Average Atomic Mass Relative Atomic Masses Masses of atoms (in grams) are very small, so for convenience we use relative masses. Carbon-12 is our standard Atomic mass (u or amu): 1/12 the mass of a carbon-12 atom or 1.6605402 x 10-24 g. **Mass number and atomic mass are close to each other, but not identical because the proton and neutron masses deviate slightly from 1 amu and atomic mass includes electrons** Average Atomic Mass Average Atomic Mass: the weighted average of the atomic masses of the naturally occurring isotopes of an element This number appears on the periodic table below the symbol Steps 1. Convert % abundance to decimal form (80 % 0.80) 2. Multiply decimal form of % abundance by the actual mass of isotope 3. Add the products of each isotope to get the average atomic mass Example 1 Copper exists as two isotopes, copper-63 (actual mass 62.939598) with 69.17% abundance and copper-65 (actual mass 64.927793) with 30.83% abundance. Find the average atomic mass. Cu-63 = (0.6917) (62.939598) = 43.53531994 Cu-65 = (0.3083) (64.927793) = 20.01723858 63.55 amu + Example 2 Calculate the estimated average atomic mass of neon if neon exists naturally as 90.22% neon-20, 0.57% neon-21, and 8.82% neon-22. Note: If the actual mass of each isotope is not available, the average atomic mass may be estimated by using the mass number of each isotope. Ne-20 = (0.9092) (20) = 18.184 Ne-21 = (0.0057) (21) = 0.1197 Ne-22 = (0.0882) (22) = 1.764 + 20.07 amu