1 Student Packet for 12/7/15 – 12/11/15 Midterm set up: 40 Definitions 1. Hypothesis 2. Independent variable 3. Dependent variable 4. Observation 5. Constants 6. Control 7. Conclusion 8. Qualitative and quantitative 9. Accuracy and precision 10. Endothermic and exothermic 11. Matter, mass, volume, density 12. Solution, heterogeneous and homogeneous mixtures, colloids, suspensions 13. Solute and solvent 14. Protons, neutrons, electrons, ions, isotopes Topics to be covered : 60 Questions 1. Be able to list and explain the steps in the Scientific method 2. Matter and its states, heterogeneous and homogeneous mixtures and their properties; compounds and elements 3. Chemical and physical properties and changes 4. Calculation of density, mass, volume 5. Charles and Boyles gas law 6. Endothermic and exothermic reactions 7. Atomic theories and models (Democritus, Dalton, Rutherford, Bohr) 8. Periodic table and its trends 9. Calculating subatomic particles 10. Ions and isotopes 11. Bohr Model 12. Electron Configuration, Energy Levels and orbitals 13. Valence Electrons 2 List and describe the six steps to the scientific method in order. 1. ____________________________________________________________________________ 2. ____________________________________________________________________________ 3. ____________________________________________________________________________ 4. ____________________________________________________________________________ 5. ____________________________________________________________________________ 6. ____________________________________________________________________________ 7. ________ A student decided to set up an experiment to see if cats preferred skim milk or 2% milk. She put out a cup of milk for 5 kittens and then measured how much the kittens drank over the course of a day. The same kittens were used and the milk was served at the same temperature. The student discovered that the cats liked the 2% milk more than the skim milk. What is wrong with the above experiment? A. There is no independent variable. B. The milk should be served at different temperatures C. There are no constants present. D. Repeated experimentation is needed Raising the average temperature of the earth’s atmosphere will cause the polar ice caps to reduce in size. 8. ______________________________ is the independent variable 9. ______________________________ is the dependent variable 10. What is the control group?_________________________________ 11. What is the independent variable?_____________________________________ 12. What should Smither’s conclusion be?____________________________________ __________________________________________________________________________ __________________________________________________________________________ 3 1. Define Each of the following: matter volume weight gravity mass physical property conductivity malleability ductility solubility density boiling point melting point solute solvent atom element molecule compound heterogeneous mixture homogeneous mixture chemical property flammability reactivity precipitate viscosity 4 2. Identify the following changes as either physical or chemical. Be able to explain your answer. a. Burning coal b. Baking brownies c. Dissolving sugar in tea d. Melting butter e. Exploding fireworks 3. What are the signs of a chemical change? 4 What are the two types of pure substances? How are they alike? How are they different? 5 What are the three types of mixtures? How are they alike? How are they different? 6. draw a flow chart showing the classification of matter DENSITY 1. What is the density of CO gas if 0.196 g occupies a volume of 100 ml? 5 2. A block of wood 3 cm on each side has a mass of 27 g. What is the density of the block? (Hint, don’t forget to find the volume of the wood.) 3. A block of lead has dimensions of 4.50 cm by 5.20 cm by 6.00 cm. The block weighs 1587 g. From this information, calculate the density of lead. 4. What is the density of a board whose dimensions are 5.54 cm x 10.6 cm x 199 cm and whose mass is 28.6 g? 5. Calculate the mass of a liquid with a density of 3.2 g/mL and a volume of 25mL. 6. Calculate the density of a 500 g rectangular block with the following dimensions: length=8 cm, width=6 cm, height=5 cm 7. An irregular object with a mass of 18 g displaces 2.5mL of water when placed in a large cylinder. Calculate the density of the object. 8. A graduated cylinder has a mass of 80g when empty. When 20 mL of water is added, the graduated cylinder has a mass of 100 g. If a stone is added to the graduated cylinder, the water level rises to 45 mL and the total mass is now 156 g. What is the density of the stone? 6 9. Draw the graphs for and explain Endothermic and Exothermic Reactions. On the periodic table, these symbols refer to what elements? 1. Ar- ______________________ 2. Be _______________________ 3. B ________________________ 4. P - __________________________ 5. Si- ___________________ 6. Na ________________________ 7. He- ________________________ 8. Mg- _________________________ 9. N - ________________________ 10. Cl- ___________________________ 11. Li _________________________ 12. F - ___________________________ 13. Hydrogen ___________ 14. Neon __________ 1. The order of elements in the periodic table is based on _________________________________________________________________________________ _________________________________________________________________________________ 2. Atoms of elements that are in the same group have the same number of ______________________________________________________________________________ 3. List alkali metals and give 2 characteristics 7 4. List Alkaline earth metals and give 2 characteristics 5. List the halogens – and give 2 characteristics 6. List the noble gasses – and give 2 characteristics 7. What groups form anions? What groups form cations? 8. Group 1 is called _____________________________ 9. Group 2 is called ___________________________ 10. Groups 3-12 are called _________________________________________ 11. Group 17 is called ___________________________________ 12. Group 18 is called __________________________________ 13. What are metalloids __________________________________________________________________________ __________________________________________________________________________ Development of Atomic Theory: Part 1 (Democritus to Thomson) Do ideas or theories in Science stay the same? What causes this? Who was Democritus? What does the Greek word atomos” mean? ________________________________ 8 What is our modern definition of the atom? In the late 1700’s a British chemist and schoolteacher, John Dalton, brought back Democritus’s idea of the atom. What 3 ideas did his new theory of the atom propose? In 1897 a British scientist named Thomson discovered that atoms were not indivisible but were made up of smaller particles. What particle did Thomson discover and what electrical charge does it have? Thomson showed that electrons were part of atoms. Where did he think they were? What was the funny name for this model? Draw a model of the atom proposed by Thomson Label electrons. 1. _________________________________ _________________________________ _________________________________ _________________________________ 2. _________________________________ _________________________________ _________________________________ 3. _________________________________ _________________________________ The particle Thomson discovered was the ____________. It has a ___________charge. On the back of this sheet draw a diagram (Fig. 3) that shows the Cathode Ray Experiment” that Thomson used to prove that atoms included smaller particles. (.Include all text boxes a-e) Thomson believed the electrons were ______________________________________ Thomson’s model was called the ________________________________ but today we might call it the _________________ _____________________________________. In 1909 a former student of Thomson’s, Ernest Rutherford decided to test the idea that electrons are evenly distributed throughout the atom. Draw a diagram that shows Rutherford’s Gold Foil Experiment. Label What did Rutherford discover about the Most of the particles ____________________ _______________________________________ 9 movement of the particles that he shot at the gold foil? Due to the results of his experiment Rutherford revised the atomic theory in 1911. Using Fig. 6 and page 168 complete the statements that describe Rutherford’s revised atomic theory. But surprisingly a few particles ____________ ___________________________ and some even ________________________________ Result: Most of the positively charged particles went straight through the gold foil. Atomic Theory: Most of the matter of the atom is found in a _________________part of the atom. This is called the ___________ of the atom. It is very tiny and extremely __________. Result: Some of the positively charged particles were deflected or even bounced back. Atomic Theory: Like charges repel so the nucleus must have a _____________________. If electrons have a negative charge they could not be in a positively charged nucleus. Electrons must ______________________________________. Result: The diameter of the nucleus is 100,000 times smaller than the diameter of the entire gold atom. Atomic Theory: Atoms are mostly ______________ with a tiny, massive _________________________. In 1913, Niels Bohr studied the way that atoms react to light. What did he learn about electron movement? Can they change paths? The Modern Theory of the atom states that electrons do not travel in specific paths or orbits. Describe the region where electrons travel. Can we predict where an electron may be found? Electron clouds exist at a certain Energy Level. 10 Therefore the energy that an electron has is based on what? 1. Draw representatives of the atomic model and explain them for each of the following Dalton Thompson Rutherford Bohr Worksheet: Boyle’s Law and Charles’s Law CHEMISTRY: A Study of Matter 1. Boyle’s Law: When _ proportional. _ is held constant, the pressure and volume of a gas are 2. Mathematically, Boyle’s law is stated PV = _ or P1V1 = . 3. At a pressure of 405 kPa, the volume of a gas is 6.00 cm3. Assuming the temperature remains constant, at what pressure will the new volume be 4.00 cm3? 4. A volume of gas at 1.10 atm was measured at 326 cm3. What will be the volume if the pressure is adjusted to 1.90 atm? 5. If 36.5 m3 of a gas are collected at a pressure of 755 mm Hg, what volume will the gas occupy if the pressure is changed to 632 mm Hg? 11 7. Mathematically, Charles’s Law is stated: V/T = ________or V1/T1 = ____________________ 8. The ___________________ temperature scale must be used in all gas law problems. 9. At 189 K, a sample of gas has a volume of 32.0 cm3. What volume does the gas occupy at 242 K? 10. 10. The gas in a balloon occupies 2.25 L at 298 K. At what temperature will theballoon expand to 3.50 L? 11. A sample of gas has a volume of 852 mL at 25°C. What Celsius temperature is necessary for the gas to have a volume of 945 mL? 12 13 14 15 16 17 18 History of the Atom Worksheet John Dalton (1766 – 1844): John Dalton was an English chemist. His ideas form the atomic theory of matter. Here are his ideas. All elements are composed (made up) of atoms. It is impossible to divide or destroy an atom. All atoms of the same elements are alike. (One atom of oxygen is like another atom of oxygen.) Atoms of different elements are different. (An atom of oxygen is different from an atom of hydrogen.) Atoms of different elements combine to form a compound. These atoms have to be in definite whole number ratios. For example, water is a compound made up of 2 atoms of hydrogen and 1 atom of oxygen (a ratio of 2:1). Three atoms of hydrogen and 2 atoms of oxygen cannot combine to make water. 1. What is the name of John Dalton’s theory? _____________________________________ 2. What are elements made of? ________________________________________________ 3. An atom of hydrogen and an atom of carbon are _________________________________. 4. What are compounds made of? _______________________________________________ 5. The ratio of atoms in HCl is: a) 1:3 b) 2:1 c) 1:1 J. J. Thompson (Late 1800s): J. J. Thompson was an English scientist. He discovered the electron when he was experimenting with gas discharge tubes. He noticed a movement in a tube. He called the movement cathode rays. The rays moved from the negative end of the tube to the positive end. He realized that the rays were made of negatively charged particles – electrons. 1. What did J.J. Thompson discover? _____________________________________________ 2. What is the charge of an electron? ____________________________________________ 3. What are cathode rays made of? ______________________________________________ 19 4. Why do electrons move from the negative end of the tube to the positive end? ________________________________________________________________ __________ 5. What was Thompson working with when he discovered the cathode rays? ________________________________________________________________ __________ Lord Ernest Rutherford (1871 – 1937): Ernest Rutherford conducted a famous experiment called the gold foil experiment. He used a thin sheet of gold foil. He also used special equipment to shoot alpha particles (positively charged particles) at the gold foil. Most particles passed straight through the foil like the foil was not there. Some particles went straight back or were deflected (went in another direction) as if they had hit something. The experiment shows: Atoms are made of a small positive nucleus; positive nucleus repels (pushes away) positive alpha particles Atoms are mostly empty space 1. What is the charge of an alpha particle? _______________________________________ 2. Why is Rutherford’s experiment called the gold foil experiment? _____________________ ________________________________________________________________ __________ 3. How did he know that an atom was mostly empty space? __________________________ ________________________________________________________________ __________ 4. What happened to the alpha particles as they hit the gold foil? _____________________ ________________________________________________________________ __________ 5. How did he know that the nucleus was positively charged? _________________________ ________________________________________________________________ __________ 20 Niels Bohr (Early 1900s): Niels Bohr was a Danish physicist. He proposed a model of the atom that is similar to the model of the solar system. The electrons go around the nucleus like planets orbit around the sun. All electrons have their energy levels – a certain distance from the nucleus. Each energy level can hold a certain number of electrons. Level 1 can hold 2 electrons, Level 2 - 8 electrons, Level 3 - 18 electrons, and level 4 – 32 electrons. The energy of electrons goes up from level 1 to other levels. When electrons release (lose) energy they go down a level. When electrons absorb (gain) energy, they go to a higher level. 1. Why could Bohr’s model be called a planetary model of the atom? __________________ ________________________________________________________________ __________ 2. How do electrons in the same atom differ? _____________________________________ ________________________________________________________________ __________ 3. How many electrons can the fourth energy level hold? ____________________________ 4. Would an electron have to absorb or release energy to jump from the second energy level to the third energy level? _____________________________________________________ 5. For an electron to fall from the third energy level to the second energy level, it must ___________________________________ energy. 21