Unit 6 Plants and Fertilisers Sugars Starch, sugar and alcohol are all linked in some way, the first two are both carbohydrates, carbohydrates undergo fermentation (chemical process) to become the alcohol found in drinks (beer, wines, spirits). Plants, Sugars and Sunlight All plants make sugars in their leaves. To do this they use the energy they get from sunlight. This sugar is called GLUCOSE. The sugar that you put on your cereal and use to bake with i.e. table sugar is a sugar called SUCROSE. Some plants can convert the glucose they make into sucrose. These plants are sugar cane and sugar beet. Sugar cane Sugar beet Some plants convert the glucose into another sugar called FRUCTOSE, this is common in plants which produce fruits, hence the sugar’s name. Another type of sugar is MALTOSE which is produced in germinating cereals such as barley. This is the sugar which is used in the brewing process (i.e. the making of beer). The sugar LACTOSE is produced by animals and it is found in the milk of the animal, including human milk, hence why it is sometimes known as milk sugar. Sugar properties Properties Appearance Taste Solubility pH Conduction Glucose Sucrose Fructose Maltose Lactose Think about the results for the conductivity of sugars. What do you think the bonding in sugars is, ionic or covalent? Covalent Why do you think this? There are no ions in covalent bonding. What were the similarities and differences between the five sugars? Similarities Differences Testing with Benedict’s Solution Benedict’s solution can be used to test for some sugars. The positive test for sugars with Benedict’s is when the Benedict’s solution turns from blue to a reddish, brown colour (although dark mustard yellow and orange count as a positive result). Try the following experiment: Take five test tubes and place ½ a spatula of glucose in one test tube, ½ a spatula of sucrose in one, ½ a spatula of fructose in one, ½ a spatula of maltose in one and ½ a spatula lactose in the last tube. Label the test tubes, so the sugars do not get mixed up. Place roughly 150cm3 of hot water into a 250cm3 beaker, this is used as a water bath. Add a depth of 2cm of water in the test tubes and shake the tubes. Add 10 drops of Benedict’s to the test tubes and place them in the water bath for five minutes and record the results. Sugar Glucose Sucrose Fructose Maltose Lactose Result with Benedict’s Solution Which sugar can you NOT use Benedict’s solution to test for? Elements in Sugar All sugars contain the same elements – just in a different structure. These elements can be identified by heating the sugar. Carry out the following experiment to find out what elements are in sugars: Collect a dry test tube, tongs, Bunsen burner, sucrose and a small piece of blue cobalt chloride paper. Add one spatula of sucrose into the test tube and heat for a few seconds in a quiet blue flame. Remember and hold the tube horizontally. Move tube away from the flame when condensation is seen and test the condensation with the blue cobalt chloride paper. Place test tube back in the flame and leave the sugar until it is roasted. The cobalt chloride paper turns from blue to ___________, this occurs in the presence of ______________ which is made up of ___________ and _____________. The element that remains in the burnt black solid is________; this is the same element that is present when you burn your toast. All sugars are made up of the same three elements, as the name of the group they belong to suggests: carbohydrates. CARBO HYDR ATE carbon hydrogen oxygen Sugar Molecules Single Unit Sugars (Simple Units) Glucose and fructose are classed as simple sugars. These molecules are quite complicated to draw so it is easier simplifying the diagram by using a block to represent the main part of the molecule and only draw the atoms which take part in reactions. When using these simply diagrams, use different colours to distinguish between glucose and fructose. The chemical formula for glucose and fructose are C6H12O6. The difference between the glucose and fructose is the structure of the molecules. Double Unit Sugars Double unit sugars are formed when two single unit sugars join together: When the two single unit sugars join together to form the double unit sugar some atoms have to be lost. These atoms then join up and form a small molecule: The formula for double unit sugars: sucrose, maltose and lactose is C12H22O11. The number of carbon atoms in a double unit is 2x the number in a single unit – hence the name double! Sugar units are called saccharides by scientists. Single unit sugars can also be called a monosaccharide (mono means one). Double unit sugars can also be called disaccharides (di means two). Remember: Isomers: molecules with the same molecular formula but different structural formulas