Unit 13 Marker Board Review Acids & Bases You need a marker board, marker, eraser, calculator, & periodic table. Question #1 List 4 properties of acids. Answer: 1 – Sour taste 2 – React with metals to form hydrogen gas 3 – React with metal carbonates to form CO2 gas 4 – Turn indicators red Question #2 List 4 properties of bases. Answer: 1 – Taste bitter 2 – Unreactive with metals and carbonates 3 – Feel slippery 4 – Turn indicator blue Question #3 According to Arrhenius, acids ionize to produce _______ ions & bases ionize to produce _______ ions. Answer: hydrogen hydroxide Question #4 A Bronsted acid _____________ a _______________ and a base ______________ a ____________. ___________ is a substance that can either donate or accept a H+ ion. Answer: - donates, hydrogen ion - accepts, hydrogen ion - Amphoprotic/Amphoteric Question #5 Label the Acid, Base, Conjugate Acid, & Conjugate Base for each reaction below: • NH3 + H2O NH4+ + OH• H2CO3 + H2O H3O+ + HCO3Answer: NH3 + H2O NH4+ + OHB A CA CB H2CO3 + H2O H3O+ + HCO3A B CA CB Question #6 Strong acids ionize _______________ while weak acids ionize ________________. Which is the stronger acid? Oxalic Acid: Ka = 5.1 x 10-5 Carbonic Acid: Ka = 4.8 x 10-11 Answer: completely; only partially; Oxalic Acid (larger Ka value) Question #7 When an acid reacts with a base to neutralize it, the products are a ___________ & ___________. Answer: Salt & Water Question #8 List (write the formula for) the 6 strong acids. Answer: HCl HI HBr HClO4 HNO3 H2SO4 Question #9 Acids have a pH ___________ than 7. Bases have a pH __________ than 7. Pure water has a pH of _____ because . . .? Answer: Less Greater 7 because it is neutral! Question #10 Write the name for the following formulas. Is it an acid or base? Check your answers after you’ve written ALL of them! • • • • • • • • • HBr NaOH HNO2 H3PO3 NH3 H2SO4 Mg(OH)2 H2CO3 HC2H3O2 Hydrobromic Acid—acid Sodium Hydroxide—base Nitrous Acid—acid Phosphorous Acid - acid Ammonia—base Sulfuric Acid—acid Magnesium Hydroxide - base Carbonic Acid—acid Acetic Acid—acid Question #11 Write & balance the equation for the neutralization of sulfuric acid with potassium hydroxide. Answer: H2SO4 + 2 KOH 2 H2O + K2SO4 Question #12 Write & balance the neutralization reaction of hydrobromic acid & calcium hydroxide. Answer: 2 HBr + Ca(OH)2 2 H2O + CaBr2 Question #13 The formula for the hydronium ion is ____________________ & for the hydroxide ion _______________. Answer: H30+ & OH- Question #14 An H+ ion is really just a _______________ and cannot exist in solution. Answer: Proton Question #15 Write the equation for the self-ionization of water. Answer: H2O + H2O OH- + H3O+ Question #16 The formula for calculating [H3O+] from pH is ______________________. I type this into my calculator as: _________ Answer: [H3O+] = 10^(-pH) 2nd log (negative pH) Question #17 The formula for calculating [H3O+] from [OH-] is ______________________. I type this into my calculator as: _______ Answer: Kw = [OH-][H3O+] = 1.0 x 10-14 [H3O+] = 1.0 x 10-14 [OH-] 1.0 E -14 / [OH-] Question #18 • List the formulas for pH, H+ concentration, pOH, & OH- concentration. Answer: pH = -log [H+] OR 14 - pOH [H+] = 10^(- pH) OR 1.0 x 10-14 / [OH-] pOH = -log [OH-] OR 14 - pH [OH-] = 10^(- pOH) OR 1.0 x 10-14 / [H3O+] Question #19 • pH + pOH = ___________ •Answer: 14 Question #20 What is the pH of an HCl solution with a concentration of 0.0015 M? Acidic or basic? •Answer: pH = -log (0.0015) = 2.8 Acidic Question #21 • What is the pH of a solution with an pOH of 10.5? Acidic or basic? Answer: pH = 14 – pOH = 14 – 10.5 = 3.5 Acidic Question #22 • What is the [H+] of a solution with a pH of 4.51? Answer: [H+] = 10^(-4.51) = 3.09 x 10-5 M Question #23 • What is the pOH of a solution with a [H+] of 9.99 x 10-9 M? Acidic or basic? Answer: pOH = -log [OH-] [OH-] = 1.0 x 10-14 / 9.99 x 10-9 = 1.0 x 10-6 M pOH = -log(1.0 x 10-6) = 6.0 pH = 14 – 6.0 = 8.0 Basic Question #24 • What is the pOH of a solution with an [OH-] of 7.81 x 10-3 M? Acidic or basic? Answer: pOH = -log [OH-] = -log (7.81x10-3) = 2.1 pH = 14 – 2.1 = 11.9 Basic Question #25 • Calculate the [OH-] if the pOH is 5.21. Answer: [OH-] = 10^(-5.21) = 6.17 x 10-6 M. Question #26 What is the purpose of a titration? What is the role of an indicator in a titration? What has been reached when acid and base completely neutralize one another? Answer: A titration enables you to determine the concentration of a solution by reacting a known volume of the solution with a solution of known concentration. An indicator changes color when the end point of the titration has been reached. The end point has been reached. Question #27 • You add a substance to pure water and the pH rises from 7 to 9. What has happened to the concentration of H3O+? Is the substance added an acid or a base? Answer: The concentration of H3O+ has decreased. The substance is a base. Question #28 • In the titration of a strong acid with a strong base, what pH range should the indicator have? Answer: 6-8 Question #29 • Write the balanced equation for the reaction between nitric acid and magnesium hydroxide. Answer: 2 HNO3 + Mg(OH)2 Mg(NO3)2 + 2 H2O Question #30 • What is the molarity of HNO3 if 15.0 mL is completely neutralized by 38.5 mL of 0.15 M Mg(OH)2? Answer: 2 HNO3 + Mg(OH)2 Mg(NO3)2 + 2 H2O MaVaCb = MbVbCa Ma(15.0)( 1) = (0.15)(38.5)(2) Ma = 0.77 M