The Periodic Table MENDELEEV Old image of periodic table The following slides show the Structure of the atom and how this relates to the Modern Peiodic Table The Atom Nucleus Shell or Orbit Electron The structure of the atom ELECTRON negative, mass nearly nothing NEUTRON neutral, same mass as proton (“1”) PROTON positive, same mass as neutron (“1”) Mass and atomic number Particle Relative Mass Relative Charge Proton Neutron Electron 1 1 0 1 0 -1 MASS NUMBER = number of protons + number of neutrons SYMBOL PROTON NUMBER = number of protons (obviously) How many protons, neutrons and electrons? Periodic table The periodic table arranges all the elements in groups according to their properties. Vertical columns are called GROUPS Mendeleev Horizontal rows are called PERIODS The Periodic Table Fact 1: Elements in the same group have the same number of electrons in the outer shell (this correspond to their group number) H He Li Be B C N O F Na M g Al Si P S Cl Ar K Ca Fe Ni C u Zn Ag Pt E.g. all group 1 metals have __ electron in their outer shell A u Ne Br Kr I Xe H g These elements have __ electrons in their outer shells These elements have __ electrons in their outer shell The Periodic Table Fact 2: As you move down through the periods an extra electron shell is added: E.g. Lithium has 3 electronHin the configuration 2,1 He Li Be B C N O F Na M g Al Si P S Cl Ar K Ca Sodium has 11 electrons inFethe Ni configuration 2,8,1 Pt Potassium has 19 electrons in the configuration __,__,__ C u Zn Ag A u Br Kr I H g Ne Xe Fact 3: Most of the elements are metals: The Periodic Table H These elements are metals He Li Be B C N O F Na M g Al Si P S Cl Ar K Ca Fe Ni C u Zn Ag Pt A u This line divides metals from nonmetals Ne Br Kr I Xe H g These elements are non-metals Fact 4: (Most important) All of the elements in the same group have similar PROPERTIES. This is how I thought of the periodic table in the first place. This is called PERIODICITY. The Periodic Table H He Li Be B C N O F Na M g Al Si P S Cl Ar K Ca Fe Ni C u Zn Br Kr Ag 1 metals. They all: I E.g. consider the group 1) Are soft Pt A u H g 2) Can be easily cut with a knife 3) React with water Ne Xe Group 0 – The Noble gases He Ne Ar Kr Xe Rn The Nobel gases • The Nobel gases have full outer shells and they are found in group 0 of the periodic table. Helium, Neon, Argon, Krypton, Xenon and Radon. Group 0 • • • • • • • These are the noble gases. They have complete electron shells. The electron shells are full. They are unreactive. They are inert. They do not react. They include, Helium, Neon, Argon, Krypton, Xenon and Radon Group 0 – The Noble gases Some facts… 1) All of the noble gases have a full outer shell, so they are very _____________ 2) They all have low melting and boiling points 3) They exist as single atoms rather then diatomic molecules 4) Helium is lighter then air and is used in balloons and airships (as well as for talking in a silly voice) 5) Argon is used in light bulbs (because it is so unreactive) and argon , krypton and neon are used in fancy lights The Atom Helium Proton Electron Neutron Helium has two electrons, two protons and two neutrons The Atom Neon Protons Neutrons Neon has ten electrons, ten protons and ten neutrons. Electrons Group 1 – The alkali metals Li Na K Rb Cs Fr The Alkali metals • Lithium, Sodium and Potassium have one electron in their outer shell and this is why they are found in group one of the periodic table. Group 1 • Lithium, sodium and potassium are all in group 1. • They all have one electron in the outer shell. • They are all metals. • They react with group 7 to form metal halides. Group 1 – The alkali metals Some facts… 1) These metals all have ___ electron in their outer shell 2) Reactivity increases as you go _______ the group. This is because the electrons are further away from the _______ every time a _____ is added, so they are given up more easily. 3) They all react with water to form an alkali (hence their name) and __________, e.g: Potassium + water 2K(s) + 2H2O(l) potassium hydroxide + hydrogen 2KOH(aq) + Words – down, one, shell, hydrogen, nucleus H2(g) The Atom Lithium Protons Neutrons Electrons The Atom Sodium Protons Electrons Neutrons Sodium has eleven electrons, eleven protons and twelve neutrons. Group 7 – The halogens F Cl Br I At The Halogens • Fluorine, Chlorine, Bromine and Iodine are the Halogens and they all have seven electrons in their outer shell. This is why they are found in group 7 of the periodic table. Group 7 • Fluorine ,Chlorine, Bromine and Iodine. • They all have 7 electrons in their outer shell. • They are all coloured. • They form metal halides with group 1 metals. Group 7 – The Halogens 1) Reactivity DECREASES as you go down the group Decreasing reactivity Some facts… (This is because the electrons are further away from the nucleus and so any extra electrons aren’t attracted as much). 2) They exist as diatomic molecules (so that they both have a full outer shell): Cl Cl 3) Because of this fluorine and chlorine are liquid at room temperature and bromine is a gas Halogens Name Colour Fluorine Pale Yellow State Gas M.P. -220 B.P. -188 Chlorine Green Gas -101 -34 Bromine Brown Liquid -7 59 Iodine Solid 114 184 Slate grey The Atom Fluorine Protons Electrons Neutrons Fluorine has nine electrons, nine protons and ten neutrons. Uses of the Halogens • Fluorine is put into water supplies to kill harmful bacteria and to help keep teeth healthy. • Chlorine is used in swimming pools to bacteria in the water. • Bromine is used in pesticides. Silver bromide is used in photography. • Iodine is an antiseptic on cuts and grazes. The halogens – some reactions 1) Halogen + metal: + + Na Cl Halogen + metal Cl Na ionic salt 2) Halogen + non-metal: H + Cl Halogen + non-metal Cl H covalent molecule Reactions • • • • • • Sodium and Chlorine react to form Sodium Chloride. Iron and Chlorine react to form Iron Chloride. 2Na + Cl2 2NaCl. Fe + Cl2 FeCl2. Displacement • Fluorine can displace Chlorine, Bromine and Iodine. F Cl Br I Displacement • Chlorine can displace Bromine and Iodine but it cannot displace Fluorine Cl Br I F Displacement • Bromine can displace Iodine but it cannot displace Fluorine or Chlorine Br I F Cl Displacement • Iodine cannot displace Iodine Fluorine, Chlorine or Bromine I F Cl Br Fluorine reacts with sodium chloride. Which equation is correctly shows this reaction? • • • F2 + 2Na 2NaF F + Na NaF 2F + 2Na 2NaF Which will displace? • • • • • • • 2NaF + Cl2 Yes or No 2NaBr + Cl2 Yes or No 2KI + I2 Yes or No 2LiCl + I2 Yes or No 2NaBr + I2 Yes or No 2NaBr + F2 Yes or No Cl2 + 2NaBr Yes or No