Chemistry Midterm Free Response Review Part I. Atomic Structure & Subatomic particles Mg2+ a) b) c) d) 1. Based on the information provided: The overall charge of this ion is _________. The number of protons is ___________. The number of electrons overall is (greater/less) _________ than the number of protons. If the atomic number for Magnesium is 12, the number of electrons is ___________. Cl12. Based on the information provided: a) The overall charge of this ion is _________. b) The number of protons is ___________. c) The number of electrons overall is (greater/less) _________ than the number of protons. d) The number of electrons is ___________. Sr2+ a) b) c) d) 3. Based on the information provided: The overall charge of this ion is _________. The number of protons is ___________. The number of electrons overall is (greater/less) _________ than the number of protons. The number of electrons is ___________. N-3 4. Based on the information provided: a The overall charge of this ion is _________. b) The number of protons is ___________. c) The number of electrons is ___________. 5. a) Identify the ion that has 18 electrons and a +2 charge. _______ b) Identify the ion that has 36 electrons and a -1 charge. _______ c) Identify the ion that has 18 electrons and a -3 charge. _______ 6) There are four naturally occurring isotopes of the element chromium. The relative 50Cr = 4.31%, 52Cr = 83.76%, 53Cr = 9.55%, 54Cr = 2.38%. abundance of each is: Calculate the average atomic mass of chromium. 7a) Give the electron configuration for a neutral atom of selenium. 7b) How many unpaired electrons are there in a neutral atom of selenium? 7c) What is the most common ion that selenium would form? Justify your response. 8a) How many electrons are in the highest occupied energy level of a neutral strontium atom? 8b) Give the four quantum numbers for all of the valence electrons in a neutral strontium atom. 9) What is the frequency of light with wavelength 1.0 x 10-8 m? (c = 3.0 x 108 m/s) 10) What is the wavelength of light with a frequency of 1.0 x 10 20 Hz? (c = 3.0 x 108 m/s) 11) What is the energy of a photon of light with frequency 1.0 x 10 12 Hz? (h = 6.6 x 10-34 J-s) 12) Calculate the deBroglie wavelength of a 100-kg particle travelling at 20m/s. Part II. Periodic Trends Fill in each of the following with either: INCREASES (I) DECREASES (D) STAYS THE SAME (S) I. Across a period, as atomic number increases: 1) The number of principal energy levels __________________. 2) The distance between the valence electrons and the nucleus __________________. 3) The force of attraction between the valence electrons and the nucleus __________________. 4) From left to right the nuclear charge __________________. 5) As atomic number increases, atomic radius overall _____________. 6) As atomic number increases, electronegativity overall ____________. 7) As atomic number increases, ionization energy overall ____________. II. Down a group or family, as atomic number increases: 8) The number of principal energy levels __________________. 9) The distance between the valence electrons and the nucleus __________________. 10) The force of attraction between the valence electrons and the nucleus __________________. 11) The addition of principal energy levels down a group __________ the distance between the nucleus and the valence electrons. 12) As atomic number increases, atomic radius overall __________. 13) As atomic number increases, electronegativity overall ____________. 14) As atomic number increases, ionization energy overall ____________. III. In General: 15) If electronegativity ____________, it is harder for the atom to attract more electrons. 16) If ionization energy ____________, it is harder to remove electrons. 17) If atomic radius increases, the electrical force between an atom’s nucleus and its valence electrons ____________, 18) Which element in the second period has the greatest atomic radius? 19) Tell which atom in each pair has the larger IONIC radius. a) Al or B b) S or O c) Br or Cl d) Na or Al e) O or F 20) Indicate which element in each pair has the greater electronegativity. a) Calcium, gallium b) Lithium, oxygen c) Chlorine, sulfur d) Bromine, arsenic Part III. Bonding Complete the following chart. Molecule / Ion 1) CO2 2) N2 3) HCN 4) SO42- 5) ClO31- 6) SO2 7) CO32- 8) XeF4 9) PCl5 10) SeF4 Lewis Structure VSEPR numbers EDG MG Part IV. Writing Chemical Formulas & Naming Compounds Write formulas for these compounds: 1. Potassium sulfide _____________________ 2. Tin (IV) chloride _____________________ 3. Dihydrogen monosulfide _____________________ 4. Calcium oxide _____________________ 5. Aluminum fluoride _____________________ 6. Trinitrogen pentoxide _____________________ 7. Iron (III) carbonate _____________________ 8. Sulfur hexafluoride _____________________ 9. Ammonium hydroxide _____________________ 10. Magnesium phosphate _____________________ 11. Which of the ten compounds listed above are ionic compounds? (Circle them.) 12. How can you distinguish between an ionic compound and a molecular compound? calcium carbon oxygen potassium 13. Choose from the elements above to write a formula for an IONIC compound. __________ 14. Name the compound you gave in #13. ________________________________________ 15. Choose from the elements above to write a formula for a MOLECULAR compound. __________ 16. Name the compound you gave in #15.________________________________________ Part V. Reactions Practice For each of the following write a balanced chemical equation. 1. Write balanced equation for the decomposition of potassium choride into its elements. 2. Write balanced equation for the complete combustion of octane, C 8H18. For each of the following reactions that occur, write a balanced chemical equation. If it does not occur, write “No Rxn”. 3. Zn (s) + H2SO4 (aq) 4. Na (s) + H2O (l) 5. Sn (s) + NaNO3 (aq) 6. Cl2 (g) + NaBr (aq) 7. Fe (s) + Pb(NO3)2 (aq) 8. I2 (g) + NaCl (aq) 9. Ca (s) + HCl (aq) For each of the following write a balanced chemical equation with phases. All reactants are dissolved in water. 10. barium chloride + ammonium carbonate 11. magnesium nitrate + copper(II) sulfate 12. lead (II) nitrate + potassium carbonate 13. silver nitrate + sodium phosphate Part VI. Stoichiometry Determine the empirical formula of the following compounds based on percent composition data: 1. 42.9% C and 57.1 %O 2. 32.00% C, 42.66% O, 18.67% N, and 6.67% H 3. 71.72% Cl, 16.16% O, and 12.12% C Free Response Answer Key PAGE 1 Question 1 a. +2 b. 12 c. Less d. 10 Question 2 a. -1 b. 17 c. Greater d. 18 Question 3 a. +2 b. 38 c. Less d. 36 Question 4 a. -3 b. 7 c. 10 Question 5 a. Ca 2+ b. Br c. P 3PAGE 2 Question 6 52.0569 g Question 7 a. 1s22s22p63s23p64s23d104p4 b. 2 c. Se2- , it forms octet Question 8 a. 2 b. [5,0,0,+1/2] and [5,0,0,-1/2] Question 9 3 x 1016 Hz Question 10 3 x 10-12 m Question 11 6.6 x 10-22 J Question 12 3.3 x 10-37 m PAGE 3 Question I 1) S 2) D 3) I Page 4 OF THE REVIEW PAGE 3 (continued) Question I(continued 4) I 5) D 6) I 7) I Question II 8) I 9) I 10) D 11) I 12) I 13) D 14) D Question III 15) D 16) I 17) D 18) Li Question 19 a) Al b) S c) Br d) Na e) F Question 20 a) gallium b) oxygen c) chorine d) bromine PAGE 4 (On Back) PAGE 5 1. K2S 2. SnCl4 3. * Typo: Dihydrogen monosulfide: H2S 4. CaO 5. AlF3 6. N3O5 7. Fe2(CO3)3 8. SF6 9. NH4OH 10. Mg3(PO4)2 11. K2S, SnCl4, CaO, AlF3, Fe2(CO3)3, Al(OH)3, Mg3(PO4)2 12. Ionic –metal and a nonmetal Molecular – 2 nonmetals PAGE 5 (continued) 13. CaO or K2O 14. Calcium oxide or Potassium oxide 15. CO, CO2 16. Carbon monoxide, carbon dioxide PAGE 6 1. 2KCl → 2K+Cl2 2. 2C8H18+25O2 → 16CO2+18H2O 3. Zn +H2SO4 → H2+ZnSO4 4. 2Na+H2O → 2H2+Na2O 5. No Reaction 6. Cl2+2NaBr → Br2+2NaCl 7. Fe + Pb(NO3)2 →Pb + Fe(NO3)2 8. No Reaction 9. Ca + 2HCl → H2 +CaCl2 10. BaCl2(aq)+(NH4)2CO3(aq) → 2 NH4Cl(aq) +BaCO3(s) 11. No Reaction (all aqueous) 12. Pb(NO3)2(aq)+K2CO3(aq) → 2KNO3(aq) +PbCO3(s) 13. 3AgNO3(aq)+Na3PO4(aq) → 3NaNO3(aq)+Ag3PO4(s) PAGE 7 1. CO 2. C2H5O2N 3. COCl2 a) Molecule / Ion Lewis Structure VSEPR numbers 220 EDG Linear MG Linear : 𝑵 ≡ 𝑵: (none) Linear Linear 𝑯 − 𝑪 ≡ 𝑵: 220 Linear Linear 440 Tetrahedral Tetrahedral 431 Tetrahedral Trigonal pyramidal 321 Trigonal planar Bent 330 Trigonal planar Trigonal planar 642 Octahedral Square planar 550 Trigonal bipyramidal Trigonal bipyramidal 541 Trigonal bipyramidal Seesaw 11) CO2 12) N2 13) HCN 14) SO42- 15) ClO31- 16) SO2 (has resonance) 17) CO32(has resonance) 18) XeF4 19) PCl5 20) SeF4