Aerospace & Ocean Engineering Chemical Engineering Biological Systems Engineering Civil & Environmental Engineering Mining & Mineral Engineering GREEN ENGINEERING & ENVIRONMENTAL LIFE CYCLE ANALYSIS AT VIRGINIA TECH Environment Society Dr. Sean McGinnis Director – Green Engineering Program VT College of Engineering Economics www.eng.vt.edu Technology VIRGINIA TECH GREEN ENGINEERING PROGRAM MISSION: GREEN ENGINEERING: (2) To provide students with courses and other educational experiences in which they learn skills to minimize environmental impacts and to design for sustainability (3) To facilitate interdisciplinary research and collaboration in areas of green engineering and sustainability among faculty (4) To engage the university, local, and global communities in discussions focused on engineering approaches to sustainability. • Green Engineering focuses at the interface between the environment, technology, economics, and society. 2. Materials Selection - The mass and production energy of materials used are key factors for determining life cycle environmental impact 3. Consider waste as a design flaw - Waste from all life cycle phases should be minimized through the use of materials which either return to nature or can be recycled indefinitely 4. Look to nature for sustainable designs - Nature designs materials and systems with high performance, efficient energy use, and no waste LIFE CYCLE ANALYSIS (LCA): - A method based on scientific data for analyzing and quantifying environmental impacts of products, processes, and systems over their entire life cycle - LCA provides objective environmental data for decision-making on issues that cross political, economic, social, technological, and environmental boundaries kg 0.0015 0.0001 Bentazon (C10H12N2O3S) kg 0.0013 0.0001 Electricity MJ 19 Gasoline (Farm Tractor) gal 2.1 Bromoxynil (C7H3Br2NO) kg 0.0017 Lime (quick, CaO) kg 83 Chlorpyrifos (C9H11Cl3NO3PS) kg 0.00056 0.00002 Liquified Petroleum Gas (fuel) MJ 19 Clomazone (C12H14ClNO2) kg 0.00029 0.00001 Natural Gas (fuel) MJ 19 Glyphosate (C3H8NO5P) kg 0.10 0.0043 Nitrogen Fertilizer (NH4NO3 as N) kg 1.1 Metolachlor (C15H22ClNO2) kg 0.0029 0.0001 Phosphorous Fertilizer (TSP as P2O5) kg 3.8 Potash Fertilizer (K2O) kg 7.7 Transport: Rail (kg.km) tkm 46 Transport: Road (diesel oil, liter) gal 0.27 Cropland (Conservation Tillage) m 2 2278 Cropland (Conventional Tillage) m 2 956 Cropland (Reduced Tillage) m2 813 Water Used (total) gal 10897 Water: River gal 6887 Water: Well gal 4010 Manufacturing recycle Extraction Use reuse compost Disposal Example: Biodiesel Production From Soybeans SOYBEAN OIL CONVERSION - PROCESS INPUTS Climate Change Ozone Depletion Smog Formation Acidification Human Health 1.2 0.0007 0.00003 Pendimethalin (C13H19N3O4) kg 0.016 0.0007 Hydrosphere Sulfosate (C12H32NO5PS3) kg 0.008 0.0004 Trifluralin (C13H16F3N3O4) kg 0.016 0.0004 Carbon Dioxide (CO2) (biomass uptake) kg -1559 Hydrocarbons (unspecified) kg 0.25 Nitrogen Oxides (NOx as NO2) kg 0.19 Nitrous Oxide (N2O) kg 2.47 Eutrophication Acidification Aquifer depletion Ecotoxicity Human Health Nitrogenous Matter (unspecified, as N) kg 0.14 Phosphorous Matter (unspecified, as P) kg 0.02 Suspended Matter (unspecified) kg 2812 Soybean Residues kg Sodium Hydroxide (NaOH) catalyst kg 2.3 SOYBEAN OIL CONVERSION - PROCESS OUTPUTS Methanol (CH3OH) kg 96 Biodiesel (neat) kg 1000 Sodium Methoxide (CH3ONa) kg 24 Crude Glycerin kg 150 Electricity MJ 230 Soap stock kg 0.54 Steam kg 1030 Process Water (chemically polluted) liter 380 Process Water liter 360 Waste (other) kg 12 Air Emissions (various) see graphs 1.08 Petrodiesel Fossil Energy 1.0 Petrodiesel Total Energy 0.8 0.6 0.4 0.311 0.08 0.066 0.003 0.004 0.007 0.0 Comparison of Net CO2 Life Cycle Emissions for Biodiesel Blends and Petroleum Diesel Comparison of Total Wastewater Flows for Biodiesel and Petroleum Diesel Life Cycles Biosphere 2097 1040 Biodiesel Total Energy 1.2 0.151 kg kg 1.24 Biodiesel Fossil Energy 0.2 Metribuzin (C8H14N4OS) Soybean Oil (degummed) Industrial System Engineering 1.4 Co nv er Bi sio od n ie se lT ra ns po rt To ta lE ne rg y Alachlor (C14H2OClNO2) Atmosphere Life Cycle Air Emissions for B20 and B100 Compared to Petroleum Diesel O il 0.0001 Tr an sp or t 0.0021 O il kg So yb ea n Materials Science & Engineering 2,4 - D (C8H6Cl2O3) Solid Cr us hi ng 4.5 Water So yb ea n gal Air So yb ea n Diesel (Farm Tractor) OUTPUTS PER 1000 KG SOYBEAN OUTPUT Life Cycle Total and Fossil Fuel Production Energies (including feedstock) for Biodiesel and Petroleum Diesel Tr an sp or t 0.41 NREL LCI Database http://www.nrel.gov/lci − Use scientifically derived characterization factors for comparison re kg NREL LCI Database http://www.nrel.gov/lci − How should different impact categories be weighted? − How accurate and sensitive are results to the data? − LCA provides the data/analysis, not the decision Engineering Science & Mechanics Soil depletion Deforestation Resource Depletion Ecotoxicity Human Health Electrical & Computer Engineering Agrochemicals − Confirm mass balance (inputs = outputs) within system boundaries 4. Data Interpretation (ISO 14043) ul tu −What system boundaries? Which impact categories? Which data sources? INPUTS PER 1000 KG SOYBEAN OUTPUT (1 acre) 3. Translate inventory outputs to potential environmental impacts across categories (ISO 14042) 2. Compile a detailed inventory of all inputs and outputs (ISO 14041) So yb ea n 1. Define the project scope, boundaries, and assumptions (ISO 14040) Ag ric • Since green engineering is multidisciplinary, the program searches for opportunities in education, outreach, and research across all VT colleges and departments. - Environmental impacts occur across multiple life cycle phases for products/processes and are most effectively minimized by good design Computer Science Mechanical Engineering Green Engineering considers life-cycle environmental impacts as initial design constraints. It recognizes that environmental impacts are more effectively minimized the further upstream they are considered. 1. Consider the entire life cycle Energy (MJ/MJ Fuel) • Green Engineering is the design of materials, processes, devices, and systems with the objective of minimizing overall environmental impact across the entire life cycle. GREEN ENGINEERING DESIGN PRINCIPLES: So yb ea n • (1) To increase students’ awareness of the environmental impact of engineering practice “An Overview of Biodiesel and Petroleum Diesel Life Cycles” http://www.nrel.gov/docs/legosti/fy98/24772.pdf Engineering Education spm 2/17/07