Naming Ionic Compounds Learning the Language of Chemistry Naming Ionic Compounds Ionic Compounds are composed of two parts. Metal (Positive, Cation) Non-Metal (Negative, Anion) Naming Ionic Compounds There are two types of Ionic compounds: Binary Ionic Compounds Ternary Ionic Compounds Two ions present (one metal and one non-metal) Three or more elements (one metal and one polyatomic ion) When combining ions to form an ionic compound it must have a net charge of ZERO! Naming Ionic Compounds Calcium and Oxygen Calcium has what charge when it becomes an ion? Oxygen has what charge when it becomes an ion? What ratio will these two ions combine to form a compound? (Remember the charges must add up to equal zero!) Ca2+ O2- CaO The charges cancel each other out! +2 + (-2) = 0 Naming Ionic Compounds Barium and Nitrogen Barium has what charge when it becomes an ion? Nitrogen has what charge when it becomes an ion? What ratio will these two ions combine to form a compound? (Remember the charges must add up to equal zero!) Ba2+ N3- Ba3N2 The charges cancel each other out! 3(+2) + (2(-3)) = 0 Naming Ionic Compounds When naming binary ionic compounds: 1. 2. You first name the cation (metal, positive), which is the same name as the element Second you name the anion (non-metal, negative) with the ending –ide Naming Ionic Compounds NaCl Sodium Chloride CaCl2 Calcium Chloride Sr3N2 Strontium Nitride Naming Ionic Compounds Acetate- C2H3O2Nitrite- NO2 Nitrate- NO3 Silicate- SiO32 Cyanide- CN Phosphate- PO43 Phosphite- PO33 Ammonium- NH4+ Hydrogen carbonate or bicarbonate- HCO3 Dichromate- Cr2O72 Chromate- CrO42 Carbonate- CO32Oxalate- C2O42 Permanganate- MnO4 Sulfate- SO42 Sulfite- SO32 Hydroxide- OH Hypochlorite- ClO Chlorite- ClO2 Chlorate- ClO3 Perchlorate- ClO4 Naming Ionic Compounds Barium and Nitrate Barium has what charge when it becomes an ion? Nitrate has what charge when it becomes an ion? What ratio will these two ions combine to form a compound? (Remember the charges must add up to equal zero!) Ba2+ NO3- Ba(NO3)2 The charges cancel each other out! +2 + (2(-1)) = 0 We use () to keep the polyatomic together and show the number of nitrates present Naming Ionic Compounds When naming Ternary ionic compounds 1. 2. You first name the cation (metal, positive), which is the same name as the element Second you name the polyatomic anion (non-metal, negative) with the ending of either –ite or –ate (some polyatomics do end in –ide) Naming Ionic Compounds NaNO3 Sodium nitrate CaCO3 Calcium carbonate Ba(OH)2 Barium hydroxide Naming Ionic Compounds But what about those pesky transition metals? Those ions that have more than one possible charge? We use Roman numerals to describe the charge! Example: Iron (III) ion Naming Ionic Compounds Iron (III) oxide Fe2O3 Iron (II) oxide FeO Copper (II) nitrate Cu(NO3)2