Ch. 20 Notes -- Acids and Bases What makes something an acid? Acid Properties: sour lemons (1) tastes _______-_______________ metals (2) corrosive to _________ H+ ] (or [ _____ H3O+ ] = “_______________” hydronium (3) contains [ ___ ions) (4) proton ([ ___ Brønsted-Lowry Theory H+ ]) __________-donor Example: HCl + H2O ______ Cl− + H O 3 + ______ Properties of Bases What make something a base? Base Properties: (…the opposite of acid properties) bitter -- ___________ banana peel , (1) tastes ________ parsley, dark chocolate (2) feels _____________ slippery -- ________ soap OH− ] ions (3) contains [ _____ acceptor (4) proton ([H+]) ______________-Brønsted-Lowry Theory NH4+ + _______ OH− Example: NH3 + H2O ______ pH of food Content Goal: Students will test pH to determine if household substances are an acid or a base. Language Goal: Students will show they know the material by filling out the paper that will be completed in class today Social Goal: Students will work together safely and will follow instructions so that everyone has equal access to lab materials. Safety No play fighting or any touching. Move around the room in numerical order. Please keep the beakers on the table. Do not move the beakers to you, move to the beakers. Place used test strips into the waste beaker. Wash your hands after the lab. Common Acids Examples of Common Acids: • citrus juices, ___________, aspirin Pepsi, _________ stomach acid, battery acid, _____________, vinegar ______ DNA • Common Bases Examples of Common Bases: milk of magnesia, ___________, ammonia antacid baking drain cleaner, soap, blood, ____________ tablets, ___________ ________. soda • Indicators An indicator is a chemical that will change ___________ colors when placed in an acidic, basic or neutral environment. Indicator Colors For Acids • • • • red litmus paper = _______ clear phenolphthalein = ___________ red cabbage juice (universal indicator) = ________ red methyl orange = _______ red • • • • Indicator Colors for Bases litmus paper = _______ blue yellow methyl orange = ____________ blue red cabbage juice (universal indicator) =________ phenolphthalein = ______ pink phenolphthalein Acid Base Universal pH Paper : Indicator Colors Neutral Acidic Basic • Acid Vocabulary strong acid - readily ___________ dissociates to produce ______ many [H+] ions in water H2SO4 Examples: _________, HCl HNO3, _______ • small weak acid - produces a __________ amount of [H+] ions when in water H2CO3 lemon juice Examples: HC H O (vinegar) , _________, _________ 2 3 2 • Base Vocabulary strong base- readily __________ dissociate to produce ______ many [OH−] ions in water Examples: NaOH , ________ KOH • small amount of [OH−] ions when in weak base- produces a __________ water NH3 (ammonia); Mg(OH) (milk of magnesia) Examples: _____ 2 Other Vocabulary • • _______________another term for basic solutions Alkaline Amphoteric _______________a substance that can act as both an acid and a base − H O HCO 2 3 Examples: ___________ , ____________ Self-Ionization of Water • Pure water is _____________. neutral It can ionize itself to form OH− and H3O+ ions in __________ small amounts. H2O + (or • H2O H3O+ + OH− H+ OH− ) H2O _______ + _______ green The universal indicator color is ___________ in neutral solutions. self-ionization of water Measuring the Amount of H+ and OH− Ions in a Solution • • _____ pH Scale- measures the _____________ concentration of [H+] ions in a solution pOH Scale- measures the concentration of [ ____ OH− ] ions in a solution _____ Formulas pH = − (log [H+]) [H+] = 10−pH [H+] x [OH−] = 1 x 10−14 • pOH = −(log [OH−]) [OH−] = 10−pOH pH + pOH = 14 With the pH scale, we have another way to define acids and bases: below Acids have a pH _________7.0 above Bases have a pH _________7.0 = Neutral pH ___7.0 pH Testing Alkalinity Testing Practice Problems: 1) a) Calculate the pH of a 0.001 M HCl solution [H+] = 0.001 M So…pH = − (log 0.001 M) pH = 3 b) What is the pOH of this solution? pH + pOH = 14 So…14 − 3 = pOH pOH = 11 c) What is the concentration of [OH−] ions in the solution? [OH−] = 10−pOH 2) [OH−] = 10−11 Molar or 1 x 10−11 M a) Calculate the pOH of a NaOH solution that has a pH of 8.50 pH + pOH = 14 So…14 − 8.5 = pOH pOH = 5.5 b) What is the [OH−] of this solution? [OH−] = 10−pOH [OH−] = 10−5.5 Molar or 3.16 x 10−6 M c) What is the concentration of [H+] ions in the solution? [H+] = 10−pH [H+] = 10−8.5 Molar or 3.16 x 10−9 M Neutralization Reactions salt When an acid and base are mixed, the reaction produces _______ water and ___________. • • If the initial concentrations and volumes of the reactants are equal, neutral the products will be ____________... (pH= 7.0) double All neutralization reactions are ___________ replacement reactions. H2O HX + M(OH) ______ MX + ______ (“Salt”) • • • • • Titration Mixing an acid with a base to determine a __________________ concentration is called “titration.” An ____________ indicator is used to determine when neutralization has occurred. Standard ________________ Solution - the solution of known concentration End _________ Point - the point of ______ neutralization when titrating end point, the moles of At the ______ [H+] ions = moles of [OH−] ions. Determining the Concentration of an Acid (or Base) by Titration (Macid)x(Vacid) = (Mbase)x(Vbase) Practice Problems: (1) A 25 mL solution of HNO3 is neutralized by 18 mL of 1.0 M NaOH standard solution using phenolphthalein as an indicator. What is the concentration of the HNO3 solution? ( Macid ) x ( 25 mL ) = ( 1.0 M ) x ( 18 mL ) Macid = 0.72 Molar (2) How many mL of 2.0 M KOH will it take to neutralize 55 mL of a 0.76 M HCl standard solution? (0.76 M ) x ( 55 mL ) = ( 2.0 M ) x ( Vbase ) Vbase = 20.9 mL