Understand the difference between molar mass and formula weight ▪ Formula weight – weight of one molecule in units of amu, ▪ Molar mass – weight of one mole of molecules in grams (per mole). Know how to determine the ▪ Formula weight – in amu and in grams ▪ Molar mass – in grams o Know that these two are numerically the same but different in units Avogadro’s number and Molar Mass ▪ Define Avogadro’s # as the mole (a counting unit) -24 1 amu = 1.66 x 10 grams 1 mole = 6.02214199 x 1023 Like 1 dozen = 12 Glucose, C6H12O6 Formula weight: 180 amu Molar mass: 180 g/mole How much does one glucose molecule weigh? How much does one mole of glucose molecules weigh? Urea, (NH2)2CO Formula weight: 60.0 amu Molar mass: 60.0 g/mole How much does one urea molecule weigh? How much does one mole of urea molecules weigh? Chemical Equations ▪ ▪ ▪ ▪ Know the basic features of a chemical equation Left of the arrow are the reactants Right of the arrow are the products To be interpreted as the number of molecules or moles that react or are produced Know how to balance a chemical equation Know how to use the coefficients in a chemical reaction to predict the moles of reactants needed or the moles of products produced reactants products C3 H8 (g) + 5O2 ( g) 3CO2 (g) + 4H2 O( g) Balance… Ca( OH) 2 ( s) + HCl( g) Calcium hydroxide CO2 ( g) + H2 O(l) CaCl2 (s) + H2 O( l) Calcium chlorid e photosynthes is C6 H1 2 O6 (aq) + O2 (g) Glucose C4 H1 0 ( g) + O2 (g) Butane CO2 (g) + H2 O(g) How many moles of N2 are required to react with 6 moles of H2 to produce NH3 N2 (g) + 3H2 (g) 2NH3 ( g) Know what reduction and oxidation mean ▪ In a chemical equation, know how to identify the atom that 1. Was reduced (gained electrons) 2. Was oxidized (lost electrons) ▪ In a chemical equation, know how to identify the molecule that 1. Was reduced (gained H atoms or Lost O atoms) 2. Was oxidized (gained O atoms or Lost H atoms) Electrons flow from Zn to Cu Zn( s) + Loses electrons; is oxidized Gives electrons to Cu 2+ ; is the reducing agent Gaining and losing electrons 2+ Cu 2 + ( a q) Gains electrons; is reduced Takes electrons from Zn; is the oxidizing agent Zn 2 + ( a q) + Cu( s) Gaining and losing H and O atoms Is reduced CH4 ( g ) + 2 O 2 ( g) Methane Is oxidized CO 2 ( g) + 2 H2 O( g ) Thermochemistry – Heat of the reaction ▪ Know endothermic and exothermic mean exothermic reaction: one that gives off heat. endothermic reaction: one that absorbs heat. Thermochemistry – Heat of the reaction ▪ Know how to recognize endothermic and exothermic reactions C( s) + O2 (g) CO2 (g) + 94.0 kcal/mole C exothermic reaction: one that gives off heat. Avogadro’s number and Molar Mass ▪ Use molar mass and Avogadro’s # to convert between grams and moles and # of particles • A tablet of aspirin, C9H8O4, contains 0.360 g of aspirin. How many molecules of aspirin are present? – first we find how many mol of aspirin are in 0.360 g. 0.360 g aspirin x 1 mol aspirin 180.0 g aspirin = 0.00200 mol aspirin – each mole of aspirin contains 6.02 x 1023 molecules. – the number of molecules of aspirin in the tablet is 0.00200 mole x 6.02 x 1023 molecules = 1.20 x 1021 molecules mole