History of Elementary Particles • Greeks invented concept of Atom approximately Let’s call 2500 years ago it … an atom. • Later thought matter was made up of fire,water,air,earth Definition of Atom: Smallest particle of an element that retains the chemical identity of the element 400 B.C 1492 A.D. 1700 A.D. 0 Greeks invent concept of atom Columbus Discovers About late 1700s some the West new ideas through experiments came to be discussed. What Were Some of the Results of These Experiments? • Law of Conservation of Mass • Law of Constant Composition (also called Law of Definite Proportions) • Law of Multiple Proportions Law of Conservation of Mass + = • Matter is not created or destroyed in a chemical reaction Law of Constant Composition or Law of Definite Proportions OR A chemical has exactly the same proportions no matter the size Example: Doesn’t matter if 3 crystals or a jar of salt 66 % of mass is always Chloride 33 % of the mass is always Sodium Same “Proportions”, Same “Composition” Example of the Law or Constant Composition (Law of Definite Proportions) What would happen if I take a small bite of cake or a GIANT bite of cake? Would it taste the same? The “Composition” of the cake is the same all the way through. A COMPOUND (like sugar or salt) is the SAME no matter where you find it, or how much you have. The Law of Multiple Proportions Chemicals always combine in ratios of small whole numbers Example: H2O - Water There will always be a 2 to 1 ratio between Hydrogen and Oxygen Whether you have one water molecule or an ocean full water Law of Multiple Proportions Example Molecules are not made up of “1/2” or an atom or pieces of an atom This proportion might be 1: 3/4 Remember WHOLE numbers. 1492 400 B.C 0 Greeks invent concept of atom . A.D Late 1700s 1803 QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Columbus Discovers the West New Experiment s and Laws John Dalton and the Atomic Theory of Matter QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. • At age 12 Dalton was teaching the local school • Was reading Newton’s Book in Latin • Color Blindness was called “Daltonism” for a lengthy time John Dalton - 1803 Atomic Theory of Matter QuickTime™ and a TIFF (Unc ompressed) decompres sor are needed to see this picture. QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. • UNIQUE - Atoms are unique from other elements • GROUPS - Compounds are combined in small whole numbers. • LAW OF CONSERVATION OF MATTER - atoms are rearranged or combined but not destroyed • INDIVIDUALS - Elements are composed of atoms (smallest building block) 1492 400 B.C 0 . A.D Late 1700s 1803 Almost 1900 QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Greeks invent concept of atom QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Columbus Discovers the West New Experiments and Laws John Dalton and the Atomic Theory of Matter Thompson Discovers the Electron John Thompson, circa 1900 Discovers Electron QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. • Prior to this a man named Faraday hypothesized that atoms had a charge • Thompson hypothesized that the electrical charge was negative and that the particle had mass Thompson’s Experiment using a Cathode Ray Tube (CRT) • Elements are neutral (no charge) • Thompson could alter path of particles by using magnets (that showed they had a charge) • The type of magnet showed that it had a negative charge QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. battery magnets Thompson (continued) QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. • Now Thompson knew that there was a negative particle in the atom but where??? I’m tired… Quic kT i me™ and a T IFF (Unc ompres s ed) dec ompres s or are needed t o s ee thi s pi c ture. 1492 400 B.C 0 . Late 1700s A.D Almost 1900 1803 QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Greeks invent concept of atom Columbus Discovers the West John Dalton New and the Exper-Atomic imentsTheory of and Matter Laws 1910 QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Thompson Discovers the Electron QuickTime™ and a TIFF (Uncompress ed) dec ompres sor are needed to s ee this pic ture. Rutherford discovers the nucleus Quic kTime™ and a TIFF (Unc ompres sed) dec ompres sor are needed to see this pic ture. • Rutherford was not a brilliant man, often getting lost in Math, not terribly clever in experimentation, just tenacious and openminded • His assistant was Hans Geiger, inventer of the “Geiger Counter” Rutherford’s Model of the Atom QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Rutherford hypothesized that the inside of an atom was a mass with bits of matter mixed in. Yum Yum! He called the model the “Plum Pudding” Model QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Rutherford’s Gold Foil Experiment QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. • Rutherford set up very thin gold foil as a target • “shot” positive charges to foil • Watched patterns that positive particles made Results of the Rutherford’s Experiment QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. • Alpha particles (positive particles) went through • Only sometimes ‘bounced” back • Proved that nucleus was mostly empty space • Called center “nucleus” Rutherford’s NEW Model of the Atom Rutherford hypothesized that the inside of an atom was a small mass called a nucleus. QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Yuck! QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Rutherford’s Gold Foil Experiment Animation http://micro.magnet.fsu.edu/electromag/java/rutherfor d/index.html What Do I Need to Remember ? • • • • • Greeks came up with Atom 3 Laws that started it all… Dalton - Atomic Theory of Matter Thompson CRT Experiment Rutherford’s Gold Foil Experiment Memory Helps • Rutherford QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. – – – – A Ford Truck carrying Plum Pudding Covered in Gold Foil Discovered the Nucleus I’d “Rather” have a Ford (Rutherford) 3 Laws Always One You Already Know… Law of Conservation of Matter Whole #s Law of Definite Proportions Law of Multiple Proportions Thompson Cathode Ray Tube QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Daltons Theory of Matter • UGLI QuickTime™ and a TIFF (Unc ompressed) decompres sor are needed to see this picture. – U Unique (Elements are..) – G Groups (They are grouped in small whole number groups Law of Multiple Proportions) – L Law of Conservation of Matter – I Individual (Matter is made up of individual atoms)