Chemistry Final Exam Review and Practice Chapters Covered – ESSENTIALLY CUMMULATIVE – List of Chapters: CP: . 4, 5, 7, 8, 14, 15, 18, 19 H: 5, 6, 7, 8, 12, 14, 18 Topics to Expect: Periodic Table: s, p, d, f blocks Metal, Metalloid, Non –metal, etc. Electron Configuration: Electron Configuration: Orbitals and SubLevels Atomic #, mass, core notation Valence Electrons Periodic Trends: Bonding: Covalent and Ionic Lewis dot diagrams Bonding: Electronegativity Solutions: solubility curves Acid and Bases and pH Chemical and Physical Properties Atomic Radii, Electronegativity, Ionic Radii, Ions /Compounds Family names Bonding : molecular shapes, intermolecular forces to determine if nonpolar covalent or polar covalent, both bond and molecules. Atomic Sturcture and Electron Configuration Location of electrons in s, p, d, f orbitals. Shape and number of s and p orbitals. Number of electrons each orbital each sublevel and each level can hold. Location of s, p, d, f blocks on periodic table. Lewis dot diagrams. Formation of complete octets by transfer of / sharing of electrons. Electron Configuration & Periodic Table Filling orbital diagrams Writing electron configurations Core notation using chemical symbol of preceding noble gas Trends for physical and chemical properties Atomic radii, ionization energy, electronegativity Bonding Ionic versus covalent Valence electrons and dot diagrams Lewis structures: shared pairs and lone pairs Stability of “octet” electron arrangement of noble gases Molecular Shapes and Polarity Recognize drawings of ball and stick models Use VSEPR Recognize dipole as electrons being pulled towards the higher electronegative element, causing a partial negative charge on that atom and a partial positive charge on the lower electronegative atom Dispersion, dipole-dipole, hydrogen bonding: types of intermolecular forces in covalent compounds Solutions Solubility Curves Vocabulary – Saturated, Unsaturated, Supersaturated – Solute, Solvent, Solution, etc. Molarity definition and calculation Acids, Bases and pH Acid and base characteristic Vocabulary: – Ka, dissociation, electrolyte,amphoteric neutralization reaction and products Self Ionization of Water and pH – Defintion / math formula – Calculation from molarity #1 What is the maximum number of electrons that can by held in an “s” sublevel? A. B. C. D. 1 2 6 8 #2 What is the maximum # of e- that can by held in a “p” sublevel? A. B. C. D. 1 2 6 8 #3 What is the total number of sublevel for n=2? A. B. C. D. 1 2 6 8 #4 For an element whose electron configuration is [Ne]3s23p3, how many dots would the Lewis dot diagram have? A. B. C. D. 3 5 8 13 How many dots does the Lewis dot diagram for chlorine have? #5 A. B. C. D. 3 5 7 8 #6 A positive lithium ion is formed when a neutral lithium atom: A. B. C. D. gains one proton gains one electron loses one proton loses one electron #7 When a potassium atom becomes an ion, it: A. B. C. D. gains one proton gains one electron loses one proton loses one electron When a calcium atom becomes an ion, it: #8 A. B. C. D. gains two protons gains two electrons loses two protons loses two electrons #9 Use the periodic table to locate K; what block is it in? a. b. c. d. s-block p-block d-block f-block #10 What does 1 [Ar]4s represent? a. the full electron configuration of K b. the abbreviated electron configuration for K c. the full mass designation for K d. the block designation for K #11 What does Ar represent in [Ar]4s1? a. the block of the periodic table b. the highest orbital filled c. the chemical symbol of the preceding noble gas d. the chemical symbol of the element #12 What kind of bond is predicted to form between B and H if their electronegativities are 2.0 and 2.2 respectively? a. b. c. d. nonpolar covalent polar covalent ionic intermolecular #13 A bond is nonpolar covalent if the difference in electronegativities between the two atoms is: A. B. C. D. 2.1 or more between 0.5 and 2.1 less than 0.4 less than zero #14 Which of the following bonds would be considered completely nonpolar? A. B. C. D. H-N O-O O-C F-Cl #15 For the diatomic molecule Cl2, how many electron(s) does each chlorine share with the other chlorine? A. B. C. D. 1 2 7 8 #16 How many pairs of shared and unshared electrons does the Lewis dot structure for water have? A. B. C. D. 4, 0 3, 1 2, 2 4, 4 #17 In a double bond between two atoms, the number of shared electrons is: A. B. C. D. 2 4 6 8 #18 In the compound ammonia, NH3: A. Each hydrogen has a partial negative charge B. The nitrogen has a full positive charge C. The N-H bond is ionic D. The Lewis structure will have one unshared pair of electrons #19 What kind of compound would form between nonmetallic atoms and non metallic atoms? A. Nonpolar covalent B. Polar covalent C. Ionic D. Covalent #20 What kind of compound would form between polyatomic ions and metallic ions? A. Nonpolar covalent B. Polar covalent C. Ionic D. Covalent #21 What kind of compound would form between metallic ions and nonmetallic ions? A. B. C. D. Nonpolar covalent Polar covalent Ionic Covalent #22 What kind of compound would form between potassium and bromine?: A. B. C. D. Nonpolar covalent Polar covalent Ionic Macromolecular covalent #23 Predict the physical state of the compound formed between magnesium and oxygen: A. B. C. D. Probably a gas Probably a liquid Probably a solid Impossible to determine from the given data #24 The physical state of nearly all ionic compounds at room temperature is: A. Solid B. liquid C. Gas D. Different for each ionic compound #25 Ionic Compounds are generally: A. Conductors of electricity in the solid state B. Gases at room temperature C. Formed when a metal transfers its valence electron to a nonmetal D. Electrically charged #26 How does a covalent bond differ from an ionic bond? A. Ionic: transfer of e-; covalent: sharing of e B. Ionic: involves 2 e-; covalent: involves 4 e C. Ionic: btw metals; covalent btw nonmetals D: Ionic: usually acids; covalent: usually bases #27 Which theory is used to account for the shape of molecules? A. theory of relativity B. thermodynamic theory C. kinetic theory D. VSEPR theory #28 Which of the following does a ball and stick model reveal about chemical bonds? A. their arrangement in space B. their presence and type C. both A and B D. neither A or B #29 What shape does an ammonia , NH3, molecule have? A. pyramidal B. trigonal planar C. tetrahedral D. bent #30 What shape does a water molecule have? A. pyramidal B. trigonal planar C. tetrahedral D. bent #31 In a molecule of carbon dioxide, what kind of bonds connect the carbon atom to the 2 oxygen atoms? A. two single bonds B. one single and one double bond C. one double and one triple bond D. two double bonds #32 What shape is a carbon dioxide molecule? A. linear B. bent C. trigonal planar D. pyramidal #33 What shape is a methane, CH4 molecule? A. tetrahedral B. bent C. trigonal planar D. pyramidal #34 What is the bond angle of a molecule of ammonia , NH3? A. B. C. D. 107o 109.5o 120o 180o #35 What is the bond angle of a molecule of carbon dioxide? A. B. C. D. 107o 109.5o 120o 180o #36 What is the bond angle of a molecule of methane? A. B. C. D. 107o 109.5o 120o 180o #37 What is the bond angle of a molecule of water? A. B. C. D 90o 105o 107o 109.5o Which of the following properties would you expect to find in a small nonpolar molecule? #38 A. B. C. D Gas at room temperature Solid at room temperature Very high melting point Very high boiling point In a pyramidal molecule, how many unshared pairs of valence electrons does the central atom have? #39 A. B. C. D. None One Two Three In a tetrahedral molecule, how many unshared pairs of valence electrons does the central atom have? #40 A. B. C. D. None One Two Three #41 In polar bonds electrons are: A. B. C. D. Shared unequally Shared equally Completely transfered Not shared at all #42 Dipoles are: A. B. C. D. Nonpolar bonds Polar bonds Nonpolar molecules Polar molecules #43 What determines the polarity of a bond? A. B. C. D. Electronegativity difference only Molecular shape only Both A and B Neither A and B #44 What determines the polarity of a molecule? A. B. C. D. Electronegativity difference only Molecular shape only Both A and B Neither A and B #45 How are the electrons shared in a bond between carbon & oxygen? A. B. C. D. They are shared equally Carbon attracts them more Oxygen attracts them more Electrons are completely transferred #46 All solutions have the following properties except that the: A. Dissolved particles are very small B. Particles in a solution are evenly distributed C. Solution particles do not settle out D. Final physical state of a solution is a liquid Which of the following statements applies to the dissolved solute particles in a solution? #47 A. B. C. D. They can be seen with the unaided eye They will be in the same phase as the solvent They will settle out when left standing There is always less solute than solvent #48 An alloy is an example of a: A. B. C. D. Gaseous mixture Liquid solution Solid solution Solid mixture #49 Solutions with water as the solvent are called: A. B. C. D. Liquids Miscible solutions Aqueous solutions Electrolytes #50 Molarity is expressed as: A. B. C. D. Moles of solvent / Liters of solute Moles of solute / Liters of solvent Moles of solute / Liters of solution Moles of solute / moles of solution A solution that contains as much solute as can possibly be dissolved under existing conditions is said to be: #51 A. B. C. D. saturated supersaturated soluble concentrated #52 Which of the following is NOT an important factor influencing solubility? A. B. C. D. Chemical nature of solute Temperature Chemical nature of solvent Volume of solution #53 Common nonpolar solvents include all of the following except: A. B. C. D. Salt water Carbon tetrachloride Hexane Vegetable oil #54 Ionic solids best dissolve in liquid solvents that are: A. B. C. D. polar nonpolar viscous transparent #55 Which of the following’s solubility is most affected by pressure? A. B. C. D. Ionic solids Supersaturated solutions Gases Alloys #56 Why can water dissolve NaCl, whereas hexane cannot? A. Hexane is attracted to the sodium, but not to the chlorine B. As a polar solvent, water is attracted to both anions and cations C. Both water and salt are inorganic, while hexane is organic D. Water can form hydrogen bonds with NaCl #57 The rate at which a solid can be dissolved in a liquid solvent can be increased by: A. B. C. D. Lowering the temperature of the solvent Grinding the solute into smaller pieces Increasing the air pressure on the liquid Lowering the temperature of the solute #58 To identify the strongest acid, compare the Ka and: A. B. C. D. The highest Ka value is the strongest acid The lowest Ka value is the strongest acid The Ka closest to pH 7 is the strongest acid The Ka closest to pH 0 is the strongest acid #59 Substances that change color when added to acids or bases are called: A. indicators B. electrolytes C. insulaotrs D. capacitators #60 The ionic compound formed in acid-base neutralization reactions is: A. water B. a salt C. hydride D. hydroxide #61 A substance that can act as either an acid or a base is described as: A. neutral B. ambidextrous C. conjugate D. amphoteric #62 Which of the following is least able to donate a proton? A. HF B. H2O C. HCO3 D. F #63 Which of the following could be a conjugate acid-base pair? A. strong acid –strong base B. weak acid - weak base C. strong acid – weak base D. need more information #64 The acid dissociation constant, Ka, measures an acid’s: A. concentration B. strength C. number of protons D. degree of sourness #65 HNO3 reacts with magnesium metal to give off the gas: A. oxygen B. nitrogen C. hydrogen D. no gas is given off #66 HNO3 turns litmus paper: A. blue B. red C. no color change D. green #67 What is the pH of 0.00100M HCl? A. B. C. D. 3 2 1.3 4 #68 What affect does increasing the pH by 2 have on the hydronium ion concentration? A. B. C. D. Doubles it Halves it Increases by power of 2 (100 times more) Decreases by power of 2 (100 times less) #69 What is the pH of an acid if the hydronium ion concentration is 1 x 10-4 M? A. B. C. D. 1 4 10 10000 #70 Determine the pH of a 0.00100M NaOH solution. A. B. C. D. 3 4 11 14 #71 Pure water contains which of the following species? A. H2O molecules B. H3O+ ions C. OH- ions D. all of these #72 Determine the hydroxide ion concentration of a solution with a pH of 13. A. 1.0 x 10-13 B. 13 C. 1 D. 1.0 x 10-1 #73 The definition of pH is: A. –log[H3O+] B. the percent of hydronium ions C. the parts per million of hydronium ions D. log[OH-] #74 Two common ways to measure pH are: A. with indicators and thermometers B. with indicators and a pH meter C. by taste and color D. by electric conductivity and by temperature #75 The equivalence point of a strong acid-strong base titration curve is: A. at a pH of 7 B. at the steepest part of the curve C. when the solution is neutral D. all of the above Chemistry Final Exam Good Luck! Read CHAPTER SUMMARIES Complete the review package.