Surface Water Quality Dr. Martin T. Auer MTU Department of Civil & Environmental Engineering Surface Water Quality Management • water supply • recreation • wastewater discharge In A Watershed Everyone Lives Downstream Add Clark Surface Water Quality Management • wastewater discharge • recreation • water supply Temperature and the Density of Water 1.0000 0.9995 Density (g∙cm3) 0.9990 Maximum Density 3.94 °C 0.9985 0.9980 0.9975 0.9970 0.9965 0.9960 0.9955 0.9950 0 5 10 15 20 Temperature (°C) 25 30 Thermal Stratification spring summer Temperature (°C) Thermal Stratification Seasonality in Stratification and Mixing = °C Dollar Bay - Temperature 0 1 1 2 2 Depth (m) Depth (m) 0 3 3 4 4 5 6 M A M J J A S O N D 5 6 7 7 8 8 Temperature (°C) 0 5 10 15 20 You are what you eat. For example, there’s this lake … … and there’s that lake. Trophic State Oligotrophic Eutrophic Low in algae High in algae High transparency Low transparency Cold water fishery Warm water fishery The Limiting Nutrient Concept The Product The Supplies The Divided Lake Productivity and Oxygen Trophic State and Oxygen Profiles Eutrophic Lake Oligotrophic Lake Clinograde (°C) Temperature Orthograde (°C) Temperature 5 10 15 20 0 25 0 0 2 2 4 4 6 6 8 8 10 12 Depth (m) Depth (m) 0 10 12 14 14 16 16 18 18 20 20 5 10 15 20 25 Dollar Bay - Temperature 0 1 1 2 2 Depth (m) 0 3 3 4 4 5 6 M A M J J A S O N D 5 6 7 7 8 8 Temperature (°C) 0 5 10 15 20 Dollar Bay – Dissolved Oxygen M 0 A M J J A S O N D 1 Depth (m) 2 3 4 5 6 7 8 Dissolved Oxygen (mg∙L-1) 0 2 4 6 8 10 12 Onondaga Lake – Dissolved Oxygen Oneida Lake – Dissolved Oxygen Lake Erie – Dissolved Oxygen Gulf of Mexico – Dissolved Oxygen Aerobic and Anaerobic Metabolism Aerobic (oxygen available) C ( H 2O ) O2 CO2 H 2O Anaerobic (oxygen not available) C ( H 2O ) NO3 CO2 H 2O N 2 HCO3 C ( H 2O ) Mn 4 CO2 H 2O Mn 2 C ( H 2O ) Fe3 CO2 H 2O Fe 2 C ( H 2O ) SO42 CO2 H 2O H 2 S C ( H 2O ) CO2 CH 4 Oligotrophic Eutrophic Low in nutrients, TP<10 High in nutrients, TP>20 Low in algae High in algae Oxygen at saturation Oxygen (+, epi), (-, hyp) High transparency Low transparency Cold water fishery Warm water fishery Deep lakes with steep sides and infertile, often rocky watersheds. Shallow lakes with gently sloping sides and cultivated, fertile watersheds. Natural Eutrophication Cultural Eutrophication Lakes: Loss of Beneficial Use • Nutrients – aesthetics, recreation, drinking water • Microorganisms – recreation, drinking water • Toxics – wildlife, drinking water • heavy metals: cadmium, lead, mercury • synthetic organic chemicals: DDT, PCB, dioxin Engineering Approaches for Lake Management (Phosphorus) 1. Lake Protection • Point source control (advanced waste treatment) • Nonpoint source control Engineering Approaches for Lake Management (Phosphorus) 1. Lake Protection • Point source control • Nonpoint source control (land use management) Engineering Approaches for Lake Management (Phosphorus) 2. Diversion Seneca River Onondaga Lake METRO Engineering Approaches for Lake Management (Phosphorus) 3. Hypolimnetic Aeration Support Raft Gas Vent Support Cables Contact Chamber Air Line & Diffuser Ballast Engineering Approaches for Lake Management (Phosphorus) 4. Sediment Inactivation Engineering Approaches for Lake Management (Phosphorus) 5. Dredging Engineering Approaches for Lake Management (Phosphorus) 6. Algicides Engineering Approaches for Lake Management (Phosphorus) 7. Biomanipulation River Water Quality In A Watershed Everyone Lives Downstream Add Clark Biochemical Oxygen Demand BOD exerted, y BOD remaining, L Dissolved Oxygen (mg/L, ppm) Dissolved Oxygen Saturation and Deficit 16.0 14.0 12.0 10.0 8.0 6.0 0 5 10 15 20 Temperature (°C) 25 30 35 Dissolved Oxygen Sag Curve Change in oxygen concentration = inputs from reaeration – losses to deoxygenation Stream Zones and Biota Organism Diversity and Abundance