Alabama Science in Motion Latent Heat of Fusion Latent Heat of Fusion Purpose: The purpose of this experiment is to measure the latent heat of fusion for water using standard calorimeter techniques. You will be adding ice to room temperature water and measuring the temperature change. Then you will calculate the latent heat of fusion. Materials/Equipment: GLX Styrofoam cup (Calorimeter) Room Temperature Water Temperature Probe Plastic Spoon Paper Towels Top Loading Balance Ice in Ice Bath Pre Lab Questions: 1. What should be the temperature of the ice in the ice water bath? Explain your reasoning. 2. Will the temperature of the ice change as it is melting? Explain your reasoning. 3. Is the melting of ice an endothermic or exothermic process? Explain your answer. 4. Is the cooling of water an endothermic or exothermic process? Explain your answer. Procedure: 1. Plug the temperature probe into the GLX. 2. Turn on the GLX. A graph will appear. Hit the Home key and scroll right to Digits then press the key. The GLX should be reading temperature. 3. Adjust the GLX to read more significant digits. Press the key twice to show a drop down menu. Scroll down to Data Properties. Press the key and scroll down to Number of Digits. Increase the number of digits to 2. Press F1 (OK). You now have the GLX set up to measure the temperature to hundredths of a degree. 4. Obtain a Styrofoam cup containing ice and water. This mixture, called an ice bath, should have been sitting in an insulated cooler for a short while to allow the ice and water to come to an equilibrium temperature of 0.00 °C. Measure the temperature of the ice bath and record in the data table. 5. Remove the temperature probe and dry it off. 6. Obtain an empty Styrofoam cup and measure the mass and record in the data table. 7. Fill the Styrofoam cup ½ full of room temperature water. Measure the mass of the water and cup and record in the data table. 8. Next, place the temperature probe into the room temperature water. Allow the temperature to stabilize. Record the initial temperature of the room temperature water. 9. Next, remove a small piece of ice from the ice bath. Dry the ice to remove excess water. Using a plastic spoon, place the small piece of ice into the room temperature water. Carefully swirl the cup until the ice melts. Do not use the temperature probe as a stirrer. 10. Continue adding small pieces of “dried” ice (using the plastic spoon) and melting it until the temperature of the room temperature water decreases by at least 7°C. Each cube of ice should be allowed to melt before adding additional ice. 11. After the last ice cube has melted, continue to monitor the temperature for several minutes to determine the final equilibrium temperature. Record the final temperature of the water-melted ice mixture. 12. Measure and record the final mass of the cup/water/melted ice mixture. May, 2013 Page 1 of 5 Alabama Science in Motion Latent Heat of Fusion Student Data Sheet Name _____________________________ Partner’s Name(s) _____________________________________ Period/Block _______________________ Date ___________________ Pre Lab Questions: 1. What should be the temperature of the ice in the ice water bath? Explain your reasoning. 2. Will the temperature of the ice change as it is melting? Explain your reasoning. 3. Is the melting of ice an endothermic or exothermic process? Is the value of heat (Q) for this process positive or negative? Explain your answer. 4. Is the cooling of water an endothermic or exothermic process? Is the value of heat (Q) for this process positive or negative? Explain your answer. Data: Ice Initial Temperature, Tice °C Mass Empty Cup, mcup g Mass Cup and Water, mcup+water g Water Initial Temperature, Ti °C Water/Melted Ice Final Temperature, Tf °C Mass Cup + Water + Ice, mcup+water+ice g Calculations: Mass of Water, mwater Heat released from Water, Qwater Mass of Ice, mice kg J kg Heat absorbed by melted Ice, Qice J Heat absorbed to melt Ice, Qmelt ice J Latent Heat of Fusion, Hf J/kg Standard Latent Heat of Fusion, Hf J/kg % Error May, 2013 % Page 2 of 5 Alabama Science in Motion Latent Heat of Fusion Calculations: Show all your work including formulas and units for numbers. 5. Calculate the mass of the room temperature water as mwater, in kg. 6. Calculate the amount of heat removed from the room temperature water as Qwater. 7. Calculate the mass of the ice added as mice in kg. 8. Calculate the amount of heat gained by the ice (after it melted) as it increased in temperature to the final equilibrium temperature as Qice. 9. Using the Law of Conservation of Energy, calculate the amount of heat required to melt the ice as Qice melt. 10. Calculate the latent heat of fusion (Hf) in units of J/kg. 11. Calculate the percent error using the 3.34 x 105 J/kg as the standard heat of fusion for water. Questions: 12. Which would be more effective in cooling a canned soda; 50 g of ice or 50 g of 0°C water? Explain your answer in terms of heat. May, 2013 Page 3 of 5 Alabama Science in Motion Latent Heat of Fusion 13. After a long winter, the top layer of a lake may be frozen. As the warm weather arrives, it may take several weeks for the air temperature by the lake to reach the temperature farther inland. Explain the reason for this. 14. As a 24.0 ton piece of glacier melts, how much heat does it absorb from the environment? Assume the glacier is composed of pure water. 1 ton has a mass of 907.2 kg. 15. A student fails to dry the ice cubes before placing them into the cup of water. How will the student’s calculated value for heat of fusion be compared to the standard value? May, 2013 Page 4 of 5 Alabama Science in Motion Latent Heat of Fusion Heating Curve for Water 150 Temperature, °C 100 50 0 -50 May, 2013 Energy, J Page 5 of 5