Deans Community High School Chemistry Department National 5 Homework Booklet Homework 1– Chemical Reactions 1. Write down three examples of everyday chemical reactions. 2. Write word equations for the following reactions: (a) Hydrogen joins up with oxygen to form water. (b) The reaction of sulphuric acid with calcium carbonate produces calcium sulphate, carbon dioxide and water. (c) Silver oxide breaks up when heated to form its elements. (d) Ammonium sulphate is produced by the reactions of ammonia with sulphuric acid. 3. If a substance effervesces (fizzes), is there a chemical reaction taking place? Explain your answer. 4. The first 20 elements (hydrogen to calcium) in the periodic table were all discovered before the twentieth century began. Use the data booklet (page 8) to help you answer the following questions about these elements. (a) Which two elements were known in prehistoric times? (b) Which elements were discovered in the 18th century? (c) Name three elements from your periodic table which are named after famous scientists. 5. Name two elements which are: a b c d e f g metallic non-metallic solid at room temperature liquid at room temperature gas at room temperature naturally occurring made by scientists 1 6. The elements are arranged in the Periodic Table a What is meant by a group? b What is meant by a period? c Give an example of a physical similarity of elements in group 1. d Give an example of a chemical similarity of elements in group 1. 7. Divide the following list of substances into elements and compounds. carbon, petrol, alcohol, zinc, oxygen, sugar, sodium chloride, gold, copper sulphate, nitrogen, aluminium, silver oxide 8. Explain what is meant by (a) an element (b) a compound (c) a mixture (d) a solute (e) a solvent (f) a solution 9. Name the compound which is formed when each of the following pairs of elements join up. (i) magnesium and chlorine (ii) lead and sulphur (iii) sodium and oxygen (iv) hydrogen and iodine 10. Name two possible compounds containing potassium, sulphur and oxygen. 11. (a) (b) 12. What elements are present in: (a) (b) 13. How many elements are there in compounds whose names end in “ide”. If a compounds name ends in “ite” or “ate”, what does this tell you about the number of elements in the compound and which element is always present? sulphur oxide potassium sulphate (c) (d) phosphorus chloride lithium sulphite Crude oil is a mixture of compounds. Explain clearly what is meant by this statement 2 Homework 2 – Speed of Reactions 1. List the following in order of rate of reaction, fastest first: Milk turning sour A motor car rusting Frying an egg Striking a match 2. The grid shows factors that can affect the speed of a chemical reaction. A B increase in particle size D C increase in concentration E decrease in particle size increase in temperature F decrease in concentration decrease in temperature Identify the factor responsible for the change in speed of reaction in each of the following examples. (a) Seawater corrodes iron jetties near the Equator more quickly than in northern Scandinavia. (b) Magnesium ribbon burns more slowly than magnesium powder. (c) Two scoops of biological detergent in a washing machine remove stains from clothing more quickly than using one scoop. 3. The speed of a reaction depends on the reaction conditions. Describe how each of the following affects the speed of a reaction. a) particle size of the reactants b) concentration of reactants c) temperature of reactants d) using a catalyst 4. Explain each of the following a) A log burns faster if it is chopped into small sticks b) Food is preserved longer when stored in a fridge c) Plants grow faster in a greenhouse than in the open air 5. Three experiments were set up as shown. Each experiment is carried out 3 at room temperature and the mass of magnesium is the same in each case. (a) Explain any difference that would be observed between (i) A and B (ii) A and C (b) Explain any difference that would be observed if experiment A was repeated at 50oC Homework 3 – Speed of Reactions Interpreting Graphs 1. The graph shows the volume of carbon dioxide produced in the reaction of (i) calcium carbonate powder (ii) calcium carbonate lumps with excess dilute hydrochloric acid Volume of carbon dioxide / cm3 x y Time / s a) b) 2. Which graph, X or Y, shows the results of using calcium carbonate powder? State three variables that must be kept the same when comparing the reactions 5g of magnesium ribbon was added to excess sulphuric acid and the Volume of hydrogen / cm3 4 Time / s a) b) volume of hydrogen gas evolved was measured. A graph of the result is shown below:Copy the graph and draw a line to show how the volume of hydrogen produced would compare if 5g of magnesium powder was added to the acid. Draw another line of the graph showing the volume of hydrogen produced if 2.5g of magnesium ribbon was added. Homework 4 – Atomic Structure 1. a b c d e 2. 3. What name is given to the "core" at the centre of an atom? What charge has this part of the atom? What name is given to the particles which move around outside the centre of the atom? What charge do these particles have? Explain why an atom is neutral. Name the elements with each of the following atomic numbers: (i) 23 (ii) 3 (iv) 28 (v) 17 (iii) 18 a Name the elements with each of the following electron arrangements: (i) (iii) b 2, 8, 1 2, 4 (ii) (iv) 2, 8 2, 8, 4 Which two elements will have similar chemical properties? 5 4. Copy and complete the following table: Particle Proton Neutron Electron 5. Ne N Ca A B C 6. Charge Location Copy and complete the following table: Element (b) Mass Atomic Number Mass Number Number of Protons Number of Neutrons Number of Electrons 22 7 40 4 9 14 89 Identify elements A, B, and C 6 36 Calculate the number of protons neutrons and electrons in each of the following atoms of elements. (i) 23 Na 11 (iv) 16 (ii) 35 Cl 17 (iii) 39 K 19 O 3 7. Calculate the number of protons, neutrons and electrons in each of the following ions of elements (i) 23 Na+ 11 (iv) (ii) 35 - Cl 17 (iii) 40 20 32 S216 6 Ca2+ 20 8. 9. Ne and 22 Ne are two different kinds of neon atom. (a) In what way are the neon atoms different? (b) Explain why these atoms can be regarded as atoms of the same element. Copper has a relative atomic mass of 63∙5. It contains two isotopes. 63 65 Cu Cu (a) How many neutrons are present in each of the two atoms? (b) Which of the two atoms is more common in copper? Homework 5 – Covalent Bonding 1. (a) Explain what is meant by (i) (ii) H a molecule a chemical formula (b) Write the chemical formula for each of the following substances: =H (i) (ii) H O C H H H 2. 3. H H H H Molecules are made up of non-metal elements held together by covalent bonds. Which of the following compounds will be made up of molecules? (a) (c) (e) (a) sodium chloride (b) CH3Cl hydrogen chloride (d) MgO aluminium nitrate (f) NO2 Explain what is meant by a diatomic molecule 7 (b) Which of the following elements exist as diatomic molecules? Calcium Carbon Nitrogen Aluminium Hydrogen Neon Chlorine Sulphur Magnesium Oxygen Fluorine Argon (c) Which diatomic element has a triple covalent bond between the atoms? 4. 5. Write the formula for each of the following substances. (i) sulphur trioxide (ii) phosphorus pentachloride (iii) carbon monoxide (iv) silicon tetrachloride (v) hydrogen oxide (vi) phosphorus fluoride Draw target diagrams to show how the outer electrons are arranged in each of the following elements: (i) hydrogen (iii) oxygen (ii) (iv) 8 phosphorus fluorine 6. 7. Draw lewis diagrams to show how the outer electrons form covalent bonds in each of the following molecules: (a) hydrogen (b) oxygen (c) nitrogen (d) hydrogen oxide (e) phosphorus chloride (f) carbon fluoride Explain fully what a covalent bond is. Homework 6 – Ionic Bonding 1. Why are the noble gases unreactive? 2. How do metal atoms achieve electron arrangements similar to that of noble gases? 3. How do non-metal atoms achieve electron arrangements similar to that of noble gases? 4. (a) Copy and complete the following table to show the numbers of protons and electrons in each of the following ions. Ion Number of Protons Number of Electrons 2+ Ca ClAl3+ O2Na+ 9 (b) For each of the ions in the table above write their electron arrangement and identify the noble gas with the same arrangement. 5. (a) Explain clearly what happens when (i) an atom of fluorine forms a fluoride ion. (ii) an atom of lithium forms a lithium ion. (b) What happens during the formation of an ionic bond in lithium fluoride? 6. A compound is formed from a Group 2 element and a Group 6 element. Choose two elements and show by means of a diagram what happens to the electrons in the outer shell of the atoms involved. 7. What is meant by an ionic lattice? Homework 7 Properties of Substances 1. (a) By means of a labelled diagram, show the experimental apparatus which can be used to classify substances into conductors and nonconductors. (b) Study the following list of solids. nickel, iodine, copper, magnesium, sulphur, sodium, phosphorus, scandium Arrange the solids into two columns, headed conductors and nonconductors. (c) Study the following list of liquids: petrol, copper sulphate solution, silicon tetrachloride, hexene, liquid oxygen, molten sulphur, sodium chloride solution, mercury, strontium nitrate solution, molten iron Arrange the liquids in two columns, headed conductors and nonconductors. 10 2. Study the following list of substances: glucose, sulphur, sodium bromide, paraffin wax, silicon dioxide, silver, potassium, carbon tetrachloride, potassium, nickel chloride (a) Name the substances which conduct electricity when solid. (b) (i) Name the substances which conduct electricity when in aqueous solution. (ii) Explain why the solutions you have chosen do not conduct when solid. 3. The table below shows some properties of two chlorides. Chloride M.pt. / oC B.pt. / oC XCl YCl4 801 1417 Solubility in water soluble -23 77 insoluble (i) Which of these chlorides would you expect to be covalent and which is likely to be ionic? (ii) In which group of the Periodic Table would you expect to find element X? 4. A pupil carried out experiments to investigate what happens during electrolysis of melts. Explain what is meant by electrolysis. 5. Shown below is a list of compounds and their colours. sodium chloride sodium selenate nickel sulphate white white green State the colour of (a) copper selenate (c) nickel chloride sodium sulphate copper sulphate vanadium sulphate white blue violet (b) vanadium chloride 11 the 6. A crystal of copper dichromate was placed on moist filter paper at position X. When a high voltage was applied, a blue colour moved towards the negative electrode while an orange colour moved towards the positive electrode. 250 V d.c. X (a) (i) What can be learned from this experiment about the colour and charge of the dichromate ion? (ii) Explain your answer. (b) State any safety precaution which should be observed in this experiment. 7. A pupil carried out an experiment to investigate the products of the electrolysis of nickel bromide solution. (a) Explain why a d.c supply is used for this experiment. (b) Explain what would be seen at the negative electrode. (c) Explain what would be seen at the positive electrode. (d) Write ion-electron equations for the change at each electrode. 12 8. Water in swimming pools can be purified using a chlorinating cell. Sodium chloride solution is electrolysed in the cell to produce chlorine. sodium chloride powder water from pool 9. chlorinated water to pool pump chlorinating cell (a) Why can solid sodium chloride not be electrolysed? (b) (i) (ii) At which electrode is chlorine produced? Describe what is happening in the formation of chlorine. The following table shows the properties of four substances. Property appearance solubility in water electrical conductivity melting point / o C boiling point / oC P sparkling solid Q silvery liquid R insoluble insoluble soluble soluble does not conduct conducts when solid or molten conducts when molten or in solution does not conduct 3547 -61 801 -115 4827 357 1417 59 white solid S colourless liquid For each of P, Q, R and S, explain whether the substance is likely to be a metal, an ionic compound or a covalent compound (small molecule or network). 13 Homework 8 – Writing Formulae 1. Write formula for each of the following compounds. (a) (c) (e) (g) 2. 5. hydrogen oxide carbon hydride aluminium chloride barium bromide carbon monoxide sulphur dioxide phosphorous pentachloride (b) (d) (f) silicon dioxide sulphur trioxide dinitrogen tetroxide Write formula for each of the following compounds. (a) (c) (e) (g) 4. (b) (d) (f) (h) Write formulae for each of these compounds with meaningful names. (a) (c) (e) 3. silicon bromide phosphorous iodide magnesium chloride calcium sulphide sodium bromide potassium sulphide iron (III) oxide nickel (I) sulphide (b) (d) (f) (h) calcium chloride aluminium oxide cobalt (II) chloride titanium (III) nitride Write formula for each of the following compounds containing a group ion. (a) lithium nitrate (f) sodium hydrogencarbonate (b) calcium carbonate (g) potassium (c) calcium chromate (h) magnesium (d) barium sulphate (e) aluminium hydroxide hydrogensulphite hydrogencarbonate Write formula for each of the following compounds containing both a transition metal and a group ion. (a) lead (II) carbonate (b) iron (III) sulphate (c) silver (I) chromate (d) iron (III) hydroxide 14 15 Name: ________________________ Teacher: ___________________ 16