Tuesday, Sept. 24th: “A” Day Wednesday, Sept. 25th: “B” Day Agenda Ch. 8 Tests Begin Ch. 9: Stoichiometry Start Sec 9.1: “Calculating Quantities in Reactions” Stoichiometry, mole ratios Moles Moles Moles Mass In-Class : Worksheet pg. 14-15 (moles moles) Mass to Mass Stoichiometry worksheet **You MUST show work for credit!** Ch. 8 Test “Chemical Equations and Reactions” Class 3A 4B Average Score Average (out of 60) Percentage 53.09 88.48% 51.23 85.38% Balanced Equations Show Proportions The proportions of the ingredients in a muffin recipe let you adjust the amounts to make enough muffins even if you don’t have balanced amounts initially. A balanced chemical equation is very similar to a recipe in that the coefficients in the balanced equation show the proportions of the reactants and products. Consider the reaction for the synthesis of water… Balanced Equations Show Proportions 2 H 2 + O2 2 H2O The coefficients show that two molecules of hydrogen react with one molecule of oxygen and form two molecules of water. Calculations that involve chemical reactions use the proportions from balanced chemical equations to find the quantity of each reactant and product involved. Relative Amounts in Equations can be Expressed in Moles The coefficients in a balanced equation also represent the moles of each substance. For example, the equation below shows that 2 mol C8H18 react with 25 mol O2 to form 16 mol CO2 and 18 mol H2O. 2 C8H18 + 25 O2 16 CO2 + 18 H2O Relative Amounts in Equations can be Expressed in Moles You can determine how much of a reactant is needed to produce a given quantity of product, or how much of a product is formed from a given quantity of reactant. The branch of chemistry that deals with quantities of substances in chemical reactions is known as stoichiometry. Stoichiometry: the proportional relationship between two or more substances during a chemical reaction. The Mole Ratio is the Key The coefficients in a balanced chemical equation show the relative numbers of moles of the substances in the reaction. As a result, you can use the coefficients in conversion factors called mole ratios. Mole ratios bridge the gap and can convert from moles of one substance to moles of another. The Mole Ratio is the Key! The mole ratio is….. THE SECRET MAGIC STEP!! when solving stoichiometry problems. All stoichiometry problems can be solved by following these 3 steps: 1. Change the units of what you know into moles. 2. Use the mole ratio (secret magic step) to convert moles of the substance you were given into moles of the substance you want. 3. Change out of moles into the unit that you need for your final answer. That’s all there is to it! Sample Problem A, pg. 304 Consider the Haber process for the commercial preparation of ammonia, NH3: N2 + 3 H2 2 NH3 Question: How many moles of hydrogen, H2, are needed to prepare 312 moles of ammonia, NH3? 1. Start with what you know: 312 moles NH3 2. Use the “secret magic step” to convert moles of NH3 into moles of what you want, H2. 312 mol NH3 X 3 mol H2 = 2 mol NH3 468 mol H2 Practice #1, pg. 304 Calculate the amounts requested if 1.34 mol H2O2 completely react according to the following equation: 2 H2O2 2 H2O + O2 a. Moles of oxygen formed 1.34 mol H2O2 X 1 mol O2 = 0.670 mol O2 2 mole H2O2 b. Moles of water formed 1.34 mol H2O2 X 2 mol H2O = 1.34 mol H2O 2 mol H2O2 Practice #2, pg. 304 Calculate the amounts requested if 3.30 mol Fe2O3 completely react according to the following equation: Fe2O3 + 2 Al 2 Fe + Al2O3 a) Moles of aluminum needed 6.60 mol Al b) Moles of iron formed 6.60 mol Fe c) Mole of aluminum oxide formed 3.30 mol Al2O3 Problems Involving Mass, Volume, or Particles Substances are usually measured by mass or volume. (Can you go to the balance and measure out 5 moles of NaCl?) As a result, before using the mole ratio (Secret Magic Step) you will need to convert units for mass and volume into moles. Mass Moles The conversion factor for converting between mass and moles is simply the molar mass of the substance. You do remember molar mass, don’t you?..... Molar Mass Review What is the molar mass of table salt, NaCl? Na: 22.99 g/mol + Cl: 35.45 g/mol 58.44 g/mol What is the molar mass of sulfuric acid, H2SO4? H: 2 (1.01 g/mol) = 2.02 g/mol S: = 32.07 g/mol + O: 4 (16.00 g/mol) = 64.00 g/mol 98.09 g/mol OK, I feel better now that you guys remember this stuff. Let’s try a sample problem……… Remember the 3 steps: 1. Change the units of what you know into moles. 2. Use the mole ratio (secret magic step) to convert moles of the substance you were given into moles of the substance you want. 3. Change out of moles into the unit that you need for your final answer. Sample Problem B, pg. 307 What mass of NH3 can be made from 1,221 g H2 and excess N2? N2 + 3 H2 2 NH3 ***Remember, hydrogen is a diatomic element*** 1. Start with what you know: 1,221 g H2 2. Convert to moles using molar mass: 1,221 g H2 X 1 mol H2 = 604.5 mol H2 2.02 g H2 3. Use mole ratio to convert moles H2 moles NH3 604.5 mol H2 X 2 mol NH3 = 403.0 mol NH3 3 mol H2 Sample Problem B cont… 4. Finally, use the molar mass to change moles of NH3 into grams of NH3: 403.0 mol NH3 X 17.04 g NH3 = 6,867 g NH3 1 mol NH3 That’s it…you did it! Practice #1, pg. 307 Use the equation below to answer the questions that follow: Fe2O3 + 2Al 2Fe + Al2O3 a) How many grams of Al are needed to completely react with 135 g Fe2O3? b) How many grams of Al2O3 can form when 23.6 g Al react with excess Fe2O3? c) How many grams of Fe2O3 react with excess Al to make 475 g Fe? d) How many grams of Fe will form when 97.6 g Al2O3 form? Update your graphic organizer: 1. What do you use to change from Moles Moles Mole Ratio “Secret Magic Step” 2. What do you use to change from Moles Mass Molar Mass (g/mol) In-Class/Homework Assignment Worksheet pg. 14-15 (moles moles) Mass to Mass Stoichiometry worksheet We will finish section 9.1 next time…. ***You must SHOW ALL WORK on these worksheets for credit***