the same element were identical in all their properties. Explain why this assumption is not valid. 2) What happens to the ratio of the mass number to the atomic number of a stable isotope, as stable isotopes become heavier? 3) What is the trend in metallic character (increasing/decreasing) as you go down group 4A? 4) What is the trend in metallic character (increasing/decreasing) as you move from left to right across a period in the periodic table? 5) Now, what do you think “metallic character” means? ______________________________________ 6) What is the difference between ionic and covalent bonding? 7) What is the difference between an anion and a cation? 8) Do salts (ionic compounds) form molecules? Explain. ____________________________________ 9) If 1 L of H2 reacts with 1 L of Cl2 at the same temperature and pressure, what volume of HCl is formed? 10) A sample of sulfuric acid contains 2.02 g hydrogen, 32.07 g sulfur, and 64.00 g oxygen. How many grams of sulfur would be present in a second sample of sulfuric acid if it contained 7.27 g of hydrogen? 11) In a combustion reaction, 46.0 g of ethanol reacts with 96.0 g of oxygen to produce water and carbon dioxide. If 54.0 g of water is produced, what mass of carbon dioxide is produced? 12) What are the symbols of the following elements? a. Sodium ___________ b. Radium ___________ c. Iron ___________ d. Manganese ___________ e. f. g. h. Chlorine ___________ Sulfur ___________ Oxygen ___________ Phosphorous___________ 13) Classify the following as metals, metalloids, or nonmetals. a. Mg _____________________ f. Br b. Bi _____________________ g. Element #17 c. B _____________________ h. Element # 63 d. Ge _____________________ i. Element #2 e. Am _____________________ j. Element #55 _____________________ _____________________ _____________________ _____________________ _____________________ 14) Color the periodic table to the right, giving each group its own color according to the list below. Use the list as a key by circling/shading/highlighting each group with the color you used. a. Alkali metals b. Alkali earth metals c. Halogens d. Noble gases e. Transition metals f. Inner transition metals g. Other metals h. Other nonmetals 15) Write the atomic symbol for an isotope where Z = 20 and the number of neutrons = 27. __________ 16) How many protons and neutrons are in the nucleus of one atom of… a. Cesium-133? p = ______ n = ______ b. Iron-57? p = ______ n = ______ 17) How many protons and electrons (total and valence) are in each of the following ions? a. Ba2+ p = ______ total e= _______ valence e = ______ 3b. N p = ______ total e= _______ valence e = ______ 3+ c. Co p = ______ total e= _______ valence e = ______ 18) Which groups of elements typically gain electrons when they become ions? _____________ Which groups typically lose electrons when they become ions? ___________ Thursday 8/28/2014 Pg. 72-80 Fill out the following table. Name Formula NaBr Strontium fluoride CaS Potassium nitride Hg2O Tin (II) nitride CoS Mercury (II) oxide CsF Ag2S TiO2 Zinc Chloride Tin (IV) bromide Calcium phosphide KMnO4 K2Cr2O7 Chromium (III) hydroxide Magnesium cyanide Diboron trioxide Arsenic Pentafluoride CuI NaOCl NH4NO3 HC2H3O2 Pb3(PO4)2 KClO3 SnO2 HClO SO42SeO42H2TeO4 HClO3 HIO3 Sulfur difluoride Sodium dihydrogen phosphate Ammonium acetate Disulfur dichloride Ammonia Sodium oxide Sodium peroxide Nitrous acid Iodous acid Zinc sulfide Silicon dioxide Perbromic acid Each of the following compounds is incorrectly named. Circle the part that makes it incorrect, and write the correct name for each formula. There may be more than one error in some of the names. FeCl3 Iron chloride Correct name: _____________________________________ NO2 Nitrogen (IV) oxide Correct name: _____________________________________ Mg(C2H3O2)2 Magnesium diacetate Correct name: _____________________________________ H2S Sulfuric acid Correct name: _____________________________________ FePO4 Iron (II) phosphide Correct name: _____________________________________ Friday 8/29: Go over any questions from this homework set that you may have had trouble with. The answers are online and our Ch 1/2 Exam is on W 9/3. We will review T 9/2.