Nonrenewable Fossil Fuels are FINITE!! • Include: – Coal – Oil – Natural Gas What are they? Hydrocarbons! CHx’s (C-H chains): How did oil and natural gas form? Black Gold • Plants/animal that lived up to 300 million yrs. ago died and decomposed… –Mostly phyto/zooplankton • Pressure/heat/time broke down this organic matter into simpler hydrocarbons Oil extraction: Drilling • Petroleum or crude oil: thick/gooey – Hundreds of CHx’s and impurities – Needs to be Refined through Distillation (separated by different boiling points) • “Cracking” • The oil industry is the world’s largest business… What country has the largest proven crude oil reserves??? Saudi Arabia OPEC • Organization of Petroleum Exporting Countries –Algeria –Angola –Ecuador –Iran –Iraq - Kuwait - UAE - Libya - Venezuela - Nigeria - Qatar - Saudi Arabia ANWR • Should the U.S. Drill for more??? Other oil resources… • Shale Oil: kerogen Oil/Tar sands • Bitumen However… • $$$$$$ (oil shale) • Need a LOT of water • MINING ruins more land than drilling • Pollution • LOW net energy • Net Energy: –Total amount of energy available from the resource (ex: shale oil) minus the energy needed to find, extract, process, and get it to consumers. Natural gas extraction: Drilling • Mostly Methane but also – Ethane – Propane – Butane – Hydrogen sulfide Liquified Natural Gas (LNG) LNG • Natural gas is cooled to -162°C (260°F) • Lowered net energy • Shipped as a flammable liquid How did coal form? • Decomposed plant matter: – Sedimentary rock formed by coalification Steps in COAL formation: • Peat – Lignite – Bituminous – Anthracite • • • • Peat: low heat Lignite: low heat, low sulfur Bituminous: high heat, high sulfur Anthracite: high heat, low sulfur Coal extraction: Mining • What country has the biggest coal reserves??? • The United States! –Followed by: •Russia and China How do they provide ENERGY? • Combustion!! (Burning a CHx) releases ENEGY!!!! – Example: coal C137H97O9NS + O2 CO2 + H2O + SO2 + NO • 20C137H97O9NS + 2680O2 2740CO2 + 97H2O + 20SO2 + 20NO No… you don’t need to memorize this one… • Example: gasoline • Examples: methane and ethane How does that do work? • Energy for cars: Burn Gasoline – Internal Combustion Engine Intake-- Intake valve opens allowing fuel/air mixture into the cylinder · Compression-- The piston rises, reducing volume and increasing pressure · Expansion (power stroke)-- Spark plug ignites, fuel expands pushing piston · Exhaust-- Exhaust valve opens expelling spent fuel from cylinder • Burn natural gas for heat (which can also be used for electricity) • Burn coal for heat to produce electricity!! Electricity From a COAL FIRED power plant: • MINE for coal • PULVERIZE the coal • BURN the coal (in the boiler) • The heat boils water: –Liquid to steam • Steam turns a turbine – which is connected to a copper wire in the GENERATOR • Spinning copper wire is in a magnetic field • ELECTRONS FLOW! A simpler version… This power plant burns 25 TONS of coal each MINUTE • 3000 MW of electric power… START… END!