The Nature of Matter What is matter? Matter: Anything that hass mass and volume Matter can be measured in these ways: • Volume: amount of space that matter takes up • Mass: a measure of matter’s inertia (more mass = greater inertia) -mass is always constant, no matter where the object is in the universe; weight is a measure of the force of gravity. • Density: the mass of a given volume of a substance • Length: You hopefully know what this is… Physical properties of matter: Physical Property: Things that can be observed about a substance or object without changing the identity of the substance or object. Examples of Physical Properties: • Color • Odor • Mass • Volume • How well it conducts electricity • Malleablity (ability to be bent into shapes) • • • • Density ( d = m/v) State at room temeperature Heat or electricial conductivity Ductility (ability to be pulled in wire) Characteristic property: Characteristic property: a property of a substance that can help identify a substance. Examples: • Copper has a reddish color • Water has a density of 1 g/ml • Diamonds are much harder than other minerals. Physical & Chemical Changes: Physical Change: a change in a substance that does not change the identity of a substance. (example: crumpling up a piece of paper.) Chemical change: a change in a substance that changes its identity (examples: setting a piece of paper on fire; iron rusting in salt water.) Chemical Properties: Chemical properties describe matter’s ability to turn into other types of matter. Examples: • Flammability: the ability to burn (be converted to energy) • Reactivity: the ability to combine with other types of matter and become a new substance Signs of chemcial change: • • • • Change in color Change in odor Creation of gas (fizzing, bubbling) Production of heat or other change in temperature • Creation of light • Creation of sound (e.g., explosion) The most important sign that a chemical change has occurred is that it cannot be easily reversed. Elements vs. Compounds: Element: A substance which contains only identical atoms. Examples: hydrogen, helium, oxygen Molecule: A group of atoms that are connected (either by sharing or transferring electrons) Compound: A substance that contains two or more types of atoms that are chemically bonded togther. Examples: water, carbon dioxide How to Read the Periodic Table: Checkpoint Quiz on Structure of the Atom: 1. Describe the particle model of matter. 2. Draw and label a diagram of Thomson’s model of the atom. 3. Who proved that an atom’s volume is mostly composed of nothing at all? 4. An atom of nitrogen has an atomic number of 7 and an atomic mass of about 14. Draw a Bohr diagram of an atom of this element. 5. Which part of an atom has a positive electrical charge? Isotopes of Atoms: Isotope: the number of neutrons varies from the most-common variety listed in the periodic table. Example: Most atoms of carbon have 6 neutrons. However, some carbon atoms may have more or less than this number. Therefore, their mass may be more or less than the usual 12 AMU (atomic mass units) Naming Isotopes: Isotopes of a given element are named (numbered) according to their mass number. Example: a carbon atom that has 6 protons and 8 neutrons has a mass of 14, so the name of that isotope is C-14 . Properties of isotopes: • Generally, isotopes of an element have the same physical and chemical properties of other isotopes of the same element. • However, some isotopes have unstable nucleii, and they decay rapidly (i.e, are radioactive.) For example C-14 is somewhat radioactive Forces Within atoms (and throughout the universe): • Gravity: exists because mass curves space-time • Electromagnetic force: the force created by particles with positive or negative electric charges • Strong nuclear force: the force that keeps particles in the atom from flying apart from one another • Weak nuclear force: The force that that allows subatomic particles to turn into other types of particles (and is the cause of radioactive decay) Organization of the Periodic Table: Elements, when arranged by atomic number (or even by atomic mass), follow a pattern known as the Periodic Law: The physical and chemical properties of the elements re-occur in a regular pattern as you go through the elements in order of their atomic numbers. Groups and Periods: The periodic table is organized into groups and periods: Groups (columns) have similar properties. Periods (rows) have similar atomic numbers and masses. Main Regions of the Periodic Table: 1. Metals: Most elements are metals. They are mainly listed to the left of the zigzag line (commonly called the staircase). Most metals are: • Solid at 20 o C • Shiny • Ductile • Malleable • Good conductors of heat and electricity 2. Nonmetals: Nonmetals are mostly to the right of the staircase. Most nonmetals: • Are gases or solids at 20o C • Have almost completely full outer electron orbits • Are poor conductors • Are brittle (if solid) 3. Metalloids: metalloids are found on the staircase. They have some properties of metals, and some properties of nonmetals. A More Detailed Look at the Table: Properties of the Groups: Group 1: Alkali Metals: They are highly reactive, soft, and brittle. They all have one electron in their outer orbit. Group 2: Alkaline Earth Metals: They are like group 1, but slightly less reactive. They have 2 electrons in their outer orbit. Groups 3-12: Transition Metals: Have “normal” properties of metals. They are less reactive than groups 1-2. Electrons flow freely among atoms (which is why they’re good conductors) Group 17: Halogens. Very reactive nonmetals. They frequently form chemical bonds with metals in groups 1 and 2. Group 18: Noble Gases. These gases have completely full outer electron orbits, so do not form bonds with any other elements. They are always found in pure form in nature. Homework: LO: Describe the organization of the periodic table of the elements. SLE: Read and write proficiently. 1. Read p. 114-120. 2. Answer the review questions on p. 121 (on loose leaf). States of matter and the particle model: Three states of matter: 1. Solids: have a definite shape and volume. Particles within solids are vibrating, but not moving much in relation to each other. Types of solids: • Crystalline: particle arrangement is very orderly, and follows a definite pattern. • Amorphous: particle arrangement is random 2. Liquids: liquids have a definite volume, but they take the shape of the container they are in. Particles in a solid move around quite a bit, but their energy level (and velocity) is relatively low. 3. Gases: Gases have no definite shape or volume. The particles have a lot of energy and are moving very fast, and will rapidly spread out to fill whatever space they are in. The space between gas molecules is very large compared to solids and liquids. Two Gas Laws: 1. Charles’ Law: Given the same amount of pressure, if you increase the temperature of a gas, the volume will also increase. Boyle’s Law: Given the same temperature, if you increase the pressure on a gas, the volume will decrease. Homework: LO: Describe states of matter in terms of the particle model of matter. SLE: Read and write proficiently. 1. Read p. 36-45 2. Review questions p. 39, 45 LO: Describe endothermic and exothermic reactions. SLE: Work cooperatively. • • • • • • • • • • • • • Exothermic Reaction: Endothermic Reaction: 1. Place thermometer in jar and close lid. 2. Wait 5 minutes and record temperature. 3. Soak steel wool in vinegar for 5 minutes. 4. Wrap vinegar-soaked steel wool around thermometer bulb, place back in jar. 5. After 5 more minutes, record temperature again. 1. Pour some vinegar (citric acid) into a beaker. 2. Record temperature. 3. Stir in some baking soda. 4. Wait 30-60 seconds 5. Record temperature again. Temperature before vinegar: ____________C Temperature after Sodium bicarbonate: _____________C Temperature after vinegar: __________C What happened? Why? What happened? Why? In general, what is the difference between exothermic and endothermic reactions? Temperature before Sodium bicarbonate: ___________C LO: Describe the crystal structure of some solids SLE: Work cooperatively Salt crystal shape: Sugar crystal shape: LO: Describe states of matter SLE: Apply academic habits for success Checkpoint quiz on states of matter: 1. Describe the motion of particles in solids, liquids and gases. (2 pts) 2. State Charles’ Law. 3. State Boyle’s Law. 4. If you decrease the pressure applied to a certain volume of gas, what will happen to the volume? Why? Compounds and Chemical Bonds: Review: An element is a substance that contains only a single type of atom. A compound is a substance that contains molecules that are composed of two or more different kinds of atoms. A molecule is a collection of two or more atoms that are bonded together through the transfer or sharing of electrons. Types of chemcial (molecular) bonds: 1. Ionic Bond: created when an electron in the outer orbit of one atom gets transferred to another atom. This transfer creates two ions (atoms with positive or negative charge) , one of which is positively charged, and one of which is negatively charged. They they bond together via electromagnetic attraction. 2. Covalent Bonds: are formed when two or more atoms share electrons in their outer (valence) orbit. Diatomic molecules (O2 for example) are formed by covalent bonds. Homework: LO: Describe kinds of chemical bonds SLE: Work independently 1. Read p. 8-17 in Interactions of Matter 2. Review questions on p. 11 & 17 LO: Compare strength of covalent and ionic bonds. SLE: Work collaboratively Problem: Are ionic bonds harder to break apart that covalent bonds? Hypothesis: Independent variable: Dependent variable: 3 Controls: Procedure: 1. Put salt (ionic bond, NaCl) in a pan 2. Place pan on a hot plate and heat on high for 5-10 minutes. 3. Repeat steps #1-2 with sugar (Covalent bond, C6H12O6). 4. Observe and record results . Observations: What happened when salt was heated: What happened when sugar was heated: Conclusion: LO: Describe how elements are chemically combined SLE: Meet or exceed NGSS Checkpoint Quiz on Chemical Bonds: 1. Describe how covalent bonds happen. 2. Describe how ionic bonds happen. 3. What part of an atom determines how it bonds to other atoms? 4. Na (group 1) is most likely to form an ionic bond with which group of atoms on the periodic table? (Give the group number) 5. How many atoms (total) are in a molecule of C6H12O6? Law of Conservation of Mass: In any physical system, even during a chemical reaction, the total amount of mass (i.e., the total number of atoms) will not change. LO: Model the law of conservation of mass. SLE: Work collaboratively. Problem: If a gas is produced in a closed system during a chemical reaction, does the total mass of the system stay the same? Hypothesis: Procedure: 1. Pour some water into a ziplock bag and seal it closed. 2. Measure the total mass of the ziplock bag and one tablet of Alka Seltzer. 3. Open the ziplock bag, put one Alka Seltzer tablet in the bag and quickly reseal it. 4. After 5 minutes, find the mass of the bag again. 5. Repeat Steps 1-4, but this time, instead of re-sealing the ziplock bag after adding Alka Seltzer, leave the bag open. Data: Type of system: Mass before reaction (g): Closed Open Conclusion: Mass after reaction (g): Forming New Sustances: Chemical Reaction: A process in which one or more substances is changed into one or more new substances with different properties. Reactants: the substances you start out with. Products: the substances you end up with. Signs of chemical reactions: • • • • • Formation of a gas. Formation of a new solid (precipitate) Change in temperature Change of color Creation of light Chemical Formulas: Chemical formula: a formula that tells you what molecules of a compound look like: HCl: Hydrogen chloride; 1 atom of hydrogen, 1 atom of chlorine in each molecule. H2SO4: Hydrogen sulfate; 2 atoms of hydrogen, 1 atom of sulfur, and 4 atoms of oxygen. Predicting chemical formulas: The formula for covalent compounds is just based on the name: Carbon disulfide: 1 C, 2S, so it’s CS2 Carbon monoxide: 1 C, 1O, so it’s CO For ionic compounds, you have to know the group numbers and charges of the ions: Magnesium Chloride: Mg is in group 2 and has a charge of -2; Cl is in group 17, has room for 1 extra electron, so has a charge of +1: But Mg want to give 2 electrons away, so 2 Cl atoms are involved in the bond: MgCl2 Charges of polyatomic ions: • Ammonium ion, NH4; 1+ • Carbonate ion, CO3; 2− • Hydroxide ion, OH; 1− • Nitrate ion, NO3; 1− • Phosphate ion, PO4; 3− • Sulfate ion, SO4; 2− Unfortunately, because polyatomic ions involve reactions with molecules that are based on covalent bonds, these need to just be remembered or looked up. Chemical Equations: Chemical Equation: a way to describe what happens in a chemical reaction by displaying the changed chemical formulas of the substances involved. Reactant Product Balancing Chemical Equations: It’s really important that chemical equations: 1. Reflect reality; 2. Reflect (obey) the law of conservation of mass. C + O2 CO2 To balance equations, because of the way electrons move around in chemical bonds, coefficients must be added to the equation: H2 + O2 H2O : Not balanced 2H2 + O2 2H2O Balanced Homework: LO: Describe chemical reactions using chemical equations. SLE: Work independently. 1. Read pages 28-37 in Interactons of Matter. 2. Complete review questions on p. 37 (on loose leaf).