Chapter 4: Igneous Rocks Add section detail briefings Classification of Igneous Rocks Pyroclasts Extrusive rocks Porphyry Intrusive rocks Intrusive (plutonic)—Extrusive (volcanic) Pyroclasts Volcanic ash Extrusive rocks Porphyry Intrusive rocks Bomb Pumice Intrusive (plutonic)—Extrusive (volcanic) Pyroclasts Volcanic ash Extrusive rocks Porphyry Intrusive rocks Bomb Pumice Extrusive pyroclasts form in violent eruptions from lava in the air. Intrusive (plutonic)—Extrusive (volcanic) Pyroclasts Volcanic ash Extrusive rocks Porphyry Intrusive rocks Bomb Mafic Basalt Pumice Felsic Rhyolite Extrusive pyroclasts form in violent eruptions from lava in the air. Intrusive (plutonic)—Extrusive (volcanic) Pyroclasts Volcanic ash Extrusive rocks Porphyry Intrusive rocks Bomb Mafic Basalt Pumice Felsic Rhyolite Extrusive pyroclasts form in violent eruptions from lava in the air. Extrusive igneous rocks cool rapidly and are finegrained. Intrusive (plutonic)—Extrusive (volcanic) Pyroclasts Volcanic ash Extrusive rocks Bomb Pumice Mafic Basalt Felsic Rhyolite Gabbro Granite Porphyry Intrusive rocks Extrusive pyroclasts form in violent eruptions from lava in the air. Extrusive igneous rocks cool rapidly and are finegrained. Intrusive (plutonic)—Extrusive (volcanic) Pyroclasts Volcanic ash Extrusive rocks Bomb Pumice Mafic Basalt Felsic Rhyolite Gabbro Granite Porphyry Intrusive rocks Extrusive pyroclasts form in violent eruptions from lava in the air. Extrusive igneous rocks cool rapidly and are finegrained. Intrusive igneous rocks cool slowly, allowing large, coarse crystals to form. Intrusive (plutonic)—Extrusive (volcanic) Pyroclasts Volcanic ash Extrusive rocks Bomb Pumice Mafic Basalt Felsic Rhyolite Gabbro Granite Porphyry Intrusive rocks Phenocrysts Porphyry Extrusive pyroclasts form in violent eruptions from lava in the air. Extrusive igneous rocks cool rapidly and are finegrained. Intrusive igneous rocks cool slowly, allowing large, coarse crystals to form. Intrusive (plutonic)—Extrusive (volcanic) Pyroclasts Volcanic ash Extrusive rocks Bomb Pumice Mafic Basalt Felsic Rhyolite Gabbro Granite Porphyry Intrusive rocks Phenocrysts Porphyry Extrusive pyroclasts form in violent eruptions from lava in the air. Extrusive igneous rocks cool rapidly and are finegrained. Intrusive igneous rocks cool slowly, allowing large, coarse crystals to form. Some intrusive porphyritic crystals grow large, but the remaining melt cools faster, forming smaller crystals. The common rock forming minerals in the earth’s crust are made from just 8 elements. NORMAN L. BOWEN (1887-1956) Queen’s, MIT and Geophysical Laboratory at the Carnegie Institute of Washington • • Pioneering work at the interface between geology with physical chemistry Studied the formation of igneous rocks in the laboratory April 29, 1948 Dear Professor Gilluly: Having had occasion some years ago to learn the art of lipreading I noticed yesterday when I was giving may paper that at the end of each of my sentences you said, "Horse shit". Evidently you had made special note of the word "equilibria" in the title of my paper and were from time to time reminding yourself and your neighbors of the gist of the discussion. You are, however, under a misapprehension as to the derivation of the word "equilibria". It does not come from equus = a horse and libria = things liberated or discharged, but is from quite different roots. If you will consult a chemist you will be able to learn the real significance of the word and I may add that I feel that one so highly placed in geological circles as you should make it a point to acquire some familiarity with the exact significance of common terms used in collateral sciences. Trusting that you will not resent my correction and suggestions, I am Yours sincerely, Norman L. B BOWEN’S REACTION SERIES Magma composition Temperature ~600°C Orthoclase feldspar Felsic, Rhyolitic (high silica) Muscovite mica Quartz Biotite mica Sodiumrich Intermediate, andesitic Amphibole Pyroxene ~1200°C Olivine Simultaneous crystallization Calciumrich Mafic, basaltic Ultramafic (low silica) BOWEN’S REACTION SERIES As magma temperature decreases… …materials crystallize in an Temperature ordered ~600°C series… …while plagioclase feldspar crystallizes, from calciumMagma rich sodium-rich form… composition Orthoclase feldspar Felsic, Rhyolitic (high silica) Muscovite mica Quartz Biotite mica Sodiumrich Intermediate, andesitic Amphibole Pyroxene ~1200°C Olivine Simultaneous crystallization Calciumrich …and the composition of magma changes from ultramafic to andesitic. Mafic, basaltic Ultramafic (low silica) The composition of tin-lead solder is adjusted to the ‘eutectic’ in order to achieve melting at the lowest temperature An important tin/lead solder is 63/37, called “eutectic,” meaning it goes directly from solid to liquid without a partially molten stage. This alloy melts at 361°F (183°C), the lowest melting point of any tin-lead alloy. Other eutectic solders include 62.5% tin, 36.1% lead and 1.4% silver (354°F, 179°C) 96% tin and 4% silver (430°F, 221°C); 97.5% lead and 2.5% silver (581°F, 305°C) 0.75% tin, 97.5 % lead and 1.75% silver (590°F, 310°C). (590°F, 31 Physical properties of melting and crystallization Binary eutectic Fractional crystallization: Basaltic intrusion 245–275 m (800–900 ft) Sandstone Basalt Mostly sodium-rich plagioclase feldspar; no olivine Calcium-rich plagioclase feldspar and pyroxene; no olivine Olivine Basalt Sandstone Basalt cooled quickly at the edges of the intrusion. Fractional crystallization: Olivine crystallizes first Pyroxene and plagioclase feldspar crystallize A gradient of pyroxene and feldspar is established. Plagioclase feldspar continues to crystallize. Complex petrogenetic histories begin with Partial Melting: Partial melting creates a magma of a particular composition. Crystallizing minerals Blobs of melt (solidified) in a rock (migmatite) Magma chamber A Magma chamber B Partial melting of country rock Basaltic magma …more fractional crystallization Partial melting creates a magma of a particular composition. Cooling causes minerals to crystallize and settle. Crystallizing minerals Magma chamber A Magma chamber A Magma chamber B Partial melting of country rock A basaltic magma chamber breaks through. Mixing results Basaltic magma Magma mixing in andesitic magma. Magma chamber B Crystals may accumulate on the sides and roof of the chamber due to turbulence. Lava flow Country rock Ash falls and pyroclasts Volcano Volcanic neck with radiating dikes Stock Sill Sill Sill Dikes cut across layers of country rock… …but sills run parallel to them. Batholiths are the largest forms of plutons, covering at least 100 km2. Assimilation of country rock Rising magma wedges open overlying country rock. The magma melts the surrounding rock... …which changes the magma’s composition. Country rock The magma also breaks off xenoliths that sink into the magma. A sill runs parallel to country rock layers Sill A dike cuts across layers Dike Island arc volcanoes, Java, Indonesia Intermediate ISLAND ARC PLATE SUBDUCTION Island arc volcano Mafic to intermediate intrusives (plutonism) Mafic to intermediate extrusives (volcanism) Subduction zone Oceanic lithosphere Plate divergence boundary, Mid-Atlantic Ridge, Iceland Mafic PLATE DIVERGENCE Mid-ocean ridge Basatic extrusives Basaltic intrusives Partial melting Of upper mantle Rising magma Hot-spot volcano, Volcanoes National Park, Hawaii Mafic HOT-SPOT VOLCANISM Hot-spot volcano Basatic extrusives Basaltic intrusives Mantle plume (hot spot) Mantle Continental margin volcano, Mt. Rainier, Washington HOT-SPOT VOLCANISM Mafic to felsic intrusives Mafic to felsic extrusives Subduction zone Intermediate to Felsic Continental margin volcano Mafic Sediment layers OPHIOLITE SUITE Deep-sea sediments Pillow basalts Pillow basalt Sheeted dike complex Dikes Thin section of gabbro Gabbro Peridotites and other ultramafic rocks Thin section of peridotite Hot mantle rises, decompresses, and melts. Dikes A thin dike erupts, spilling lava in “pillows.” Pillow lava Newer, thinner sediments Older, thicker sediments Sheeted dikes in basalt Oceanic crust Gabbro Moho Peridotite layer Mantle Cold seawater Sheeted dikes Seawater filters through the basalt layer, where it is heated. Spreading center Heated seawater carrying dissolved minerals Mantle The heated seawater then rises. Dissolved minerals precipitate in the ocean. Dikes intruding dikes Dikes intrude dikes to form sheeted dikes. Sediments are deposited on the spreading seafloor. The gabbro layer metamorphoses by contact with the magma. Magma chamber Peridotite layer Crystals settle out of the magma, forming the peridotite layer. Intermediate Magma of intermediate composition is erupted to form arc volcanoes. Molten sediments combine with lithospheric magma. Trench Oceanic sediments Oceanic crust basalt Oceanic mantle lithosphere Magma chamber The water and molten sediments melt parts of the overlying plate. Asthenosphere Subducting oceanic crust carries sediments with it. H2O H2O H2O Water remains trapped as the pressure and temperature increase. Sediment grains Water The trapped water is released as the temperature increases,… …causing the sedimentary rocks to melt at lower temperatures.