semester 1 - WordPress.com

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Bonding,
Chemical
Reactions, and
Nomenclature
Reactions in
Aqueous
Solutions
Measurements,
Units, and the
Mole
Stiochiometry
Energy and
Thermochemistry
10
10
10
10
10
20
20
20
20
20
30
30
30
30
30
40
40
40
40
40
50
50
50
50
50
Question 1 - 10
What is the name for HNO3?
Answer 1 – 10
Nitric Acid
Question 1 - 20
What type of bond represents a sea of electrons?
Answer 1 – 20
• Metallic Bonding
Question 1 - 30
The electrons in a nonpolar covalent bond are:
a)Unequally shared between atoms
b)Just exist and do not interact
c) Shared equally between atoms
Answer 1 – 30
C) Shared equally between atoms
Question 1 - 40
Balance this equation:
__ HF(aq)+__Ca(OH)2(aq) → __ H2O(aq)+__ CaF2 (aq)
Answer 1 – 40
2 HF(aq)+Ca(OH)2(aq) → 2 H2O(aq)+ CaF2 (aq)
Question 1 - 50
Name 6 polyatomic ions
Answer 1 – 50
NH4+
NO2NO3SO32OHCN-
Question 2 - 10
1. What are the products in this double
displacement reaction?
NaOH (aq) + MgCl2 (aq) → ??
2. Does a precipitate form?
Answer 2 – 10
1. 2NaOH (aq) + MgCl2(aq) → 2NaCl + Mg(OH)2
2. Yes! Mg2+(aq) + 2OH-(aq) → Mg(OH)2(s)
Question 2 - 20
What is a spectator ion?
Answer 2 – 20
• its an ion that is present in
solution but does not
participate in the reaction
Question 2 - 30
• What is the difference between a
strong base and a strong acid?
Answer 2 – 30
• Strong Acid completely
dissociates into H+ and anion in
water
• Strong Base completely
dissociates into OH and cation in
water
Question 2 - 40
• Explain how to distinguish between the
following types of reactions:
•
•
•
•
Single replacement
Double displacement (precipitation)
Synthesis
Acid-Base
Answer 2 – 40
• Single Replacement: element a + compound
BC → element B + compound AC
• Double Displacement/precipitation: a solid
forms after mixing solutions of 2 ionic
compounds
• Synthesis: 2 reactants → 1 Product
• Acid-Base: form H2O from H+ and OH- ions
Question 2 - 50
• How do you recognize the
correct chemical formula
for an ionic compound?
Answer 2 – 50
• When the (+) cation(s) combine with the (-)
anion(s) in a ratio that results in a net charge
of 0
Question 3 - 10
• How many zeros does Avogadro's Number
have?
Answer 3 – 10
• 24 zeros
– 6.02 x 10-23
Question 3 - 20
• What is the molar mass of
CO2 expressed with 3 sig
figs?
Answer 3 – 20
• 44.0 g/mol
– Carbon = 12.01 g/mol
– Oxygen = 16.00 g/mol (2x)
– Add all together = 44.01 g/mol
– 3 sig figs!
Question 3 - 30
• How many sig figs are in the
measurement 0.003540 kg?
Answer 3 – 30
• 4 sig figs
Question 3 - 40
• If the reactants areNa₂S and Cu(NO₃)₂, what
will the products be?
Answer 3 – 40
• NaNO₃ and CuS
Question 3 - 50
Determine the:
1.Empirical Formula
2.Molecular Formula
3.Percent Composition
Of a substance with the molar mass of 78 g/ mol
• Percent of C: 92.3 %
• Percent of H: 7.7 %
Answer 3 – 50
Question 4 - 10
• Stoichiometry heavily relies on _____ ratios.
Answer 4 – 10
• Mole
Question 4 - 20
• A sample contains 27.1 g of calcium
oxide. How many moles of calcium oxide are
in the sample?
Answer 4 – 20
• 0.483 mol
Question 4 - 30
• A 2.00 g sample of ammonia is mixed with
4.00 g of oxygen. Which is the limiting
reactant and how much excess reactant
remains after the reaction has stopped?
4 NH3(g) + 5 O2(g)  4 NO(g) + 6 H2O(g)
Answer 4 – 30
• Limiting Reactant:
• Excess Reactant:
Question 4 - 40
• Define limiting reactant and excess reactant.
Answer 4 – 40
• Limiting Reactant - The reactant in a chemical reaction that limits the
amount of product that can be formed. The reaction will stop when all
of the limiting reactant is consumed.
• Excess Reactant - The reactant in a chemical reaction that remains when
a reaction stops when the limiting reactant is completely consumed. The
excess reactant remains because there is nothing with which it can react.
Question 4 - 50
• 90.0 g of FeCl3 reacts with 52.0 g of H2S. What
is the limiting reactant? What is the mass of
HCl produced? What mass of excess reactant
remains after the reaction?
Answer 4 – 50
•Grams of HCL: 60.8 g
•Limiting Reactant: FeCl3
•Excess reactant: 23.6 g H2S
Question 5 - 10
• Is burning coal an exothermic or an
endothermic reaction?
Answer 5 – 10
•Exothermic; heat is
leaving the system.
Question 5 - 20
• A 450 g piece of iron (specific
heat: 0.449 J/g°C ) is heated
from 22°C to 87°C. How much
heat was necessary to cause this
change?
Answer 5 – 20
• 13,000 J
Question 5 - 30
• Which of the following is not a state function?
Distance, energy, or temperature?
Answer 5 – 30
• Distance
Question 5 - 40
• How much energy is required to heat 7.40 mL
of water from 25°C to 46°C?
Answer 5 – 40
• q = mc delta T
• q = (7.40 g) (4.184 J/gC) (21 C)
– 7.40 mL X 1g/1mL = 7.40 g water
• q = 650. J
• 7.40 mL X 1g/1mL = 7.40 g water
Question 5 - 50
• 2O3  3O2
• O2  2 O
• NO + O3  NO2 + O2
∆H = - 427 kilojoules
∆H = + 459 kilojoules
∆H = - 199 kilojoules
• Calculate the Enthalpy (∆H) for the overall
reaction:
NO + O  NO2
Answer 5 – 50
•
•
•
•
Reverse reaction 1
Reverse reaction 2
Multiply reaction 3 by 2
Add the reactions, then divide by 2
•
delta H = +427 KJ – 459 KJ – 2 (199 KJ) = -430 KJ / 2 = -215 KJ
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