Embodied Emissions in Purchased Materials Analysis of Embodied Emissions in Purchased Materials Prepared for the OUS Sustainability Conference February 28, 2011 Corvallis, Oregon David Allaway Allaway.david@deq.state.or.us 503-229-5479 Embodied Emissions in Purchased Materials Today’s overview • Materials matter – the big picture • An introduction to life cycle analysis (LCA) • What LCAs tell us about the environmental impacts of materials . . . and opportunities to reduce them • Questions and discussion throughout Embodied Emissions in Purchased Materials DEQ Priority Toxics Focus List (Draft) Lead Naphthalenes Dioxins & Furans Ammonia PAHs Ethylbenzene Nonyphenol, 4- (& ethoxylates) Malathion Hexachlorocyclohexane Tetrachloroethylene Toluene (HCH), gamma- (Lindane) Phthalates Trichloroethylene Benzene Dichlorobenzene, 1,4- (Dichlorobenzene-p) Chlorothalonil Pentachlorophenol Formaldehyde Manganese Copper Diazinon Arsenic Trifluralin PBDEs Bisphenol A 2,4-D Triclosan Mercury (and methylmercury) Pendamethalin Silver Diuron Carbaryl Permethrin Cadmium Glyphosate Propoxur (Baygon) Chromium Nickel Diethyltoluamide, N, N- (DEET) Chlorpyrifos Atrazine Dieldrin Methoxychlor Hexachlorocyclohexane, beta- (beta-BHC) PCBs Aldrin Hexachlorobenzene Chlordane (and metabolites) Heptachlor (& Heptachlor epoxide) Hexachlorocyclohexane, alpha- (alpha-BHC) DDT (and metabolites) Trichlorophenol, 2,4,5- (2,4,5-T) Embodied Emissions in Purchased Materials DEQ Priority Toxics Focus List (Draft) Toxic Chemicals In Current Consumer Products Lead Naphthalenes Dioxins & Furans Ammonia PAHs Ethylbenzene Nonyphenol, 4- (& ethoxylates) Malathion Hexachlorocyclohexane Tetrachloroethylene Toluene (HCH), gamma- (Lindane) Phthalates Trichloroethylene Benzene Dichlorobenzene, 1,4- (Dichlorobenzene-p) Chlorothalonil Pentachlorophenol Formaldehyde Manganese Copper Diazinon Arsenic Trifluralin PBDEs Bisphenol A 2,4-D Triclosan Mercury (and methylmercury) Pendamethalin Silver Diuron Carbaryl Permethrin Cadmium Glyphosate Propoxur (Baygon) Chromium Nickel Diethyltoluamide, N, N- (DEET) Chlorpyrifos Atrazine Dieldrin Methoxychlor Hexachlorocyclohexane, beta- (beta-BHC) PCBs Aldrin Hexachlorobenzene Chlordane (and metabolites) Heptachlor (& Heptachlor epoxide) Hexachlorocyclohexane, alpha- (alpha-BHC) DDT (and metabolites) Trichlorophenol, 2,4,5- (2,4,5-T) Embodied Emissions in Purchased Materials DEQ Priority Toxics Focus List (Draft) Other Product-Related Toxics Lead Naphthalenes Dioxins & Furans Ammonia PAHs Ethylbenzene Nonyphenol, 4- (& ethoxylates) Malathion Hexachlorocyclohexane Tetrachloroethylene Toluene (HCH), gamma- (Lindane) Phthalates Trichloroethylene Benzene Dichlorobenzene, 1,4- (Dichlorobenzene-p) Chlorothalonil Pentachlorophenol Formaldehyde Manganese Copper Diazinon Arsenic Trifluralin PBDEs Bisphenol A 2,4-D Triclosan Mercury (and methylmercury) Pendamethalin Silver Diuron Carbaryl Permethrin Cadmium Glyphosate Propoxur (Baygon) Chromium Nickel Diethyltoluamide, N, N- (DEET) Chlorpyrifos Atrazine Dieldrin Methoxychlor Hexachlorocyclohexane, beta- (beta-BHC) PCBs Aldrin Hexachlorobenzene Chlordane (and metabolites) Heptachlor (& Heptachlor epoxide) Hexachlorocyclohexane, alpha- (alpha-BHC) DDT (and metabolites) Trichlorophenol, 2,4,5- (2,4,5-T) Embodied Emissions in Purchased Materials DEQ Priority Toxics Focus List (Draft) Toxic Chemicals In Current Consumer Products Lead Naphthalenes Other Product-Related Toxics Dioxins & Furans Ammonia PAHs Ethylbenzene Nonyphenol, 4- (& ethoxylates) Malathion Hexachlorocyclohexane Tetrachloroethylene Toluene (HCH), gamma- (Lindane) Phthalates Trichloroethylene Benzene Dichlorobenzene, 1,4- (Dichlorobenzene-p) Chlorothalonil Pentachlorophenol Formaldehyde Manganese Copper Diazinon Arsenic Trifluralin PBDEs Bisphenol A 2,4-D Triclosan Mercury (and methylmercury) Pendamethalin Silver Diuron Carbaryl Permethrin Cadmium Glyphosate Propoxur (Baygon) Chromium Nickel Diethyltoluamide, N, N- (DEET) Chlorpyrifos Atrazine Dieldrin Methoxychlor Hexachlorocyclohexane, beta- (beta-BHC) PCBs Aldrin Hexachlorobenzene Chlordane (and metabolites) Heptachlor (& Heptachlor epoxide) Hexachlorocyclohexane, alpha- (alpha-BHC) DDT (and metabolites) Trichlorophenol, 2,4,5- (2,4,5-T) Embodied Emissions in Purchased Materials Traditional Sector-Based View of U.S. Greenhouse Gas Emissions (2006) Residential 5% Commercial 6% Agriculture 8% Electric Power Industry 34% Industry 19% Transportation 28% Source: US EPA (2009) Embodied Emissions in Purchased Materials Materials Matter: Systems-Based Geographic Emissions Inventory (2006) Provision of Materials: Non-Food Goods 29% Building Lighting and HVAC 25% 42% Transportation of People 24% Provision of Materials: Food 13% Use of Appliances and Devices 8% Source: US EPA (2009) Infrastructure 1% Embodied Emissions in Purchased Materials Systems-Based Emissions Inventory, Geographic Emissions Adjusted for Imports and Exports (2006) Building Lighting and HVAC 21% Provision of Goods 37% 49% Transportation of People 22% Provision of Food 12% Use of Appliances and Devices 7% Infrastructure 1% Source: Joshuah Stolaroff/Product Policy Institute (2009), based on EPA (2009) and Weber & Matthews (2007) Embodied Emissions in Purchased Materials OUS Emissions FY 2008, by Scope Category Including Embodied Emissions in Supply Chain Total Emissions (MT CO2e) 250,000 200,000 150,000 100,000 50,000 0 Scope 1 Source: Good Company (2009) Scope 2 Scope 3 required by ACUPCC Scope 3 supply chain Embodied Emissions in Purchased Materials OUS FY2008 Emissions Embodied in Goods and Services (Draft) Other Goods & Services 29% Building Construction & Services 43% Commercial Printing 6% IT 7% Resale Merchandise 15% Source: Good Company (2009) Embodied Emissions in Purchased Materials A Note RE: OUS Supply Chain Emissions • By nature, these emissions estimates are very rough . . . a “sense of scale” – But just because they’re imprecise doesn’t mean they should be ignored! • Over time, estimates will likely become more precise, and product-specific Embodied Emissions in Purchased Materials Impacts vs. Attributes Examples of Impacts •Emissions of VOCs •GHG emissions •Use of non-renewable resources Examples of Attributes •Recyclability •% recycled content •Biodegradable • Impacts are more challenging to evaluate . . . requires life cycle assessment . Embodied Emissions in Purchased Materials Life Cycle Assessment (LCA) • The science of estimating environmental impacts across the “life cycle” of a product (or service) • A powerful tool for understanding impacts, where/how impacts occur, and how to reduce them • Far from perfect; potential for abuse; rapidly evolving • Two basic approaches: – Process LCA – Input/output LCA Embodied Emissions in Purchased Materials Process LCA: A Partial Example Soda Ash Production 3.3 Double-lined Kraft (DLK) 7.5 Clippings Liquor & Bark Used as Fuel Semichemical Pulp Production Inputs (OCC) 53 Repulping 42 Old Corrugated Containers Medium Manufacture Starch Adhesive 13 62 17 151 (76) 133 Roundwood * 1,649 (825) Harvesting (Softwood and Hardwood) Wood Chip Production 453 (226) Corrugating Medium Manufacture 184 120 2.6 Sodium Sulfate Mining 1.5 Salt Mining 2.4 125 Linerboard Manufacture 7.7 Sodium Hydroxide Production Corrugated Box Converting 1,000 554 136 1.1 11 Fertilizers Repulping Corn Growing & Harvesting 9.2 Corn Starch Production Limestone Mining 9.0 Lime Production 8.4 Inputs (OCC, DLK) Pesticides 4.8 Unbleached Kraft Pulp Production Liquor & Bark Used as Fuel Linerboard Manufacture Embodied Emissions in Purchased Materials Process LCA ISO 14040 series provides standards on conducting process LCAs: Embodied Emissions in Purchased Materials Process LCA • Inventory analysis: accounting of energy and material flows • Impact analysis: conversion of those flows into “impact categories”, such as: – – – – – – Acidification Ecotoxicity Eutrophication Global warming Ozone depletion Smog – Human Health • Cancer • Non-cancer • Respiratory effects Embodied Emissions in Purchased Materials Some Process LCA-Derived Tools • Building for Environmental and Economic Sustainability (BEES) http://www.bfrl.nist.gov/oae/software/bees/ • Waste Reduction Model (WARM) http://www.epa.gov/warm/ • Recycled Content Tool (ReCON) http://www.epa.gov/climatechange/wycd/waste/ calculators/ReCon_home.html • Comparative Packaging Assessment Tool (COMPASS) https://www.design-compass.org/ Embodied Emissions in Purchased Materials Input-Output LCA Engine $20,000 $2,500 Car Parts Steel Plastics $2,000 $1,200 $800 Steel Aluminum $2,500 Engine $300 $200 Conferences . . . $10 Attorneys . . . $20 Iron Ore Coal $300 Steel $45 $30 Steel ... $2 Embodied Emissions in Purchased Materials Input-Output LCA (continued) • Traditional (economic) input-output analysis estimates financial flows through the supply chain • Estimate emissions intensities (direct emissions/dollar) for different industries – Single-region or multi-region – Most common tool: www.eiolca.net • Life cycle emissions = (emissions/dollar) x (dollars) Embodied Emissions in Purchased Materials OUS FY2008 Emissions Embodied in Goods and Services (Draft) – Input-Output LCA Other Goods & Services 29% Building Construction & Services 43% Commercial Printing 6% IT 7% Resale Merchandise 15% Source: Good Company (2009) Embodied Emissions in Purchased Materials So, what do LCAs tell us? Embodied Emissions in Purchased Materials Materials: What Are We Looking For? • In the absence of readily-available life-cycle data (impacts), buyers and sustainability champions often turn to attributes such as: – – – – – – Local Energy-efficient Recyclable Recycled content Bio-based Biodegradable • How well do these attributes actually correlate with “low impact” or “sustainable”? Embodied Emissions in Purchased Materials Less is best! (Usually) • “Reduce, then reuse, then recycle” – A hierarchy of preferences • All equally effective at diverting materials from landfills – But that’s not where the big impacts occur! Embodied Emissions in Purchased Materials For Materials, “Upstream” Emissions Dominate Provision of Materials 42% Freight 7.1% Landfills & Wastewater 2.2% Building Lighting and HVAC 25% “Upstream” Processes 32.2% Transportation of People 24% Use of Appliances and Devices 8% Infrastructure 1% Embodied Emissions in Purchased Materials Tellus Institute Packaging Study (1992): Human Health Impacts Material Virgin Corrugated Box* Recycled Content Corrugated Box* Virgin Aluminum Human Health Cost ($/ton material) Production Disposal Total $95 $2 $97 $86 $2 $88 ~$923 $5 $928 Recycled Content ~$71 $5 $76 Aluminum *Assumes ~2 pounds linerboard per 1 pound of medium. Embodied Emissions in Purchased Materials Tellus Institute Packaging Study (1992): Human Health Impacts (continued) Material Virgin Glass Recycled Content Glass Virgin HDPE Virgin PET Virgin PVC Human Health Cost ($/ton material) Production Disposal Total $69 $1 $70 $47 $1 $48 $124 $327 $1,710 $4 $4 $4 $128 $331 $1,714 Note: These costs are per-ton, not per-package! Embodied Emissions in Purchased Materials DEQ’s Life Cycle Analysis of Water Delivery • 3 basic systems: Full study at: http://www.deq.state.or.us/lq/sw/wasteprevention/ drinkingwater.htm Embodied Emissions in Purchased Materials Normalized impact (baseline w/62% recycling = 100%) Recycling, Recycled Content, and Lightweighting Example: PET Water Bottles 120% 100% 80% 60% 40% 20% 0% Baseline w/ 37% recycling rate Baseline (62% recycling rate) “Baseline” = PET, half-liter, 13.3 grams, 0% post-consumer recycled content (PCR), on-site molding, purified municipal water (reverse osmosis, ozone and uv), 50 miles to retail, 5 miles home-to-retail, co-purchase w/24 other products, no chilling, 62% recycling rate. Embodied Emissions in Purchased Materials Normalized impact (baseline w/62% recycling = 100%) Recycling, Recycled Content, and Lightweighting Example: PET Water Bottles 120% 100% 80% 60% 40% 20% 0% Baseline w/ 37% recycling rate Baseline (62% recycling rate) “Baseline” = PET, half-liter, 13.3 grams, 0% post-consumer recycled content (PCR), on-site molding, purified municipal water (reverse osmosis, ozone and uv), 50 miles to retail, 5 miles home-to-retail, co-purchase w/24 other products, no chilling, 62% recycling rate. Embodied Emissions in Purchased Materials Normalized impact (baseline w/62% recycling = 100%) Recycling, Recycled Content, and Lightweighting Example: PET Water Bottles 120% 100% 80% 60% 40% 20% 0% Baseline w/ 37% recycling rate Baseline (62% recycling rate) Baseline w/25% PCR “Baseline” = PET, half-liter, 13.3 grams, 0% post-consumer recycled content (PCR), on-site molding, purified municipal water (reverse osmosis, ozone and uv), 50 miles to retail, 5 miles home-to-retail, co-purchase w/24 other products, no chilling, 62% recycling rate. Embodied Emissions in Purchased Materials Normalized impact (baseline w/62% recycling = 100%) Recycling, Recycled Content, and Lightweighting Example: PET Water Bottles 120% 100% 80% 60% 40% 20% 0% Baseline w/ 37% recycling rate Baseline (62% recycling rate) Baseline w/25% PCR Baseline lightweighted to 9.8 grams “Baseline” = PET, half-liter, 13.3 grams, 0% post-consumer recycled content (PCR), on-site molding, purified municipal water (reverse osmosis, ozone and uv), 50 miles to retail, 5 miles home-to-retail, co-purchase w/24 other products, no chilling, 62% recycling rate. Embodied Emissions in Purchased Materials Disposal vs. Recycling 120% Not a meaningful difference Normalized impact (purchase + disposal = 100%) 100% 80% 60% 40% Standard Oregon purchase* + disposal Standard Oregon purchase* + 100% recycling 20% 0% *Half-liter bottle; 0% recycled content; 13.3 grams; local water Embodied Emissions in Purchased Materials Disposal vs. Recycling vs. Prevention Normalized impact (purchase + disposal = 100%) 120% 100% 80% 60% Standard Oregon purchase* + disposal 40% 20% Standard Oregon purchase* + 100% recycling Tap water in reusable bottle** (1 use and wash/day for 1 year) 0% *Half-liter bottle; 0% recycled content; 13.3 grams; local water **Average of aluminum/PET/steel; no recycling; high-water use dishwasher Embodied Emissions in Purchased Materials Normalized impact (“best” single-use PET = 100%) Best Case Recycling vs. Best Case Prevention 120% 100% 80% 60% 40% "Best" single-use PET* "Best" tap water** 20% 0% *Not currently on market. 9.8 grams; 25% recycled content; very short transport; minimal processing of water; 100% recycling. **Steel reusable; used 5 years; used 2 times/day; washed weekly in efficient, full dishwasher; 100% recycling Embodied Emissions in Purchased Materials DEQ’s Life Cycle Analysis of E-Commerce Packaging • Full study at: http://www.deq.state.or.us/lq/pubs/docs/sw/ packaging/lifecycleinventoryshort.pdf Embodied Emissions in Purchased Materials DEQ’s E-Commerce LCA: Materials Evaluated Corrugated box* Void Fill (for boxes) Polystyrene loose fill* Corn starch loose fill Molded paper loose fill Inflated “air pillows”* Newsprint dunnage* Kraft dunnage* Shredded office paper Shredded boxes Shipping Bags Unpadded all-kraft mailer* Unpadded all-poly mailer* Kraft mailer with ONP padding* Kraft mailer with poly bubble padding* Poly mailer with poly bubble padding* *Different levels of post-consumer content also evaluated. Embodied Emissions in Purchased Materials E-Commerce Results: Petroleum Low PC Box/Fills High PC Box/Fills Low PC Bags High PC Bags 0 20 40 60 80 100 120 Million Btu of Petroleum per 10,000 Packages 140 Embodied Emissions in Purchased Materials E-Commerce Results: Natural Gas Low PC Box/Fills High PC Box/Fills Low PC Bags High PC Bags 0 10 20 30 40 50 60 70 Million Btu of Natural Gas per 10,000 Packages 80 Embodied Emissions in Purchased Materials E-Commerce Results: Coal Low PC Box/Fills High PC Box/Fills Low PC Bags High PC Bags 0 10 20 30 40 50 60 70 Million Btu of Coal per 10,000 Packages 80 90 Embodied Emissions in Purchased Materials E-Commerce Results: Atmospheric Particulates Low PC Box/Fills High PC Box/Fills Low PC Bags High PC Bags 0 10 20 30 40 50 60 70 80 90 Pounds of Atmospheric Particulate per 10,000 Packages Embodied Emissions in Purchased Materials E-Commerce Results: Atmospheric NOX Low PC Box/Fills High PC Box/Fills Low PC Bags High PC Bags 0 50 100 150 200 250 300 350 Pounds of Atmospheric NOx per 10,000 Packages Embodied Emissions in Purchased Materials E-Commerce Results: Atmospheric Mercury Low PC Box/Fills High PC Box/Fills Low PC Bags High PC Bags 0 0.0002 0.0004 0.0006 0.0008 0.001 0.0012 Pounds of Atmospheric Mercury per 10,000 Packages Embodied Emissions in Purchased Materials E-Commerce Results: Biological Oxygen Demand Low PC Box/Fills High PC Box/Fills Low PC Bags High PC Bags 0 10 20 30 40 Pounds of BOD per 10,000 Packages 50 Embodied Emissions in Purchased Materials E-Commerce Results: Waterborne Suspended Solids Low PC Box/Fills High PC Box/Fills Low PC Bags High PC Bags 0 10 20 30 40 50 60 70 Pounds of Waterborne Suspended Solids per 10,000 Packages *on a cradle-to-distribution center basis 100% Recycled Content Molded Pulp Loose Fill 50% Recycled Content Newsprint Dunnage 50% Recycled Content Kraft Paper Dunnage 30% Recycled Content Polystyrene Loose Fill 30% Recycled Content LDPE Air Packets 10% Recycled Content Newsprint Dunnage 0% Recycled Content Kraft Paper Dunnage 0% Recycled Content Corn Starch Loose Fill 0% Recycled Content Polystyrene Loose Fill 0% Recycled Content LDPE Air Packets Lbs CO2e*/10,000 packages Embodied Emissions in Purchased Materials Void Fills in E-Commerce Packaging (Boxes) 12000 10000 8000 6000 4000 2000 0 Embodied Emissions in Purchased Materials Mass Matters! • Weight of materials used is a critical factor: – All bags evaluated have lower burdens than boxes (in most categories) because of their much lower weight. – This confirms (indirectly) the relative ranking of waste prevention and recycling in the waste management hierarchy. • When comparing dissimilar materials, recyclability and recycled content do not always correlate with reduced GHG emissions: – BUT, once you’ve chosen a packaging material, increasing post-consumer content and recycling opportunities typically reduce emissions. Embodied Emissions in Purchased Materials What about degradable products? • When wastes degrade (in a landfill), they produce methane • Methane is 23 – 72 times more potent of a GHG than CO2 • Many landfills use some of the methane to produce energy • But no landfill captures 100% of its methane Photos: EPUD Embodied Emissions in Purchased Materials DEQ Drinking Water Study: Greenhouse Gas Impacts of 3 Bottled Water Systems 1105 1464 End-of-life management Consumer transport PLA, 62% composting, 100% decomposition in landfill Distribution PLA, 62% composting, inert in landfill 1600 1400 1200 1000 800 600 400 200 0 -200 -400 PET, 62% recycling Lbs CO2e per 1,000 gallons 1120 Filling Drinking water treatment (+wastewater) Manufacturing Credits Assumes no cross-contamination between PET and PLA Embodied Emissions in Purchased Materials For goods that use energy, energy efficiency is very important Provision of Goods 29% Building Lighting and HVAC 25% Use of Appliances and Devices 8% Provision of Food 13% Source: US EPA (2009) Transportation of People 24% Infrastructure 1% Embodied Emissions in Purchased Materials GHG/Product Life Cycles 100% 90% 80% 70% 60% 50% 40% 30% 20% 10% 0% Source: Lawrence Berkeley National Lab End-of-Life Use Manufacturing Embodied Emissions in Purchased Materials pounds CO2e per ton of product Is local better? EPA (2006) Embodied Emissions in Purchased Materials pounds CO2e per ton of product Production emissions typically dominate (transportation doesn’t) EPA (2006), DEQ (2009) Embodied Emissions in Purchased Materials Imported vs. local rice? Pretty and Ball (2001), DEQ (2009) Embodied Emissions in Purchased Materials Carnegie Mellon University: “Meat vs. Miles” Embodied Emissions in Purchased Materials Input-Output LCA Example: Average US Household Food Consumption Total GHG emissions by supply chain tier (c) associated with household food consumption in the United States. Food groups are aggregates of 50 commodities. Published in: Christopher L. Weber; H. Scott Matthews; Environ. Sci. Technol. 2008, 42, 3508-3513. DOI: 10.1021/es702969f Copyright © 2008 American Chemical Society Embodied Emissions in Purchased Materials Country of origin matters (but not for the reason most people think) 160 Carbon Intensity of Industrial Energy, 2003 (US = 100) 140 120 100 80 60 40 20 0 Shui & Harriss (2006) US China Embodied Emissions in Purchased Materials Embodied Energy (MJ per bag) Products are more impactful than packaging 120 100 80 60 40 20 0 Plastic Bag Sightline Institute (2007) Paper Bag Veggie-Based Omnivore Diet Diet Embodied Emissions in Purchased Materials So, Which Product Attributes Are Most Important (from a GHG perspective)? • • • • Energy efficiency Energy use Waste prevention Country of origin Life cycle assessment results trump attributes Less important • Recyclable • Recycled content • Bio-based • Biodegradable (unless discharged to water) • Local • Packaging attributes Embodied Emissions in Purchased Materials Thank you! Questions? David Allaway Allaway.david@deq.state.or.us 503-229-5479