Some Challenges in Thermoscience Research and Application Potentials Energy Ecology Economy Tsinghua University, XJTU, and HUST China 2013: Beijing, Xi’an, Wuhan, June 14-28, 2013 Prof. M. Kostic Mechanical Engineering NORTHERN ILLINOIS UNIVERSITY www.kostic.niu.edu Slide 1 Some Challenges in Thermoscience Research and Application Potentials Energy Ecology Economy Institute of Engineering Thermophysics Tsinghua University Beijing, China, June 17, 2013 Prof. M. Kostic Mechanical Engineering NORTHERN ILLINOIS UNIVERSITY www.kostic.niu.edu Slide 2 Some Challenges in Thermoscience Research and Application Potentials Energy Ecology Economy School of Energy and Power Engineering Xi’an Jiaotong University Xi’an, China, June 24, 2013 Prof. M. Kostic Mechanical Engineering NORTHERN ILLINOIS UNIVERSITY www.kostic.niu.edu Slide 3 Some Challenges in Thermoscience Research and Application Potentials Energy Ecology Economy School of Energy and Power Engineering Huazhong University of Science and Technology Wuhan, China, June 26, 2013 Prof. M. Kostic Mechanical Engineering NORTHERN ILLINOIS UNIVERSITY www.kostic.niu.edu Slide 4 Hello: Thank you for the opportunity to present a holistic, phenomenological reasoning of some challenging issues in Thermoscience. www.kostic.niu.edu 5 Slide 5 Among distinguished invites were five keynote speakers from China and seven international keynote speakers: three from the USA and one each from Japan, United Kingdom, Singapore, and Spain; including four Academicians and six university Presidents/vice-presidents. It has been my great pleasure and honor to meet Profs. ZY Guo, WQ Tao and other distinguished colleagues, and even more so to visit again and meet friends now! www.kostic.niu.edu Slide 6 Thank you for invitation … …It is my pleasure and honor to share my knowledge and experience and to learn about the Chinese people, research, education and culture www.kostic.niu.edu Slide 7 www.kostic.niu.edu Slide 8 www.kostic.niu.edu Slide 9 www.kostic.niu.edu Slide 10 Electrical Engineering Industrial and Systems Engineering Mechanical Engineering Technology & Eng. Tech. www.kostic.niu.edu Slide 11 www.kostic.niu.edu Slide 12 www.kostic.niu.edu Slide 13 www.kostic.niu.edu Slide 14 Some Challenges in Thermoscience: More details in my following lectures/discussions • • • Nature of Thermo-Mechanical energy transfer (Electro-magnetic …Photons, Phonons, Thermons) Thermal energy concept as property (decoupling from thermo-mechanical internal energy): Caloric, Exergy, Entransy Back to Caloric (Thermal Energy), caloric processes (conserved caloric regardless of irreversibility if complete)…Heat is Unique (all else is Work) and Universal (all works ultimately dissipate/convert to heat) • • • • • • • Reversible adding work or heat results in different final states (different types of internal energies). However, reversible work between two states path is independent! Entropy is dimensionless ratio (!) since temperature is a micro-particle kinetic energy! Isentropic processes conserve entropy, thus when a work is extracted the remaining thermal energy at lower temperature is at constant (conserved) entropy. Produced entropy cannot be “destroyed” by any means, it could only be transferred with thermal energy, thus entropy production is irreversible! Entropy is increasing with irreversible conversion of any work-potential (including thermal work potential) the latter due to non-equilibrium, thus terminal and maximum at equilibrium. Carnot principle defines the both: work potential and reversible heat transfer Useful or Available Energy - Exergy is additive state function for a given reference (dead state of surrounding-ultimate equilibrium: Po, To, MUo), just like other state functions (energy, etc.). www.kostic.niu.edu Slide 15 Energy and Environmental Landscape … … could be substantially enhanced with improved efficiency and diversification of energy sources, devices and processes. We are now in transitional era where further progress cannot be continued with existing technology. The difficulties that will face every nation and the world in meeting energy needs over the next several decades will be more challenging than what we anticipate now. www.kostic.niu.edu Slide 16 Challenges are many … … but so are potentials for innovative solutions based on further development of science and technology. As new paradigms are to be developed, the thermoscience (thermodynamics and heat transfer), being “the heart and soul” of all energy sciences, holds the key to provide vision and check-and-balance methods for optimizations and further innovations. www.kostic.niu.edu Slide 17 From Fundamentals to Innovations The fundamental Laws of Thermodynamics and comprehensive analysis and optimization are the most effective way for the improvements and could lead to innovative development. … our objective is to motivate young researchers/students to be excited and be persistent to reason and value fundamentals in order to innovate www.kostic.niu.edu Slide 18 The Fundamental Laws of Nature • The fundamental Laws of Nature are exceptionally simple but they appear in exceptionally many different forms, which explain universality and unity of simplicity and complexity, but also difficulties to recognize simplicity in complex diversity www.kostic.niu.edu Slide 19 Cause Is Adequate to the Effect … • The philosophic axiom "causa aequat effectum," [the cause is adequate to the effect] is traced to ancient philosophers and represents the most universal and fundamental law of nature, including existence and future, i.e. past and future transformations. www.kostic.niu.edu Slide 20 Phenomenological Laws • Furthermore, the phenomenological Laws of Thermodynamics, and in general, have much wider, including philosophical significance and implication, than their simple expressions based on the experimental observations – they are the Fundamental Laws of Nature. • They are defining and unifying our comprehension of all existence in universe and all changes in time (all processes, including life). Einstein stated that, “After mathematicians invaded (and explained) my Theory of Relativity, I do not understand it any more.” www.kostic.niu.edu Slide 21 The Fundamental Laws of Nature: The Laws of Thermodynamics have much wider, including philosophical significance and implication, than their simple expressions based on the experimental observations, they are: The Fundamental Laws of Nature: • The Zeroth (equilibrium existentialism), • The First (conservational transformationalism), • The Second (forced-directional, irreversible transformationalism), • The Third (unattainability of emptiness). The Laws are defining and unifying our comprehension of all existence and transformations in the universe. Solving practical problems helps "really" understand theory, so that one can then solve other problems more effectively. If we can not solve a problem, that "proves" we do not "truly" understand theory -- the key is integration/synergy of theory and practice, the "true" UNDERSTANDING! If one thinks theory is boring, that means one is not really interested in understanding to solve practical problems. www.kostic.niu.edu Slide 22 Thermal energy versus Internal energy concepts in Thermodynamics: The T, Cth, Entropy are related to internal thermal energy, not any internal energy (the latter obvious for incompressible substances), but is more subtle for compressible gases due to coupling of internal thermal energy (transferred as heat TdS) and internal elastic-mechanical energy (transferred as work PdV). Entropy is NOT related to any other internal energy type, but thermal (unless the former is converted/dissipated to thermal in a process). www.kostic.niu.edu Slide 23 Mechanical and Thermal Energies Are Distinguishable Within Internal Energy! DU12s= DU12v U2s=U2v U=Uth+Umech(elastic) T2s=T2v (for Ideal Gas) BUT! 2s≠2v Ps>Pv; Ss<Sv Vs<Vv, Uth,s<Uth,v & Umech,s>Umech,v Exs>Exv etc. FORCE applied or HEAT applied © M. Kostic 2009 January 10-12 Slide 24 Thermal and Mechanical energies 1 kJ heating is NOT the SAME as 1 kJ compressing! Thermal and Mechanical energies are distinguishable, NOT the same Internal energy (as argued by some)! © M. Kostic 041115 Slide 25 Heat Is Transfer of Thermal Energy • Philosophically, you cannot transfer something that does not exist. For example, you cannot transfer water unless you have water. You cannot transfer energy (type) without having it somewhere (stored) to transfer and store it somewhere else. In the process (while transferring) you may convert/reprocess (modify the "original structure") while conserving the underlying substructure (true elementary particles): existential conservationism. • Denying existence of thermal energy is the same as denying existence of heat transfer! © M. Kostic 041115 Slide 26 Useful Energy: Work potential, Exergy (and Entransy) concept(s) Two systems in non-equilibrium have potential of extracting work (useful energy). The maximum work potential is if they are reversibly brought to mutual equilibrium while the work is extracted (entropy is conserved, thus over-all isentropic), otherwise part or in-whole that work potential will dissipate via heat to thermal energy and generate entropy. If one system is fixed, an infinite thermal reservoir and taken as a reference (like environment at To & Po) then that maximum work potential depends on the other system state, i.e., it is independent of the process path, thus the system property, called Exergy. Note that there will be a need to reversibly exchange heat (and entropy) at the reference temperature or reversibly regenerate heat internally, except for isentropic processes. www.kostic.niu.edu Slide 27 Note : QIrr ο½ QGen ο½ ο€WLoss ο½ TRef SGen ( any) www.kostic.niu.edu Slide 28 All reversible processes are “over-all isentropic” (entropy conserved)! Exergy analysis to minimize and optimize irreversibility Entransy analysis to maximize and optimize heat transfer www.kostic.niu.edu Slide 29 www.kostic.niu.edu Slide 30 The Concept of "Entransy" May Be More Important Than What It Appears at First … but it has to be "properly" related to existing concepts of Thermal energy (not precisely defined yet, see elsewhere), Exergy and Entropy, as well as irreversibility and reversibility. Entransy concept and analysis have some unique advantages over other approaches. There is a need to define Entransy as a property (how it relates to other thermodynamic properties) and as process energy flux (how it relates to heat & work transfer and entropy transfer & generation). We also could advance and synergize your "Thermomass" concept with my work in that area. www.kostic.niu.edu Slide 31 What is Energy ? More important than what it appears to be If one could expel all energy out of a physical system … … then empty, nothing will be left … … so ENERGY is EVERYTHING … E=mc2 Mass (m) and energy (E) are manifestation of each other and are equivalent; they have a holistic meaning of “mass-energy” www.kostic.niu.edu Slide 32 What is Energy ? “From the Sovereign Sun to the deluge of photons out of the astounding compaction and increase of power-density in computer chips … Mass-Energy represents motion of a system structure, i.e., its representative particles at different space and time scales, and ultimately motion of photons. www.kostic.niu.edu Slide 33 Humanity’s Top Ten Problems for next 40 years 1. ENERGY (critical for the rest nine) 2. 3. 4. 5. 6. 7. 8. 9. 10. Water Food Environment Poverty Terrorism & War Disease Education Democracy Population 2013: Over 7 Billion People 2050: ~ 10 Billion ( 1010 +) People www.kostic.niu.edu Slide 34 The two things are certain even if man-made Global Warming is debatable • (1) the world population and their living-standard expectations will substantially increase (over 7 billion people now, in 50 years 10-11 billion - energy may double) • (2) fossil fuels’ economical reserves, particularly oil and natural gas, will substantially decrease (oil may run out in 30-50 years) www.kostic.niu.edu Slide 35 Efficient and Sustainable Energy Energy/Economy/Ecology Challenges and Opportunities • We are in 'energy transition era' from fossil fuels to alternative (including nuclear) and renewable energy sources (including solar, biomass, hydro, wind, and geothermal). Efficient and Sustainable Energy Energy/Economy/Ecology Challenges and Opportunities • In this transitional era, the energy CONSERVATION and EFFICIENCY (including energy storage) is the most “effective" and thus the most viable/profitable option in initial and mid-range period, until alternative and renewable energy infrastructure is developed and matured, and even more so beyond. Efficient and Sustainable Energy Energy/Economy/Ecology Challenges and Opportunities Global/National Urgency: • Energy issue is among the highest global and national priority: (economical, ecological and security). • Funding/Stimulus for education, research, development and applications. Efficient and Sustainable Energy Energy/Economy/Ecology Challenges and Opportunities Other Institutions and Existing Activities: • Many educational and other institutions and industry have been positioning their strategic and development activities in energy related area • Campus Green Sustainable Initiatives • Energy-related Educational Programs • Energy-related Research, Development and Application Efficient and Sustainable Energy 134 Million Energy/Economy/Ecology Challenges and Opportunities Efficient and Sustainable Energy Energy/Economy/Ecology Challenges and Opportunities Efficient and Sustainable Energy Energy/Economy/Ecology Challenges and Opportunities Efficient and Sustainable Energy Energy/Economy/Ecology Challenges and Opportunities Prof. Kostic’s Research & Scholarly Interests and Activities Fundamentals and Application of Energy www.kostic.niu.edu Slide 44 Efficient and Sustainable Energy Energy/Economy/Ecology Challenges and Opportunities Efficient and Sustainable… economically Energy Energy/Economy/Ecology Challenges and Opportunities Efficient and Sustainable Energy Energy/Economy/Ecology Challenges and Opportunities Thermodynamic Efficiency: Integration and Optimization Nanofluids Research: Critical Issues & Application Potentials Follow-up and update from original ASME Presentations in Honolulu, Hawaii Advanced Flow and Heat Transfer Fluids Resistively Heated Crucible Cooling System M.Liquid Kostic and Sir Harry Kroto, Nobel Laureate Deionized water prior to Oil prior to (left) and Presented at: University of Hawaii at Manoa after (right)and evaporation (left) and after (right) ASME Multifunctional Nanocomposite Conference of Int. Cu nanoparticles dispersion of Al2O3 2006 nanoparticles Prof. M. Kostic Mechanical Engineering www.kostic.niu.edu 49 NORTHERN ILLINOIS UNIVERSITY Critical Issues in Nanofluids Research and Application Potentials Advanced Flow and Heat Transfer Fluids Presented at: Resistively Heated Crucible Norwegian University for Science and Technology - NTNU Liquid NTNU Nanomechanical Lab, Trondheim, Norway, 16 May 2012 Deionized Presentedwater at: prior to Oil prior to (left) and after -(rigKTH ht) evaporation after (right) Royal Institute(left) ofandTechnology of Cu nanoparticles dispersion of Al2O 3 Nanocharacterization Center – Functional Materials, Stockholm, Sweden, 21 May 2012 nanoparticles Cooling System Prof. M. Kostic Mechanical Engineering 50 NORTHERN ILLINOIS UNIVERSITY www.kostic.niu.edu One-Step Nanofluid Production Improvement NIU in Collaboration with Argonne National Laboratory S. Choi J. Hull, and others Insulated and vertically-adjustable boatheater evaporator Rotating drum with moving nanofluid film Nitrogen cooling plate with coils and fins FIG. 2: Proposed improvements for the one-step, direct-evaporation nanofluid production apparatus www.kostic.niu.edu/DRnanofluids Locking Nut (calibrated weight for required spring tension) Power Supply Connector To the Data Acquisition System Connectors and Calibration Guage Holder Special Shape Sliding Fit Hole (avoids turning of spring) D-Type Connector Cell Cap with Rectangular Cuts (for wire outlet) Hot-Wire Voltage Output Wires T-Type Thermocouples Tension Spring (spring constant 0.02 N/mm) Constant Voltage Input Wires Sliding Tube (aligns the hot-wire) Wire Holder Striped Stranded Copper Wire (to provide flexiblity and avoid backlash) Hot-Wire Guiding Block (off-centered) Inner Wire Guide Soldered Joint # 1 Wire Protection Clip # 1 Outer Shell (test-fluid reservoir) Teflon Coated Platinum Hot-Wire Ø 0.0508 mm Coating Thickness 0.0245 mm Measurement Section 149.2 mm Best Paper for the 6th WSEAS International Conference on HEAT and MASS TRANSFER (HMT'09) Ningbo, China, January 10-12, 2009 Computerized, Transient Hot-Wire Thermal Conductivity (HWTC) Apparatus for Nanofluids, pp.71-78 M. Kostic, Kalyan C. Simham Calibration Gauge (to guard spring rod and calibrate the spring tension) Spring Rod with Threading Clients: Aegis Technologies www.aegistech.net Advanced Cooling Technology Applications http://www.acta-llc.com/ Soldered Joint # 2 Off-Centered Alignment Ring Teflon Sealing www.kostic.niu.edu/DRnanofluids Cell Base Plate Inner Semi-Circular Hot-Wire Holder Wire Protection Clip # 2 Threaded Nut Thermocouple at the Bottom L45° Wire Protection Clip # 3 Insulated Copper Wire Ø 0.254 mm Threaded Hole in Base Plate (Assembly and Cleaning) Nanofluid Flow & Heat Transfer Apparatus www.kostic.niu.edu/DRnanofluids Premature Judgment … • The nanofluids were hyped-up in the past, but it would be a mistake to hype-down nanofluids now and make premature judgments based on inconsistent and incomplete research to-date. 54 www.kostic.niu.edu Electromagnetic Nature of Thermo-Mechanical Mass-Energy Transfer , during “believed-massless” heat conduction or mechanical work transfer, there has to be electromagnetic, i.e., photon mass-energy propagation (since they are not gravitational and not nuclear interactions) through involved material structures, from a mass-energy source to a sink system. Otherwise, the mass-energy equivalence and Physics law of forced interactions will be violated! International Forum on Frontier Theories in Thermal Science Tsinghua University, Beijing, China, December 18-20, 2011 Prof. M. Kostic Mechanical Engineering NORTHERN ILLINOIS UNIVERSITY www.kostic.niu.edu Slide 55 Fig.1: Electromagnetic Nature of ThermoMechanical Mass-Energy Transfer Due to Photon Diffusive Re-Emission and Propagation: Steady-state, mass-energy transfer is depicted through heat conduction plate (right-above) and rotating shaft (right-below). Energy transfer (i.e., Einstein’s mass-energy equivalency transfer, πΈπ‘πππ = ππ‘πππ π 2 ) has to be electromagnetic by photon transfer, either as photon electromagnetic waves on-long range through space/vacuum (ππππ = ππππ π 2 ), or photon “on-contact” transfer within material structures, e.g., through heat conduction plate (rt.-above) and turbine shaft work (rt.- below). www.kostic.niu.edu Otherwise, Einstein’s mass-energy equivalency and the fundamental force/interactions in Physics will be violated. Slide 56 “The Second Law of Thermodynamics is considered one of the central laws of science, engineering and technology. For over a century it has been assumed to be inviolable by the scientific community. Over the last 10-20 years, however, more than two dozen challenges to it have appeared in the physical literature - more than during any other period in its 150-year history.” Second Law Conference: Status and Challenges with Prof. Sheehan in Sun Diego, CA June 2011 Slide 57 © M. Kostic <www.kostic.niu.edu> The Second Law Symposium has been a unique gathering of the unorthodox physicist and inventors (to avoid using a stronger word) www.kostic.niu.edu Slide 58 The “Key Fundamental Concepts” are much more important than what they appear to be Fig. 8: Significance of the Carnot’s reasoning of reversible cycles is in many ways comparable with the Einstein’s relativity theory in modern times. The Carnot Ratio Equality is much more important than what it appears at first. It is probably the most important equation in Thermodynamics and among the most important equations in natural sciences. www.kostic.niu.edu Slide 59 20 December 2013 www.kostic.niu.edu Slide 60 Qcal=Qrev+Wloss=Qrev+Qdiss Entropy, the thermal displacement property, dS=dQrev/T (or dQcal/T) with J/K unit, is “a measure” of thermal dynamic-disorder or thermal randomness, and may be expressed as being related to logarithm of number of “all thermal, dynamic-microstates”, or to their logarithmic-probability or uncertainty, that corresponds, or are consistent with the given thermodynamic macrostate. Note that the meanings of all relevant adjectives are deeply important to reflect reality and as such it has metaphoric description for real systems. www.kostic.niu.edu Slide 61 A system form and/or functional order/disorder: A system form and/or function related order or disorder is not thermal-energy order/disorder, and the former is not the latter, thus not related to Thermodynamic entropy. Entropy is always generated (due to ‘energy dissipation’) during production of form/function order or disorder, including information, i.e., during any process of creating or destroying, i.e., transforming any material structure. Expanding entropy to any type disorder or information is unjustified, misleading and plain wrong. www.kostic.niu.edu Slide 62 Entropy and Disorder … S=S(T,V) not of other type of disorder: If Tleft=Tright and Vleft=Vright ο Sleft=Sright Entropy refers to dynamic thermal-disorder of its micro structure (which give rise to temperature, heat capacity, entropy and thermal energy. It does not refer to form-nor functionaldisorder of macro-structure: For example, the same ordered or piled bricks (see above) at the same temperature have the same entropy (the same Thermodynamic state)! www.kostic.niu.edu Slide 63 The Boltzmann constant is a conversion factor: Temperature is (random kinetic) thermal-energy of a (microthermal) particle (with Boltzmann constant being the conversion factor between micro-thermal energy and macrotemperature), … thus entropy is ration between macro (multi-particle) thermal energy and a representative particle thermal-energy, thus dimensionless. ππ΅ = πΈπ‘β ππππ‘ππππ [ _ π½ ππππ‘ππππ ] πΈπ‘β π΄ππ _ ππ’ππππ πππ‘ πΈπ ππ ππππ‘ππππ [πΎ] = πΈπ ππ ππππ‘ππππ _ _ _ = [J/(Kο πππ‘ππ’ππππ)] _ The thermal-energy used for entropy is without its ‘useful’ part or work potential, thus include pressure-volume influence. In that regard, a single particle entropy without thermal-interactions is zero (no random-thermal motion), but also infinity (as if in infinite volume, taking forever to thermally interact). © M. Kostic 2009 January 10-12 Slide 64 Entropy Generation (Production) Sgen Entropy Generation (Production) is always irreversible in one direction only, occurring during a process within a system and stored as entropy property. Entropy cannot be destroyed under any circumstances, since it will imply spontaneous heat transfer from lower to higher temperature or imply higher efficiency than the ideal Carnot cycle engine www.kostic.niu.edu Slide 65 YES! Miracles are possible ! It may look ‘perpetuum mobile’ but miracles are real too … Things and Events are both, MORE but also LESS complex than how they appear and we ‘see’ them -- it is natural simplicity in real complexity … we could not comprehend energy conservation until 1850s: (mechanical energy was escaping “without being noticed how”) … we may not comprehend now new energy conversions and wrongly believe they are not possible: (“cold fusion” seems impossible for now … ?) …….Let us keep our eyes and our minds ‘open’ ……….. … but, the miracles are until they are comprehended and understood ! www.kostic.niu.edu Slide 66 www.kostic.niu.edu Slide 67 EEE-Global & Physics articles • More Encyclopedia Articles www.kostic.niu.edu Slide 68 Global Energy and Future: Importance of Energy Conservation and Renewable and Alternative Energy Resources Solar 1.37 kW/m2, but only 12% over-all average 165 W/m2 www.iea.org/publications/freepublications/ * Key World Energy Stats 2000 kcal/dayο»100 Watt World over 7 billion 2,400 Watt/c 350 Wel /c USA over 0.3 billion 10,000 Watt/c 1,500 Wel /c www.kostic.niu.edu Slide 69 World automobile population is expected to grow substantially Source: OTT Analytic Team www.kostic.niu.edu Slide 70 Vehicle Energy Efficiencies … from 15-25 MPG Classical … to 50 MPG Hybrid It is possible !!! www.kostic.niu.edu Slide 71 Coal Energy Must Be Efficient to be competitive … from 30% Classical … to 60% Combined Cycle Gas/Steam Turbine Power Plant or even 85% Combined Power-Heat Plant www.kostic.niu.edu Slide 72 Efficient: do MORE with LESS Improve true (2nd Law) efficiency by conserving energy potentials: REGENERATE before “diluting” and loosing it! Low efficiency Power Indirectly Regenerated Heat & CO2 “Waste” Heat & Directly Regenerated Heat CO2 & CO2 www.kostic.niu.edu High Efficiency Slide 73 About 20% About 0.2 % … also first steam engine www.kostic.niu.edu Slide 74 www.kostic.niu.edu Slide 76 www.kostic.niu.edu Slide 77 www.kostic.niu.edu Slide 78 www.kostic.niu.edu Slide 79 The energy “difficulties” … • (1) will be more challenging than what we anticipate now • (2) NO traditional solutions • (3) New knowledge, new technology, and new living habits and expectations will be needed www.kostic.niu.edu Slide 80 What Are We Waiting For? • Another Energy Crisis ? • A Global Environmental Problem? • or Leadership www.kostic.niu.edu Slide 81 The biggest single challenge for the next few decades by 2050 • (1) ENERGY for 1010 people • (2) At MINIMUM we need additional 10 TeraWatts (150 Mill. BOE/day) from some new clean energy source • We simply can not do this with current technology! • We need Leadership www.kostic.niu.edu Slide 82 How To “Use” Energy ? www.kostic.niu.edu Slide 83 Energy Future Outlook: …a probable scenario … in the wake of a short history of fossil fuels’ abundance and use (a bleep on a human history radar screen), the following energy future outlook is possible… 1. Creative adaptation and innovations, with change of societal and human habits and expectations (life could be happier after fossil fuels’ era) 2. Intelligent hi-tech, local and global energy management in wide sense (to reduce waste, improve efficiency and quality of environment and life) 3. Energy conservation and regeneration have unforeseen (higher order of magnitude) and large potentials, particularly in industry (also in transportation, commercial and residential sectors) 4. Nuclear energy and re-electrification for most of stationary energy needs 5. Cogeneration and integration of power generation and new industry at global scale (to close the cycles at sources thus protecting environment and increasing efficiency) 6. Renewable biomass and synthetic hydro-carbons for fossil fuel replacement (mobile energy, transportation, and chemicals) 7. Advanced energy storage (synthetic fuels, advanced batteries, hydrogen,…) 8. Redistributed solar-related and other renewable energies (to fill in the gap…) www.kostic.niu.edu Slide 84 Energy Future Outlook: …a probable scenario … in the wake of a short history of fossil fuels’ abundance and use (a bleep on a human history radar screen), the following energy future outlook is possible… 1. Creative adaptation and innovations, with change of societal and human habits and expectations (life could be happier after fossil fuels’ era) 2. Intelligent hi-tech, local and global energy management in wide sense (to reduce waste, improve efficiency and quality of environment and life) 3. Energy conservation and regeneration have unforeseen (higher order of magnitude) and large potentials, particularly in industry (also in transportation, commercial and residential sectors) 4. Nuclear energy and re-electrification for most of stationary energy needs 5. Cogeneration and integration of power generation and new industry at global scale (to close the cycles at sources thus protecting environment and increasing efficiency) 6. Renewable biomass and synthetic hydro-carbons for fossil fuel replacement (mobile energy, transportation, and chemicals) 7. Advanced energy storage (synthetic fuels, advanced batteries, hydrogen,…) 8. Redistributed solar-related and other renewable energies (to fill in the gap…) www.kostic.niu.edu Slide 85 Energy Future Outlook: …a probable scenario … in the wake of a short history of fossil fuels’ abundance and use (a bleep on a human history radar screen), the following energy future outlook is possible… 1. Creative adaptation and innovations, with change of societal and human habits and expectations (life could be happier after fossil fuels’ era) 2. Intelligent hi-tech, local and global energy management in wide sense (to reduce waste, improve efficiency and quality of environment and life) 3. Energy conservation and regeneration have unforeseen (higher order of magnitude) and large potentials, particularly in industry (also in transportation, commercial and residential sectors) 4. Nuclear energy and re-electrification for most of stationary energy needs 5. Cogeneration and integration of power generation and new industry at global scale (to close the cycles at sources thus protecting environment and increasing efficiency) 6. Renewable biomass and synthetic hydro-carbons for fossil fuel replacement (mobile energy, transportation, and chemicals) 7. Advanced energy storage (synthetic fuels, advanced batteries, hydrogen,…) 8. Redistributed solar-related and other renewable energies (to fill in the gap…) www.kostic.niu.edu Slide 86 Energy Future Outlook: …a probable scenario … in the wake of a short history of fossil fuels’ abundance and use (a bleep on a human history radar screen), the following energy future outlook is possible… 1. Creative adaptation and innovations, with change of societal and human habits and expectations (life could be happier after fossil fuels’ era) 2. Intelligent hi-tech, local and global energy management in wide sense (to reduce waste, improve efficiency and quality of environment and life) 3. Energy conservation and regeneration have unforeseen (higher order of magnitude) and large potentials, particularly in industry (also in transportation, commercial and residential sectors) 4. Nuclear energy and re-electrification for most of stationary energy needs 5. Cogeneration and integration of power generation and new industry at global scale (to close the cycles at sources thus protecting environment and increasing efficiency) 6. Renewable biomass and synthetic hydro-carbons for fossil fuel replacement (mobile energy, transportation, and chemicals) 7. Advanced energy storage (synthetic fuels, advanced batteries, hydrogen,…) 8. Redistributed solar-related and other renewable energies (to fill in the gap…) www.kostic.niu.edu Slide 87 Energy Future Outlook: …a probable scenario … in the wake of a short history of fossil fuels’ abundance and use (a bleep on a human history radar screen), the following energy future outlook is possible… 1. Creative adaptation and innovations, with change of societal and human habits and expectations (life could be happier after fossil fuels’ era) 2. Intelligent hi-tech, local and global energy management in wide sense (to reduce waste, improve efficiency and quality of environment and life) 3. Energy conservation and regeneration have unforeseen (higher order of magnitude) and large potentials, particularly in industry (also in transportation, commercial and residential sectors) 4. Nuclear energy and re-electrification for most of stationary energy needs 5. Cogeneration and integration of power generation and new industry at global scale (to close the cycles at sources thus protecting environment and increasing efficiency) 6. Renewable biomass and synthetic hydro-carbons for fossil fuel replacement (mobile energy, transportation, and chemicals) 7. Advanced energy storage (synthetic fuels, advanced batteries, hydrogen,…) 8. Redistributed solar-related and other renewable energies (to fill in the gap…) www.kostic.niu.edu Slide 88 Energy Future Outlook: …a probable scenario … in the wake of a short history of fossil fuels’ abundance and use (a bleep on a human history radar screen), the following energy future outlook is possible… 1. Creative adaptation and innovations, with change of societal and human habits and expectations (life could be happier after fossil fuels’ era) 2. Intelligent hi-tech, local and global energy management in wide sense (to reduce waste, improve efficiency and quality of environment and life) 3. Energy conservation and regeneration have unforeseen (higher order of magnitude) and large potentials, particularly in industry (also in transportation, commercial and residential sectors) 4. Nuclear energy and re-electrification for most of stationary energy needs 5. Cogeneration and integration of power generation and new industry at global scale (to close the cycles at sources thus protecting environment and increasing efficiency) 6. Renewable biomass and synthetic hydro-carbons for fossil fuel replacement (mobile energy, transportation, and chemicals) 7. Advanced energy storage (synthetic fuels, advanced batteries, hydrogen,…) 8. Redistributed solar-related and other renewable energies (to fill in the gap…) www.kostic.niu.edu Slide 89 Energy Future Outlook: …a probable scenario … in the wake of a short history of fossil fuels’ abundance and use (a bleep on a human history radar screen), the following energy future outlook is possible… 1. Creative adaptation and innovations, with change of societal and human habits and expectations (life could be happier after fossil fuels’ era) 2. Intelligent hi-tech, local and global energy management in wide sense (to reduce waste, improve efficiency and quality of environment and life) 3. Energy conservation and regeneration have unforeseen (higher order of magnitude) and large potentials, particularly in industry (also in transportation, commercial and residential sectors) 4. Nuclear energy and re-electrification for most of stationary energy needs 5. Cogeneration and integration of power generation and new industry at global scale (to close the cycles at sources thus protecting environment and increasing efficiency) 6. Renewable biomass and synthetic hydro-carbons for fossil fuel replacement (mobile energy, transportation, and chemicals) 7. Advanced energy storage (synthetic fuels, advanced batteries, hydrogen,…) 8. Redistributed solar-related and other renewable energies (to fill in the gap…) www.kostic.niu.edu Slide 90 Energy Future Outlook: …a probable scenario … in the wake of a short history of fossil fuels’ abundance and use (a bleep on a human history radar screen), the following energy future outlook is possible… 1. Creative adaptation and innovations, with change of societal and human habits and expectations (life could be happier after fossil fuels’ era) 2. Intelligent hi-tech, local and global energy management in wide sense (to reduce waste, improve efficiency and quality of environment and life) 3. Energy conservation and regeneration have unforeseen (higher order of magnitude) and large potentials, particularly in industry (also in transportation, commercial and residential sectors) 4. Nuclear energy and re-electrification for most of stationary energy needs 5. Cogeneration and integration of power generation and new industry at global scale (to close the cycles at sources thus protecting environment and increasing efficiency) 6. Renewable biomass and synthetic hydro-carbons for fossil fuel replacement (mobile energy, transportation, and chemicals) 7. Advanced energy storage (synthetic fuels, advanced batteries, hydrogen,…) 8. Redistributed solar-related and other renewable energies (to fill in the gap…) www.kostic.niu.edu Slide 91 Energy Future Outlook: …a probable scenario … in the wake of a short history of fossil fuels’ abundance and use (a bleep on a human history radar screen), the following energy future outlook is possible… 1. Creative adaptation and innovations, with change of societal and human habits and expectations (life could be happier after fossil fuels’ era) 2. Intelligent hi-tech, local and global energy management in wide sense (to reduce waste, improve efficiency and quality of environment and life) 3. Energy conservation and regeneration have unforeseen (higher order of magnitude) and large potentials, particularly in industry (also in transportation, commercial and residential sectors) 4. Nuclear energy and re-electrification for most of stationary energy needs 5. Cogeneration and integration of power generation and new industry at global scale (to close the cycles at sources thus protecting environment and increasing efficiency) 6. Renewable biomass and synthetic hydro-carbons for fossil fuel replacement (mobile energy, transportation, and chemicals) 7. Advanced energy storage (synthetic fuels, advanced batteries, hydrogen,…) 8. Redistributed solar-related and other renewable energies (to fill in the gap…) www.kostic.niu.edu Slide 92 www.kostic.niu.edu Slide 93 More information at: www.kostic.niu.edu/energy Solar 1.37 kW/m2, but only 12% over-all average 165 W/m2 However, regardless of imminent shortages of fossil fuels, the outlook for future energy needs is encouraging. Energy conservation “with existing technology” (insulation, regeneration, cogeneration and optimization with energy storage) has real immediate potential to substantially reduce energy dependence on fossil fuels and enable use of alternative and renewable energy sources. There are many diverse and abundant energy sources with promising future potentials, so 2000 kcal/dayο»100 Watt that mankind should be able to enhance its activities, standard and quality of living, by diversifying energy sources, and by improving energy conversion and utilization efficiencies, while at the same time increasing safety and World Prod. USA Prod. reducing environmental pollution. After all, in the wake of a short history of fossil 12,000 fuels’ abundance and use (a blip on 2,200 Watt/p Watt/p a human history radar screen), the life may be happier after the fossil fuel era! 275 Welec/p 1500 Welec/p More at: www.kostic.niu.edu/energy www.kostic.niu.edu Slide 94 Thank you! Any Questions ? www.kostic.niu.edu Slide 95 Appendices Stretching the mind further … www.kostic.niu.edu Slide 96 Stretching the mind further … Mass may be a special tensor-like quantity due to "over-allisotropic in all-directions" motion of elementary particles (that make up its structure) and thus give rise to inertia if accelerated in any direction, i.e., resisting change of motion in any and all directions with equal components (the isotropic mass inertia). There may be anisotropic masses, with bulk linear or rotational motion, being the extreme cases. Note that fundamental particles (without inertial mass, like photons and similar, but with relativistic masses E/c^2) has to always move with ultimate speed of light in vacuum, and such particles (some yet to be discovered) might be moving (orbiting with twisting, string-like vibration and rotation) within virtually infinitesimal spaces and thus making-up other "massive" so-called elementary particles www.kostic.niu.edu Slide 97 Force and Forcing … Force or Forcing is a process of exchanging useful-energy (forced displacement) with netzero exchange at forced equilibrium. The Second Law provides conditions and limits for process forcing (energy exchange direction www.kostic.niu.edu Slide 98 Deterministic vs. Probabilistic All interactions in nature are physical and based on simple cause-and-effect conservation laws, thus deterministic and should be without any exceptional phenomenon. Due to diversity and complexity of large systems, we would never be able to observe deterministic phenomena with full details but have to use holistic and probabilistic approach for observation; therefore, our observation methodology is holistic and probabilistic, but phenomena have to be deterministic, not miraculous nor probabilistic www.kostic.niu.edu Slide 99 Elementary Particles: Electron? There is no proof that an electron, or any other elementary particle, has or does not have a structure. The concept of elementary particle is intrinsically problematic (just because we cannot observe or reason a structure which exhibits certain phenomena, does not mean it does not exist). Past and recent history proved us to be wrong every time. Particularly problematic is the current theory which requires elementary particle annihilation/creation (“miraculous creationism”) while using conservation laws. At the very least (in phenomenological view) the elementary particles should be conserved and be the building structure for other particles and systems. Note that many concepts (in modern physics) are "virtual" entities that are part of the mathematical theory, but are not directly observable. www.kostic.niu.edu Slide Boundary Forces … There is no such thing as a unidirectional force or a force that acts on only one body (no imaginary boundary vectorforces). Put it very simply: a forcing (force-flux cause-and-effect phenomena) acts between an interface of pair of objects (forced interaction: action-reaction, including process-inertial forces), and not on a single object. The Newton Laws and the Laws of Thermodynamics imply that all forces are massenergy interactions (forced displacements with momentum and energy transfer and conservation) between different particulate bodies due to non-equilibrium (available energy or work potential, cause of forcing) towards the equilibrium. www.kostic.niu.edu Slide No Perfect Rigidity … All matter must be somewhat elastic (can be compressed or stretched). If bodies could be perfectly rigid we'd have infinite forces acting with infinite speeds for infinitesimal times (if you pushed on one end of a perfectly rigid stick, the other end would move instantaneously). System components (bodies) that exert forces have to be massive (2nd Newton Law) and with accompanying reaction forces (3rd Newton Law). www.kostic.niu.edu Slide Energy is bound by forced motion … Energy is possessed (thus equilibrium property) by material systems and redistributed (transferred) between and within system(s), due to systems' non-equilibrium, via forceddisplacement interactions (process) towards the equilibrium (equi-partition of energy over mass and space); thus energy is conserved (the 1st Law) but degraded (the 2nd Law). Effects are consequences of Causes except at Equilibrium they are equal (reversible). The existence in space and transformations in time are manifestations of perpetual mass-energy forced displacement processes: with net-zero mass-energy transfer in equilibrium (equilibrium process) and non-zero mass-energy transfer in nonequilibrium (active process) towards equilibrium. System components (particles and bodies) that exert forces have to be massive (2nd Newton Law) and with accompanying reaction forces (3rd Newton Law). www.kostic.niu.edu Slide Processes … Miracles "Nothing occurs locally nor in the universe without mass-energy exchange/conversion and irreversible entropy production. It is crystal-clear (to me) that all confusions related to the far-reaching fundamental Laws of Thermodynamics, and especially the Second Law (Abstract), are due to the lack of their genuine and subtle comprehension." The miracles are until they are comprehended and understood. www.kostic.niu.edu Slide The Concept of "Entransy" May Be More Important Than What It Appears at First … but it has to be "properly" related to existing concepts of Thermal energy (not precisely defined yet, see elsewhere), Exergy and Entropy, as well as irreversibility and reversibility. Entransy concept and analysis have some unique advantages over other approaches. There is a need to define Entransy as a property (how it relates to other thermodynamic properties) and as process energy flux (how it relates to heat & work transfer and entropy transfer & generation). We also could advance and synergize your "Thermomass" concept with my work in that area. www.kostic.niu.edu Slide For further Info you may contact Prof. Kostic at: kostic@niu.edu or on the Web: www.kostic.niu.edu Prof. M. Kostic Mechanical Engineering NORTHERN ILLINOIS UNIVERSITY © M. Kostic 041115 Slide Thank you! Any Question ? www.kostic.niu.edu Slide