4.3 APPLICATION EXAMPLE FOR MOLES Gas Behavior How does the behavior of gases affect airbags? What is pressure? Pressure – Force of gas particles running into a surface Pressure and Number of Molecules If pressure is molecular collisions with the container… As number of molecules increases, there are more molecules to collide with the wall Collisions between molecules and the wall increase As # of molecules increases, pressure increases Pressure increases Pressure and Volume If pressure is molecular collisions with the container… As volume increases, molecules can travel farther before hitting the wall Collisions between molecules and the wall decrease As volume increases, pressure decreases Pressure decreases Section 4.3—Counting Molecules So the number of molecules affects pressure of an airbag…how do we “count” molecules? How do auto makers utilize enough atoms of gas to create pressure that inflates the bag, But not so many that the pressure is too great when it hits you and your face that it causes permanent damage Count the atoms What is a mole? Definition Mole – SI unit for counting The only acceptable abbreviation for “mole” is “mol”…not “m”!! What is a counting unit? You’re already familiar with one counting unit…a “dozen” A dozen = 12 “Dozen” 12 A dozen doughnuts 12 doughnuts A dozen books 12 books A dozen cars 12 cars A dozen people 12 people What does a “mole” count in? A mole = 6.02 1023 (called Avogadro’s number) 6.02 1023 = 602,000,000,000,000,000,000,000 “mole” 6.02 1023 1 mole of doughnuts 6.02 1023 doughnuts 1 mole of atoms 6.02 1023 atoms 1 mole of molecules 6.02 1023 molecules This means a 12 ounce bottle of water would have 19.7 “moles” of water…a much easier-to-work-with number! Molar Mass Definition Molar Mass – The mass for one mole of an atom or molecule. Other terms commonly used for the same meaning: Molecular Weight Molecular Mass Formula Weight Formula Mass Mass for 1 mole of atoms The average atomic mass = grams for 1 mole Average atomic mass is found on the periodic table Element Mass 1 mole of carbon atoms 12.01 g 1 mole of oxygen atoms 16.00 g 1 mole of hydrogen atoms 1.01 g Unit for molar mass: g/mole or g/mol Molar mass for molecules The molar mass for a molecule = the sum of the molar masses of all the atoms Calculating a Molecule’s Mass To find the molar mass of a molecule: 1 Count the number of each type of atom 2 Find the molar mass of each atom on the periodic table 3 Multiple the # of atoms molar mass for each atom 4 Find the sum of all the masses Example: Molar Mass Example: Find the molar mass for CaBr2 Example: Molar Mass 1 Example: Find the molar mass for CaBr2 Count the number of each type of atom Ca 1 Br 2 Example: Molar Mass 2 Example: Find the molar mass for CaBr2 Find the molar mass of each atom on the periodic table Ca 1 40.08 g/mole Br 2 79.91 g/mole Example: Molar Mass 3 Example: Find the molar mass for CaBr2 Multiple the # of atoms molar mass for each atom Ca 1 40.08 g/mole = 40.08 g/mole Br 2 79.91 g/mole = 159.82 g/mole Example: Molar Mass 4 Example: Find the molar mass for CaBr2 Find the sum of all the masses Ca 1 40.08 g/mole = 40.08 g/mole Br 2 79.91 g/mole = + 159.82 g/mole 199.90 g/mole 1 mole of CaBr2 molecules would have a mass of 199.90 g Example: Molar Mass & Parenthesis Be sure to distribute the subscript outside the parenthesis to each element inside the parenthesis. Example: Find the molar mass for Sr(NO3)2 Example: Molar Mass & Parenthesis Be sure to distribute the subscript outside the parenthesis to each element inside the parenthesis. Example: Find the molar mass for Sr(NO3)2 Sr 1 87.62 g/mole = 87.62 g/mole N 2 14.01 g/mole = 28.02 g/mole O 6 16.00 g/mole = + 96.00 g/mole 211.64 g/mole 1 mole of Sr(NO3)2 molecules would have a mass of 211.64 g Let’s Practice #2 Example: Find the molar mass for Al(OH)3 Let’s Practice #2 Be sure to distribute the subscript outside the parenthesis to each element inside the parenthesis. Example: Find the molar mass for Al(OH)3 Al 1 26.98 g/mole = 26.98 g/mole O 3 16.00 g/mole = 48.00 g/mole H 3 1.01 g/mole = + 3.03 g/mole 78.01 g/mole 1 mole of Al(OH)3 molecules would have a mass of 78.01 g Using Molar Mass in Conversions Example: Moles to Grams Example: How many grams are in 1.25 moles of water? Example: Moles to Grams When converting between grams and moles, the molar mass is needed Example: How many grams are in 1.25 moles of water? 1.25 mol H2O H 2 1.01 g/mole = 2.02 g/mole O 1 16.00 g/mole = + 16.00 g/mole 18.02 g/mole 1 mole H2O molecules = 18.02 g 18.02 g H2O 1 mol H2O 22.53 g H2O = _______ Let’s Practice #3 Example: How many moles are in 25.5 g NaCl? Let’s Practice #3 Na 1 22.99 g/mole = 22.99 g/mole Cl 1 35.45 g/mole = + 35.45 g/mole 58.44 g/mole Example: How many moles are in 25.5 g NaCl? 25.5 g NaCl 1 mole NaCl molecules = 58.44 g 1 mole NaCl 58.44 g NaCl 0.44 = _______ mole NaCl Let’s Practice #4 Example: How many grams is a sample of 2.75 × 1024 molecules of SrCl2? Let’s Practice #4 Example: How many grams is a sample of 2.75 × 1024 molecules of SrCl2? 2.75 × 1024 molecules SrCl2 Sr 1 87.62 g/mole = 87.62 g/mole Cl 2 35.45 g/mole = + 70.90 g/mole 158.52 g/mole 1 moles SrCl2 molecules = 158.52 g 1 mol = 6.021023 molecules 1 mol SrCl2 6.02 × 1023 molecules SrCl2 158.52 g SrCl2 1 mol SrCl2 7.24 = _________ g SrCl2 Example: Grams to Molecules Example: How many molecules are in 25.5 g NaCl? Example: Grams to Molecules Example: How many molecules are in 25.5 g NaCl? Na 1 22.99 g/mole = 22.99 g/mole Cl 1 35.45 g/mole = + 35.45 g/mole 58.44 g/mole 1 moles NaCl molecules = 58.44 g 1 mol = 6.021023 molecules 25.5 g NaCl 1 mol NaCl 58.44 g NaCl 6.021023 molecules NaCl 1 mol NaCl 2.63 1023 molecules NaCl = _________