Science 10 Review * Please make notes on your review pkg, or on a separate sheets of paper to augment the points provided * CHEMISTRY REVIEW What is Chemistry? The branch of science that deals with changes in matter. Matter and Types of Matter Each one of these groups contains elements with similar chemical and physical properties. family / group vertical column with similar chemical properties period horizontal row of elements whose properties gradually change from metallic to nonmetallic as you move from left to right Metals Metals makeup more than 75% of the elements on the periodic table. Metals are characterized by the following physical properties. 1. They are shiny ( have a high luster). 2. They are usually solids at room temperature. 3. They are malleable ( can be hammered, pounded, or pressed into different shapes without breaking). 4. They are ductile (can be drawn into thin sheets or wires without breaking). 5. They are good conductors of heat and electricity Metals can be both reactive or inert ◦ Reactive: such as sodium, which will combust into a flurry of flame when it come on contact with air. ◦ Inert: extremely un-reative, like platinum or gold Nonmetals There are 17 nonmetals in the periodic table, In general, they can be grouped together b/c they DO NOT resemble metal more than having a relationship to each other. They can be a variety of states, (although they are usually gases at room temperature). They do not have a luster. They are poor conductors of heat and electricity. They generally exist as molecules. Metalloids The metalloids are B, Si, Ge, As, Sb, Te, Po and At. The members of this group are the least uniform in character. The metalloids are NOT as good at conducting as the metals, but they are better conductors than the nonmetals. ◦ Many of them are known as semiconductors. Ion Charges 1+ 2+ 3+ Multiple charges…check the box. 3- 2- 1- Info on the periodic table Every element on the periodic table is in it’s own box. Each box has the same information in it. Atomic Theory See Atomic Theory Review in your Notes Every element is made of up of three subatomic components. ◦ Protons ◦ Neutron ◦ Electrons Protons and neutrons are in the nucleus in the middle of the element. Electrons orbit the outside .These electrons are drawn to the nucleus because of their opposite charges Atomic mass vs. Mass number Atomic mass is the mass of the whole element. You add together ALL of its components: ◦ protons + neutrons + electrons = atomic mass ◦ This gives you a number with digits in to the 10,000th place! ISOTOPES Def: Atoms with differing weights but are the same type of elements. ex carbon-12 and carbon-14). Remember: atoms always have the same number of protons. Number of Protons NEVER changes!!! Therefore isotopes have differing numbers of neutrons. ISOTOPES To make it simpler we use Mass Number. ◦ protons + neutrons = mass number ◦ Therefore… mass number – protons = neutrons mass number – protons = neutrons Ex. a) vandium-51 ◦ mass number – protons = neutrons ◦ 51 – 23 = 28 ◦ There are 28 neutrons & 23 protons in vandium. ◦ Try: nickel-58, bromine-79, argon-40, uranium-238 ◦ nickel 58: mass number – protons = neutrons 58 – 28 = 30 There are 30 neutrons & 28 protons in nickel. ◦ bromine-79: 35 protons 44 & neutrons ◦ argon-40: 18 protons & 22 neutrons ◦ uranium-238: 92 protons & 146 neutrons Ions and the Octet rule The octet rule says that atoms tend to gain, lose or share electrons so as to have eight electrons in their outer electron shell. Ex: the halogens--each chlorine is missing only one electron in their valence orbital, so they each share a valance electron from each other so the molecules to stabilize. This is why all the halogens are diatomic! Other elements do the same thing. In the case of water Oxygen needs two electrons (to move from 6 to 8 valance electrons) Each hydrogen has one too many-- Each hydrogen gives an electron to the oxygen; oxygen now has a full valance orbital The oxygen shares the electrons with hydrogen too, so it has a full orbital too. Formation of ions Ultimately, elements are lazy! Elements will do whatever is the easiest way to get a full valance orbital. There are two types of ions: ◦ Cations: give up (lose) electrons. Since they now have more protons than electrons, they have a positive charge. Formation of ions Sodium has 11 protons and 11 electron; only one electron in its valance orbital, (it is much easier for it to lose one than find seven....) This leaves it with 11 protons and only 10 electrons…thus it now has a charge of 1+ b/c there is one more proton than electron. Once the electron is gone, the orbital “disappears” Anions: pick up (gain) electrons. Since they now have more electrons than protons, they have a negative charge. e- - Chlorine has 17 protons and 17 electrons; it has seven electron in its valance orbital (it is much easier for it to gain one than find seven) This leaves it with 17 protons and 18 electrons…thus it now has a charge of 1-, because there is one more electrons than proton. Only missing 1 e- Calculating # of Electrons in Ions Note: The number of protons in an atom/ion NEVER change. # of electron in an ion = # of protons – ion charge Ex. non-metal anion (O2-): Atomic # = 8 = 8 protons # of electron = # of protons – ion charge # of electron = 8 – (-2) # of electron in an ion of oxygen is = 10 Ex. metal cation (Ca2+): Atomic # = 20 = 20 protons # of electron = # of protons – ion charge # of electron = 20 – (+2) # of electron in an ion of calcium is = 18 Maintain the – sign of the ion charge Maintain the + sign of the ion charge Lets try some! What would the following elements be as ions? Magnesium, nitrogen, selenium, iodine, potassium & oxygen Magnesium Has two in it valance orbital…easier to lose 2 than gain 6. Become Mg2+ Nitrogen Has five in it valance orbital…easier to gain 3 than lose 5. Become N3- Selenium Iodine Potassium Oxygen Bohr Diagrams Bohr Diagrams are used to diagrammatically represent elements and ions. They show the number of protons, neutrons and electrons. The number of electron orbitals is equal to the number of the row the element is in. 3rd row, 3 circles (orbitals) The number of electrons that can fill each orbital is equal to the number of elements in each row. 2, 8, 8, 18, 18, etc 1 2 3 4 5 6 7 82 The number of valance electrons is equal to the number of the column that the element is in. 3rd column, 3 valance electrons 1 2 3 To draw a Bohr Diagram Place a circle in the center to represent the nucleus. Write the symbol to represent the element in the circle. Write the number of protons & neutrons in the circle to. Al 13 p+ 14 n Draw in the correct number of orbital Recall the number of rings = column the element is in The electrons are placed on the rings 1 2 3 ◦ Recall The number of electrons that can fill each orbital is equal to the number of elements in each row ◦ AND The number of valance electrons is equal to the number of the column that the element is in. Al 13 p+ 14 n Types of compound’s Ionic: ◦ cmpds that have one metal and one non-metal ion (one positive and one negative) Ex. Na+ & Cl- make NaCl(s) Molecular: ◦ cmpds that have two non-metal ions Ex. C & O make CO2 (g) Ionic Cmpds Are a result of ionic bonds ◦ Naming: the metal is always first, the non-metal second. The non-metals name is changed to have an “ide” ending (ie. sodium chloride) Ionic bonds form between metals and non-metals, ◦ This means that there is a tight arrangement of particles in rigid pattern, which is hard to break down, giving them a high melting/ boiling temp. ◦ Conduct electricity (electrolytes) ◦ Solid at room temp Ionic Bonds In ionic bonding, valence electrons are completely transferred from one atom to another. The result? Ions! ◦ Electrically charged atoms. ◦ Cations are positively charged (Mg 2+, H+, Na+) ◦ Anions are negatively charged (O2-, Cl-) The oppositely charged ions are attracted to each other by electrostatic forces. Let's take a look! How to write Ionic Cmpds: Step 1 Write each ion with its charge Step 2 Figure out how many of each you need to make the charges balance. Ca2+ and Br – 1 Ca and 2 Br Ca2+, Br – ,Br – Step 3 Write the formula using subscripts to show how many of each atom you need AND the state Ca2+ and Br – 1 Ca and 2 Br Ca2+, Br – ,Br – CaBr2 (s) * Ionic compounds are always solid (s) Multiple charges… Polyatomic Ions These are the ions found middle area of the periodic table ◦ Elements that are already grouped together and poses a charge. Molecular Cmpds Unlike ionic compounds; a positively charged metal ion and a negatively charges non-metal ion, molecular compounds are a combination of two non-metals. ◦ Since both are negatively charged, we can not balance the formula to equal zero. Covalent bonds Covalent bonds are formed as a result of the sharing of one or more pairs of bonding electrons; (this is what hold molecular compounds together) Each atom donates half of the electrons to be shared. Where the clouds overlap they are thicker, and their electric charge is stronger. See! Covalent bonds Molecular Compounds ◦ Do not have a tight crystal structure so the melting/ boiling point is lower. ◦ Do not conduct electricity (non-electrolyte) ◦ Can be any state at room temp. Molecular cmpds Naming: The first element in the compound uses the element name. The second element in the compound has the suffix ide added to it- just like ionic compounds HOWEVER… ◦ When there is more than one of the atom in the formula, a prefix is used to specify how many of that element there is. mono- 1 hexa- 6 di- 2 hepta-7 tri- 3 octa-8 tetra- 4 nona-9 penta- 5 deca-10 ◦ Here comes the exception…when the first element has only one, no prefix is used. If the second element has only one, the prefix mono is attached. Acids: ◦ Ionic cmpds, where the metal is always hydrogen. ◦ In solution will have a pH lower than 7 ◦ React predictably with indicators like litmus paper Bases: ◦ Ionic cmpds, where the non-metal is always hydroxide (OH-). ◦ In solution will have a pH higher than 7 ◦ React predictably with indicators like litmus paper Naming Acids If the compound name ends in “ide” the name of the acid becomes hydro--ic acid. ◦ For example HCl, hydrogen chloride, become hydrochloric acid If the compound name ends in “ate” the name of the acid becomes --ic acid. ◦ For example H2SO4, hydrogen sulfate, become sulfuric acid If the compound name ends in “ite” the name of the acid becomes --ous acid. ◦ For example HClO3, hydrogen perchlorite, become perchlorous acid In general the H+ ion always goes first…unless the acid has an “organic group”; (a molecule containing COOH), then the H+ goes last. Acids are always written with an (aq) subscript. Lets try some! RULE 1: hydrogen ---ide ◦ HF(aq) Hydrogen flouride ◦ H2P(aq) Hydrogen phosphide ◦ HI (aq) Hydrogen iodide becomes hydro ---ic acid Hydroflouric acid Hydrophosphoric acid Hydroiodic acid Lets try some! RULE 2: hydrogen ---ate ◦ HClO3(aq) Hydrogen chlorate becomes ---ic acid Chloric acid ◦ H3BO3(aq) Hydrogen borate Boric acid ◦ HNO3(aq) Hydrogen nitrate Nitric acid Lets try some! RULE 3: hydrogen ---ite ◦ HNO2(aq) Hydrogen nitrite becomes ---ous acid Nitrous acid ◦ H2ClO2(aq) Hydrogen chlorite Chlorous acid ◦ H2SO3 (aq) Hydrogen sulfite Sulfurous acid