equations Synthesis/Direct Combination A + B AB 2 elements combine to form a single compound Decomposition AB A + B Single compound is broken down Single Replacement A + BX AX + B An uncombined element replaces and element that is part of a compound Double Replacement AX + BY AY + BX 2 atoms or ions from 2 different compounds switch places with each other Identify the following equations: 3Mg + N2 Mg3N2 2K + 2 H2O 2KOH + H2 NH4OH NH3 + H2O 3KOH + FeCl3 3KCl + Fe(OH)3 Complete the following: CuS _____________ + _____________ Br + Ag ____________ Na + KOH _________ + _____________ K2(CO3) + Ca(OH)2 _________ + _________ Equations/Reaction Type lab activity SYNTHESIS _______________ _______________ Equations/Reaction Type lab activity DECOMPOSITION _______________ _______________ Equations/Reaction Type lab activity SINGLE REPLACEMENT _______________ _______________ Equations/Reaction Type lab activity DOUBLE REPLACEMENT _______________ _______________ Balancing Equations The Law of Conservation of Matter states that “matter cannot be created nor destroyed”. Therefore, in a balanced chemical equation, the number of atoms of each element in the reactants MUST EQUAL the number of atoms of each element in the products! CAUTION!!!! When balancing equations, you can only add or change coefficients (the big number in front of a formula)! Never change the subscripts of a balanced formula!!! AIM “Atom Inventory Method” A strategy to help you determine the coefficients needed to balance a chemical equation. Remember to change your inventory every time you add a coefficient! AIM Metal Nonmetal C H O N2 + H2 NH3 CH4 + O2 CO2 + H2O HCl + Fe2O3 FeCl3 + H2O 2C8H18 + O2 CO2 + H2O Ca(OH)2 + H3PO4 Ca3(PO4)2 + H2O Cu + H2SO4 Cu(SO4) + H2O + SO2 SiO2 + C SiC + CO (NH)3(PO4) + Ba(NO3)2 Ba3(PO4)2+ (NH4)(NO3) (IP1) ____Mg + _____O2 _____MgO (IP2) ____H2 + _____O2 _____H2O (IP3) ___Cl2 +____KBr ____KCl +____Br2 (IP4) __Al2(SO4)3 + __ZnCl2 __AlCl3 +__ZnSO4 (IP5) ___C3H8 + ____O2 ___CO2 + ___H2O Writing Balanced Equations: 1.) IDENTIFY or NAME each REACTANT & PRODUCT 2.)write CORRECTLY BALANCED FORMULAS for each reactant and product 3.) adjust the COEFFICIENTS in the equation, using AIM to have the same number of atoms of each element on each side 2. iron + chlorine iron (III) chloride 3. magnesium + nitrogen magnesium nitride 6. nitrogen + oxygen nitrogen (V) oxide 8. potassium chlorate potassium chloride + oxygen 1. hydrogen chloride + calcium hydroxide calcium chloride + water 4. silver nitrate+ aluminum chloride silver chloride + aluminum nitrate 7. Iron(III)chloride+ sodium phosphate iron(III)phosphate + sodium chloride 5. potassium phosphate+ calcium nitrate ___________ + _____________ Key to 9-16: 9. Ba(OH)2 + 2HCl BaCl2 + 2H(OH) 10. 2Al + 3Br2 2AlBr3 11. Zn + 2HCl ZnCl2 + H2 12. (NH4)(OH) NH3 + H(OH) 13. 2Al2O3 4Al + 3O2 14. 2K + 2H(OH) 2 K(OH) + H2 15. 3Ba + N2 Ba3N2 16. SnCl4 + 2(NH4)2S SnS2 + 4(NH4)Cl Predicting if a SR rxn will Occur: a single replacement rxn WILL OCCUR if the free metal is higher on ref. table J than the combined metal Which SR rxn will occur? Ca + Zn(NO3)2 Ca(NO3)2 + Zn Ca + KNO3 Ca(NO3)2 + 2K Predicting if a DR rxn will Occur: a double replacement rxn WILL OCCUR if the rxn 1.) forms a gas Na2S(aq) + 2HCl(aq) H2S(g) + 2NaCl(aq) 2.) forms water (1 molecule not both ionic) NaOH(aq) + HCl(aq) NaCl(aq) + H2O(l) 3.) forms a precipitate (Table F): form a solid AgNO3(aq) + NaCl(aq) AgCl(s) + NaNO3(aq) Which DR rxn will occur? KCl(aq) + AgNO3(aq) AgCl + KNO3 KCl(aq) + NaNO3(aq) NaCl + KNO3 Use reference table F to predict of the following double replacement rxns will produce a ppt (occur): Use reference table F to predict of the following double replacement rxns will produce a ppt (occur): Rxns hmwk: RB p. 40 #45, 48, 49-52, 54-59 45.) 3F2 + 2Ar 2ArF3 48.) 2Ni + O2 2NiO 49.) 2H2O 2H2 + O2 50.) 2Al2O3 4Al + 3O2 51.) 2NaCl 2Na + Cl2 52.) 2NH3 N2 + 3H2 54.) yes 55.) no 56.) yes 57.) yes 58.) yes 59.) a. SR b. D c. S d. DR e. S f. SR g. DR h. SR i. DR j. DR Writing Equations II: Determining Products 1. Aluminum reacts with magnesium sulfate oxidation state of Mg:_____ oxidation state of Al: _____ oxidation state of (SO4) ion:_______ Writing Equations II: Determining Products 2. Calcium chloride reacts with aluminum hydroxide oxidation state of Ca:_____ oxidation state of Al: _____ oxidation state of (SO4) ion:_______ oxidation state of (OH) ion:_______ Writing Equations II: Determining Products 3. Potassium oxide reacts with flourine gas oxidation state of K:_____ oxidation state of F: _____ oxidation state of O:_______ Writing Equations II: Determining Products 4. Calcium reacts with hydrogen phosphate oxidation state of Ca:_____ oxidation state of H: _____ oxidation state of (PO4) ion:_______ Writing Equations II: Determining Products 5. copper(I) sulfate reacts with barium chloride oxidation state of Copper (I):_____ oxidation state of Ba: _____ oxidation state of (SO4) ion:_______ oxidation state of Cl ion:_______ Writing Equations II: Determining Products 6. Potassium thiocyanate reacts with iron(III) sulfate oxidation state of K:_____ oxidation state of iron (III): _____ oxidation state of (SO4) ion:_______ oxidation state of thiosulfate ion:_______ Writing Equations III: Identification