X Chemistry Chapter 4-The Structure of the Atom

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Name: __________________________________________________

X Chemistry Unit 4 Notes: Atomic Theory

History of the Atomic Model

1.

Atomists and Democritus

Greeks experimented with idea of atom nearly 2,500 years ago

Matter was made up of atoms  _____________ or __________________ particles

Seashell experiment

2.

John Dalton

Dalton’s Model of the Atom

1766-1844; Returned to theory of atoms

4 major postulates

1)

2)

3)

4)

3.

William Crookes

Developed __________________________ (cathode ray tube) in 1870’s

First evidence for existence of ____________________

4.

J.J. Thomson

Discovered _________________ in 1897

Discovered positively charged particles surrounded by electrons

Found the ratio of the charge of an electron to its mass

Cathode ray tube experiments – advancement of ____________________ o Led to development of “plum pudding model” of the atom

Plum Pudding Model of the Atom

5.

Robert Millikan

_______________________ experiment

Determined the _______________ and ________________ of an electron

6.

Ernest Rutherford

Discovered the ________________ (dense core of atom) in 1911

Famous ________________________ experiment

Rutherford’s Model of the Atom

7.

James Chadwick

Discovered the _________________ o No charge, but same mass as __________________

Neutrons help disperse the strong repulsion of ______________________________ in the nucleus

Nucleus is very small compared to its mass!!

8.

Niels Bohr

Improved on Rutherford’s work

“_______________________________” of the atom o Positive center is surrounded by electrons in defined _____________ circling the center

Bohr’s Planetary Model of the Atom

2

Bohr Model Vocabulary energy level – ground state – excited state –

9.

Quantum Mechanical Model

Developed by _______________________________________; mathematical model

Electrons locations are based on ___________________________

Electrons are not ________________________, but ______________!

Defined “orbital”

Orbital =

Schrödinger Model of the Atom

(Quantum Mechanical Model)

Atomic Theory

Atom

Subatomic particles

3

Ion

If the atom has a (+) charge, it has more ______________________________________.

If the atom has a (-) charge, it has more ______________________________________.

Subatomic

Particle

Mass and

Abbreviation

Charge Location Discoverer

Proton

Neutron

Electron

Atomic symbol

Atomic number

Mass number

Calculations involving Subatomic Particles:

1.

2.

3.

4.

4

Isotopic Notation: Mass #

Atomic #

Symbol

Examples:

Z

A

X

1)

80

35

Br

2)

40

20

Ca 2+

# of protons = # of protons =

# of neutrons =

# of electrons =

# of neutrons =

# of electrons =

3) Write the symbol for the isotope of carbon with a mass number of 13.

4) Write the symbol when A = 92 and the number of neutrons = 146.

Isotopes & Average Atomic Mass

Isotope

Atomic mass

Isotopic abundance (percent abundance)

***Usually can round atomic mass on the periodic table to the nearest whole number to determine the most abundant isotope but NOT ALWAYS!!

5

Average Atomic Mass Calculations

1) Multiply the mass number of the isotope by the decimal value of the percent for that isotope

2) Add the relative masses of all of the isotopes to get the atomic mass of the element

Examples:

1.

Determine the average atomic mass of magnesium which has three isotpes with the following masses: 23.98 amu (78.6%), 24.98 amu (10.1%), and 25.98 amu (11.3%).

2.

If 90% of the Beryllium in the world has a mass number of 9 and only 10% has a mass number of 10, what is the atomic mass of Beryllium?

Radioactivity

Radioactivity-

Radiation-

Nuclear reactions-

Types of Particles Emitted as Radioactive Isotopes Decay:

1.

2.

3.

6

Date

100 BC

1770

1800

1803

1880

1885

1900

1909

1913

1920-present

Models of the Atom

Scientist

Democritus/Greeks

Antoine Lavosier

Joseph Proust

John Dalton

William Crookes

Goldstein

J.J. Thomson

Ernest Rutherford

Niels Bohr

Schroedinger/Planck/

DeBroglie/Einstein/etc.

Discovery________________

Concept of the atom

Law of conservation of mass

Law of definite proportions

Law of multiple proportions

Atomic Model I

Cathode Rays (electrons)

Canal Rays (protons)

Plum Pudding Model

Discovers Electron

Atomic Model II

Nucleus of atom

Atomic Model III

Planetary Model of Atom

Atomic Model IV

Modern or Wave Model

Atomic Model V

7

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