Catalyst Fill in the table with your scores on the standards. End 72.00 71.73 71.50 Total Score (%) 71.00 70.87 70.50 70.00 69.50 69.00 Period 5 Period 2 3.62 3.6 3.6 Average Scaled Score 3.58 3.56 3.54 3.52 3.5 3.48 3.48 3.46 3.44 3.42 Period 5 Period 2 Lead Nitrate and Sodium Chloride Lecture 3.2 – Types of Chemical Reactions Today’s Learning Targets LT 3.2 – I can translate a chemical reaction into a net ionic equation that contains only the ions/molecules that participate in the chemical reaction. LT 3.3 – I can identify a reaction as being an acid-base, precipitation, oxidation/reduction, decomposition, combustion, combination, single replacement, or double replacement. LT 3.4 – I can hypothesize about the product(s) that would form from the reaction between two or more reactants and write the net ionic equation for the reaction. Furthermore, I can hypothesize when a reaction will not occur. Organization of Reactions Chemical Reactions 5 Types of Chemical Reactions 3 Types of Reaction Properties Single Replacement Reactions In a single replacement reaction one molecule substitutes itself for another in a different compound. Example: NaNO3 + Cu Na + CuNO3 Cu replaces Na in the compound! Double Replacement Reactions In a double replacement reaction, the two compounds in the reaction switch the molecule that they are bonded to. Example: NaNO3 + KBr NaBr + KNO3 Both compounds switch the ion they are bonded to! Combination Reactions Combination reactions are reactions whereby two or more substances react to produce one final product. Example: 2Mg + O2 2MgO Both compounds combine to make one! Decomposition Reaction In a decomposition reaction, one substance breaks apart into two or more new substances Example: 2NaN3 2Na + 3N2 Compound breaks down to two elements Combustion Reaction Combustion reactions are produced from burning hydrocarbons (compounds of hydrogen and carbon) in air (O2). When this is done, only water and carbon dioxide are produced. Class Example Identify the types of chemical reaction shown below: Li + F2 2LiF Table Talk Identify the types of chemical reaction shown below: C6H12O6 + 6 O2 6H2O + 6 CO2 Al + HCl AlCl3 + H2 N2 + 3H2 2 NH3 Classifying Reactions by Elements We can also classify reactions based on the types of elements/compounds and/or the reaction that proceeds. Chemical Reactions 5 Types of Reactions 3 Types of Reaction Properties Acid/Base Reactions Recall that acids are substances that donate a hydrogen ions when they are placed in water. Bases are substances that accept H+ when in solution. They usually, but not always, contain an OH- ion. Acids react with bases in a neutralization reaction whereby a salt and water are produced Strong/Weak Acids and Bases An acid or base that completely dissociates, is a strong acid/base. An acid or base that partially dissociates, is a weak acid/base. Strong Acids/Bases These must be memorized! Strong Acids HCl HBr HI HClO3 HClO4 HNO3 H2SO4 Strong Bases Group 1A hydroxides: LiOH NaOH KOH RbOH CsOH Select Group 2A hydroxides: Ca(OH)2 Sr(OH)2 Ba(OH)2 Oxidation-Reduction Reaction Oxidation-Reduction reactions (or redox reactions) are reactions that involve the transfer of electrons from one element to another element More to come on these types next week! Precipitation Reaction Many reactions results in the production of a solid compound know as a precipitate. These reactions are known as precipitation reactions. We can determine whether or not a solid will form based on a few set rules. PbNO3 reaction Solubility Rules The solubility of a compound is determined by the identity of the ions in the compound Whether or not a compound will dissolve in solution or form a solid depends on the following rules: 1. All group I and ammonium ions are soluble 2. All nitrate, acetate, and chlorate compounds are soluble 3. All binary compounds of halogens (other than F) with metals are soluble, except those of Ag, Hg (I) and Pb. 4. All sulfate containing compounds are soluble, except those of barium, strontium, calcium, lead, silver, and mercury 5. Except for rule 1, all carbonate, hydroxide, oxide, silicate, and phosphate containing compounds are insoluble 6. Sulfide containing compounds are insoluble, except for those with calcium, barium, strontium, magnesium, sodium, potassium, and NH4+ Soluble Ionic Compounds Compounds Containing Exceptions NO3- None CH3COO- None Cl- Compounds of Ag+, Hg2+, Pb2+ Br- Compounds of Ag+, Hg2+, Pb2+ I- Compounds of Ag+, Hg2+, Pb2+ SO42- Compounds of Sr2+, Ag+, Hg2+, Pb2+ Insoluble Ionic Compounds Compounds Containing Exceptions S2- Compounds of NH4+, the alkali metal cations, Ca2+, Sr2+, Ba2+ CO32- Compounds of NH4+ and the alkali metal cations. PO42- Compounds of NH4+ and the alkali metal cations. OH- Compounds of NH4+, the alkali metal cations, Ca2+, Sr2+, Ba2+ Class Example Identify the compounds that soluble and the ones that are insoluble: Na2CO3 PbSO4 Table Talk Identify the compounds that soluble and the ones that are insoluble: Co(OH)2 Ba(NO3)2 Around the World All the reactions around the room are double displacement reactions. For each reaction, write the net ionic equation that results and determine if a precipitate forms. Answers are on the back side of the sheets of paper Net Ionic Equations Lab Take notes from the board and make sure that they get transferred to your lab notebook. Lab Work Time Closing Time Read sections 3.2, 4.2 and 4.3 in textbook Formal Lab Report due Monday/Tuesday! No book problems so that you can complete your lab report, but you should memorize the solubility rules. Lab write up for Lab 5 due next Thursday/Friday