Exam 1 Study Guide Answers Use your periodic table to determine the following information about the element Chlorine (Cl). Atomic #: 17 Average Atomic Mass: 35.453 Mass #: 35 (round the average atomic mass to a whole #) # protons: 17 (equal to the atomic #) # neutrons: 18 (equal to the mass # - atomic # or protons: 35 – 17 = 18) # electrons: 17 (equal to the atomic # as long as there isn’t a charge) What two things does the atomic # always tell you? a. # protons b. identity of the element The Mass # is equal to the number of protons + the number of neutrons. In the element symbol, 8035Br: a. The top # is the mass number (# protons + # neutrons) b. The bottom # is the atomic number (# protons, #electrons if no charge present) In the element symbol Carbon-14, the number 14 is the mass number An isotope has 15 protons, 16 neutrons, and 15 electrons. a. What is the atomic # of this isotope? 15 (atomic # = # protons) b. What is the identity of the isotope? P (P has atomic # 15) c. What is the mass # of this isotope? 31 (find the average atomic mass for for P in the periodic table and round it to the nearest whole #) d. What is the average atomic mass of all of the isotopes of this element? 30.974 (this is the decimal # in the periodic table) What part of Dalton’s atomic theory was disproved by Thomson’s experiment? Dalton thought that the atoms of an element were indivisible. When Thomson’s experiment led to the discovery of the electron, it showed that the atom could be divided into smaller particles. Dalton Thomson Rutherford Name of Atomic Model Billiard Ball Plum Pudding Nuclear Thomson Rutherford Chadwick Discovered Electron Positively charged nucleus (protons) Neutrons Thomson Rutherford Experiment Cathode Ray Tube Gold Foil Describe Thomson’s experiment: Scientists knew about cathode rays, but didn’t know what was in them. Thomson put a positively charged plate on one side of the cathode ray and a negatively charged plate on the other side of the cathode ray. The ray bent toward the positively charged plate and away from the negatively charged plate. This meant that the cathode ray must contain negatively charged particles that were attracted by the positively charged plate and repelled by the negatively charged plate. The negatively charged particles were called electrons. Describe Rutherford’s experiment: Rutherford shot alpha particles through a thin piece of gold foil. According to the current model of the atom at the time (Thomson’s Plum Pudding Model), Rutherford expected the alpha particles to go through the foil and come out on the other side. Most of the alpha particles behaved as expected, but a small number of them hit something in the atom and bounced back. This led to the conclusion that atoms must contain a small, dense, positively charged nucleus in the center of the atom. A new model of the atom was needed to incorporate this information (Rutherford’s Nuclear Model). Isotopes have the same number of protons, different numbers of neutrons and different mass numbers Ions have gained or lost one or more electrons. Cations have lost electrons and have a positive charge. Anions have gained electrons and have a negative charge. 16 O 8 16 O28 17 O 8 23 Na1+ 11 23 Na 11 Which of the above symbols are isotopes of an element? 16 O and 17 O (same element,O; same atomic # (protons) – the bottom #, 8; different 8 8 mass #’s, 16 and 17 – different because they have different numbers of neutrons making causing one to have more mass than the other) Which of the above symbols is/are ions? 23 Na1+, 16 O2- (because they have charges indicating that they have gained or lost one 11 8 or more electrons) Which of the above symbols is/are cations? 23 Na1+ (because cations have lost one or more electrons causing the atom to have 11 more positively charged protons than negatively charged electrons – this gives the overall atom a positive charge) Which of the above symbols is/are anions? 16 O2- (because anions have gained one or more electrons causing the atom to have 8 more negatively charged electrons than positively charged protons – this gives the overall atom a negative charge) How many electrons are indicated by the following symbols? Mg2+ 10 (normally Mg has 12 electrons (equal to the atomic #) – the positive charge indicates that the atom has lost electrons – the small “2” indicates that the atom has lost 2 electrons. So, 12 – 2 = 10 electrons) P3- 18 (normally P has 15 electrons (equal to the atomic #) – the negative charge indicates that the atom has gained electrons – the small “3” indicates that the atom has gained 3 electrons. So, 15 + 3 = 18 electrons) Draw the following atoms – the circles represent the nucleus. (The numbers indicate the number of dots you would draw for the atom and where you would draw them. p = protons, n = neutrons, e = electrons) 39 K 19 14 N37 19 F19 19e 10e 10e Here’s another one: 40 Ca2+ 20 18e 19p, 20n 7p, 7n 9p, 10n 20p, 20n # protons = atomic # = 19 (bottom # in the symbol) If no charge, # electrons = atomic # = 19 (bottom # in the symbol) # neutrons = mass # (top # in the symbol) – atomic # (bottom # in the symbol): 39 – 19 = 20 # protons = atomic # = 7 (bottom # in the symbol) If neg. charge, # electrons = atomic # (bottom # in the symbol) plus the # in the charge: 7 + 3 = 10 # neutrons = mass # (top # in the symbol) – atomic # (bottom # in the symbol): 14 – 7 = 7 # protons = atomic # = 9 (bottom # in the symbol) If neg. charge, # electrons = atomic # (bottom # in the symbol) plus the # in the charge: 9 + 1 = 10 # neutrons = mass # (top # in the symbol) – atomic # (bottom # in the symbol): 19 – 9 = 10 # protons = atomic # = 20 (bottom # in the symbol) If pos. charge, # electrons = atomic # (bottom # in the symbol) minus the # in the charge: 20 - 2 = 18 # neutrons = mass # (top # in the symbol) – atomic # (bottom # in the symbol): 40 – 20 = 20 What is the average atomic mass of Mg if 78.99% of Mg atoms are isotopes with a mass of 23.9850 amu, 10.00% of Mg atoms are isotopes with a mass of 24.9858 amu, and 11.01% of Mg atoms are isotopes with a mass of 25.9825 amu? Create a table to make this problem easier to work with. Isotope 1 2 3 % abundance 78.99 % 10.00 % 11.01 % mass (amu) 23.9850 24.9858 25.9825 Step 1: Change the %’s to decimals by moving the decimal 2 places to the left!!!! Isotope 1 2 3 % abundance .7899 .1000 .1101 mass (amu) 23.9850 24.9858 25.9825 Remember! You must move the decimal two places to the left – if there isn’t a number there – fill in with 0’s. Ex. 5.32% → .0532 0.72% → .0072 Step 2: Multiply the % abundance (in decimal form!) x mass for each isotope. .7899 x 23.9850 = 18.9 .1000 x 24.9858 = 2.5 .1101 x 25.9825 = 2.9 Step 3: Add together all the answers from step 2. 18.9 + 2.5 + 2.9 = 24.3 The answer is 24.3 amu What is the difference between a hypothesis and a theory? Hypothesis: A testable question Theory: Consistent evidence from many experiments