Chemical Equations and Chemical Reactions Framing Questions • What is a word equation? • What is a skeleton equation? • How do I balance an equation to show that the mass of the reactants equals the mass of the products? Writing A Chemical Equation The general format for chemical equations is: a+ b c +d What Does It All Mean? a+ b c +d The reactants go on the left side of the equation (a and b in this case). The + sign means “reacts with”. The means “produces or yields”. The products go on the right side of the equation (c and d in this case). Lets work with the statement: “Hydrogen gas reacts with oxygen gas to form liquid water” Word Equation hydrogen + oxygen water Skeleton Equation H2 + O2 H2O To balance equations numbers called coefficients are put before the formulas. This changes the number of molecules. You cannot add or change subscripts. You do not write coefficients of 1 (one). Balanced Equation ___H2 + ___O2 ___H2O 2H2 + O2 2H2O Why Must We Balance Equations? •Remember the Law of Conservation of Mass states that the total mass of reactants is always equal to the total mass of the products. •Remember Dalton’s Atomic Theory states that atoms can not be created or destroyed. Compounds are formed when atoms of different elements combine in fixed proportions. Sometimes you need to know the state of the chemicals that are involved in a chemical reaction. State solid liquid gas aqueous solution Abbreviation State Abbreviation solid (s) liquid gas aqueous solution State Abbreviation solid (s) liquid (l) gas aqueous solution State Abbreviation solid (s) liquid (l) gas (g) aqueous solution State Abbreviation solid (s) liquid (l) gas (g) aqueous solution (aq) Final Balanced Chemical Equation 2H2(g) + O2(g) 2H2O(l) Rules For Writing Balanced Chemical Equations This requires a lot of practice These rules will not apply in all equations. 1. Write the skeleton equation. 2. Look for a polyatomic ion that appears once on each side of the equation. Balance these first. 3. Pick single elements that appear on each side. Choose coefficients to balance this element. The terms you balanced in the previous step have to remain balanced. Repeat for any other elements. Rules For Writing Balanced Chemical Equations, Continued… 4. Check for any term you have not yet looked at. Adjust the coefficient of the term so that the numbers of the elements appearing in that term are balanced across the whole equation. If you have any fraction coefficients clear them by multiplying. Also, make sure you have the smallest possible coefficients by reducing. 5. Check the equation! Example 1: Word Equation sodium + water sodium hydroxide + hydrogen gas Skeletal Equation Na + H2O NaOH + H2 Balanced Equation ___Na + ___H2O ___NaOH +___H2 2Na + 2H2O 2NaOH + H2 Balanced Chemical Equation 2H2O__ 2Na__ + 2NaOH__ + H2___ 2Na(s) + 2H2O (l) 2NaOH(aq) + H2(g) Verification Reactants 2 Na atoms Products 2 Na atoms 4 H atoms 4 H atoms 2 O atoms 2 O atoms Example 2 Word Equation copper + silver nitrate copper(II) nitrate + silver Skeletal Equation ___ + ______ ______ + ___ Cu + AgNO3 Cu(NO3)2 + Ag Balanced Equation __Cu +__ AgNO3 __Cu(NO3)2 + __Ag Cu + 2AgNO3 Cu(NO3)2 + 2Ag Balanced Chemical Equation Cu__ + 2AgNO3__ Cu(NO3)2__ + 2Ag__ Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants 1 Cu atom Products Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products 1 Cu atom 1 Cu atom Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products 1 Cu atom 1 Cu atom 2 Ag atoms Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products 1 Cu atom 1 Cu atom 2 Ag atoms 2 Ag atoms Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products 1 Cu atom 1 Cu atom 2 Ag atoms 2 Ag atoms 2 NO3- ions Cu(s) + 2AgNO3(aq) Cu(NO3)2(aq) + 2Ag(s) Verification Reactants Products 1 Cu atom 1 Cu atom 2 Ag atoms 2 Ag atoms 2 NO3- ions 2 NO3- ions Example 3 Word Equation calcium nitrate + sodium hydroxide calcium hydroxide + sodium nitrate Skeletal Equation Ca(NO3)2 + NaOH Ca(OH)2 + NaNO3 Balanced Equation __Ca(NO3)2 + __NaOH __Ca(OH)2 + __NaNO3 Ca(NO3)2 + 2NaOH Ca(OH)2 + 2NaNO3 Balanced Chemical Equation Ca(NO3)2__ + 2NaOH__ Ca(OH)2__ + 2NaNO3____ Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants 1 Ca atom Products Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products 1 Ca atom 1 Ca atom Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products 1 Ca atom 1 Ca atom 2 NO3 - ions Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products 1 Ca atom 1 Ca atom - ions - ions 2 NO3 2 NO3 Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products 1 Ca atom 1 Ca atom - ions - ions 2 NO3 2 Na atoms 2 NO3 Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products 1 Ca atom 1 Ca atom 2 NO3 - ions 2 Na atoms 2 NO3 ions 2 Na atoms Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products 1 Ca atom 1 Ca atom - ions - ions 2 NO3 2 Na atoms 2 OH ions 2 NO3 2 Na atoms Ca(NO3)2(aq) + 2NaOH(aq) Ca(OH)2(s) + 2NaNO3(aq) Reactants Products 1 Ca atom 1 Ca atom - ions - ions 2 NO3 2 Na atoms 2 OH ions 2 NO3 2 Na atoms 2 OH ions Homework: P. 31 Q21 and 22