Boyd, P.1 200312436 Amanda Boyd-Learning Cycle 1. Introduction: a) Objectives for the overall learning cycle. Experience a variety of chemical reactions. To understand the difference between acids and bases To get students interested in science and learn lab safety b) Why you think this is a suitable topic? This is a suitable topic because there is a chemical reaction happen in our everyday life and we could not live without chemical reaction. For example baking cookies or pizza would have some type of chemical reaction involved. As well it is a unit in the Saskatchewan Science 10 Curriculum and it is used as scaffolding for Chemistry 30, if students want to take it. Plus when students take science they expect some to have some hands on lab experiments. Chemical reactions are an easy topic to allow students to do lab work rather than just taking notes and remembering facts. Before students are allowed to perform these labs they need to know some lab safety and lab etiquette. c) Curriculum fit / curriculum objectives Science 10 Chemical Reactions SCI10-CR1 Experience a variety of chemical reactions, including the role of energy changes. g. Investigate potential benefits and consequences of endothermic and exothermic chemical reactions. a. Create a representation about the prevalence of chemistry in our lives. f. Differentiate between reactants and products in chemical reactions. e. Explain why it can be difficult to classify changes as physical or chemical, including reference to the reversibility of the reaction. SCI10-CR2 Name and write formulas for common ionic and molecular chemical compounds, including acids and bases. i. Classify substances as acids, bases, or salts, based on observable characteristics, name, and chemical formula Foundation 3 of Science: Scientific and Technological Skills and Processes Preforming and recording data Analyzing and Interpreting Communication and Teamwork Boyd, P.2 200312436 d) How you will judge the overall success of the learning cycle An understanding of concepts and growth of knowledge containing Chemical Reactions Students are able to communicate their ideas and work in groups Students are interested in the nature of science e) Best estimate of an ideal time This learning cycle should take 5 classes therefore 5 hours. Engagement Activity: Elephant Toothpaste -Teacher lead activity Materials: Tall graduated cylinder (at least 500 ml) 50mL graduated cylinder Breaker Food Colouring Dawn Dish Soap 120 mL of 6% Hydrogen Peroxide (H2O2) 1 Tablespoon of dry yeast. (one tablespoon of dry yeast is 15 mL or 15 g) 45 mL Water (H2O) Safety Glasses Lab Coat Gloves Safety: o o A lab coat, gloves, and safety glasses are a must! As a teacher it is important to explain why you have to wear these items of clothing. You wear the lab coat because you do not want to ruin your clothes or some labs the chemicals can burn through your clothes which means it can burn though your skin. Hydrogen peroxide is an oxidant and can irritate skin and eyes, so the glasses and gloves are also needed. Also stress that you never eat something that in a lab unless told otherwise. For you cannot always tell if there is chemical residue in the lab equipment. Since it is called elephant toothpaste a student might ask if you can use it to clean your teeth and it is not. Procedure: 1. Measure out 120 mL of 6% Hydrogen Peroxide in a tall graduated cylinder. 2. Add 8 drops of your favorite food coloring into the bottle. 3. Add about mL of liquid dish soap into graduated cylinder and swirl the graduated cylinder to mix the solutions. Boyd, P.3 200312436 4. In a separate beaker add 45mL of warm water and the 15mL yeast (you can use the graduated cylinder to measure) together and mix for about 30 seconds, until the yeast has dissolved in the water. 5. Pour the yeast water mixture into the Hydrogen Peroxide solution. You may want to step back. 6. Watch what happens! What Happens: The Hydrogen peroxide mixes with the yeast solution allows a surprising large amount of bubbles to form creating foam. Why it Happens: The reason it is called elephant toothpaste is because a huge amount of foam is formed. The yeast was a catalyst speeding the reaction rate. This is a chemical reaction Remember the catalyst speeds up the reaction, but remains unchanged through the reaction. This is why so many bubbles containing dioxide spontaneously formed. The chemical equation would be: 2H2O2(aq) 2H2O(g) + O2(g) The experiment resulted in an Exothermic Reaction. An exothermic reaction is a reaction that releases energy thought giving off heat to the environment. As well this is a decomposition reaction for you start off with one reactant and results in two products. AB A + B Questions: 1. What type of a reaction occurs? A. A exothermic reaction B. A decomposition reaction 2. What was the chemical equation of the reaction? A. a. 3. Why is it called elephant tooth paste? A. A larger amount of foam is formed at once. 4. Are these physical or chemical changes? A. Chemical changes 5. What were some the observations you noticed? Boyd, P.4 200312436 A. Lots of bubbles were formed! B. It was large Goals / Objectives: -An understanding of what a chemical reaction compiles of. -Sparked interest in chemical reactions. -What endothermic reactions are. Source http://www.sciencebob.com/experiments/toothpaste.php With additional help from http://chemistry.about.com/od/chemistryglossary/g/DecompositionReaction-Definition.htm Exploration Activity #1: Quick Freeze -student centered activity Materials: 10g barium hydroxide 5g ammonium thiocyanate (or ammonium chloride) automatic balance 50mL beaker. Glass stir rod. Thermometer. Small pieces of wood or cardboard. (need to be bit bigger than the bottom of the 4500mL beaker Glass Pasteur pipettes with latex bulbs 1 piece of Litmus paper Safety: -lab coat and googles are needed since ammonium is being used. -If you get any of the mixture on your hands wash your hands right away with water Procedure: Boyd, P.5 200312436 1. Using the Glass Pasteur pipettes with latex bulbs collect some water from the tab. Drop 5 drops of water on a small piece of wood (or cardboard), and place the beaker on top. 2. Measure out 10g of barium hydroxide using and automatic balance in the beaker. 3. Measure out 5g of ammonium thiocyanate using and automatic balance in the beaker 4. Stir mixture for 1 min. 5. Take a piece of litmus paper and using the glass Pasteur pipette add 1 drop of water to dampen it. Now hold the litmus paper over the beaker. Observe what color it changed. 6. Pick up the beaker from the top. 7. Record the temperature of the mixture What Happened: When the two solids are mixed together a liquid is formed and freeze into a slush. As well the beaker shall freeze to the wood. The beaker should be noticeably cold Why it Happened: - This is an endothermic reaction for there was more energy needed to break bonds then the energy released therefore energy was absorbed from the surroundings making it cold. The reaction: Ba(OH)2(s) + 2 NH4SCN (s) Ba(SCN)2 (s) + 2H2O (l) + 2 NH3 (g) The temperature is reduced to -20°C to -30°C Questions: 1. What type of a reaction occurs? How can you tell? A.A Endothermic reaction, and it was really cold and you could smell ammonia 2. Where could you see an endothermic reaction in your daily life? A. melting ice cubes B. cooking an egg 3. What was the chemical equation of the reaction? A. 4. What is an Endothermic reaction? A.A cold reaction B.A reaction where energy is absorbed from the surrounding so the reaction can occur. 5. What Temperature was observed? Boyd, P.6 200312436 A. -20°C to -30°C 6. Did the litmus paper indicate a base or acid? A. Base 7. What happened to mixture that indicated a chemical change? A. A change in temperature, it got cold. Goals / Objectives - What a endothermic reaction is Teamwork for this lab would be done in groups 2 to 3 A connection between science and their daily lives. (when will I ever need this?) Starting a bit of inquiry to acids and bases (I would probably teach acids and bases after this subject) Source - http://www.sciencecompany.com/Fast-Freeze-Experiment.-An-Endothermic-Reaction..aspx With addition help from http://chemistry.about.com/od/chemistrydemonstrations/a/endothermicrxn.htm Exploration Activity #2 Exothermic and Endothermic Reactions -student centered activity Materials: Safety: Eye protection Four test-tubes or four expanded polystyrene cups with lids to act as calorimeters Spatula Teat pipette or small measuring cylinder Thermometer Access to a balance. Anhydrous copper(II) sulfate (Harmful) Citric acid crystals (2-hydroxy-1,2,3-propane tricarboxylic acid) Sodium hydrogen carbonate Copper(II) sulfate solution 0.5 mol Zinc powder (Flammable). Boyd, P.7 200312436 -Zinc is flammable so be careful -Anhydrous copper(II) sulfate is poisonous so do not inhale and wash hands/skin if it makes contact -Since these chemicals are being used googles and lab coats are a must Procedure: 1. Copy this table outline before starting the experiment 2. This experiment is to be done in groups of 3 to 4. Experiment 1 1. Put 2 mL of water in a test-tube. 2. Record the temperature of the water before reaction. 3. Add a spatula measure of anhydrous (white) copper (II) sulfate. (the measure is about .5mL to 1mL or copper(II) sulfate. 4. Carefully stir, then using the thermometer, and record the temperature now. Experiment 2 Boyd, P.8 200312436 1. In a dry test-tube mix one spatula measure (approx. 1mL) of citric acid. 2. Clean the spatula and then add one spatula (approx. 1mL) measure of sodium hydrogen carbonate. 3. Put 2 mL of water in another test tube. 4. Record the temperature of the water. 5. Add the mixture to the water. 6. Watch what happens and take the temperature of the solution. Experiment 3 1. Add 5 mL of copper(II) sulfate solution in a test-tube. 2. Record the temperature. 3. Add a spatula measure (approx. 1 mL) of powdered zinc. 4. Record the new temperature What happened Experiment one It is a Copper(II) sulfate(white) plus water(clear) will turn blue and is gets warmer. Experiment two Sodium hydrogen carbonate(white) + citric acid (clear), lots of bubbles form and the end it is a cloudy white solution. It becomes colder and colder as the reaction goes on. Experiment three CuSO4 was a blue liquid and Zn(s) is a grey color. Once you mix the two by stirring the mixture forms bubbles and in the end the liquid is a white color and the solid is now more of a brown color. Why it happened Experiment one Anhydrous means to be without water. So it is really just copper (II) sulfate with addition of water. This is an exothermic reaction since energy is released to the environment. CuSO4(s) +H2O CuSO4•H2O The • means they are attached to the formula, and sometimes is easy to break off. Like this in reaction it is revisable meaning you can reform the reactants from the produces. This is also a displacement reaction. Experiment two Boyd, P.9 200312436 This is endothermic reaction, and as result gets colder as the reaction occurs. The bubbles form because CO2 gas is formed. Since so much energy is needed break the Sodium hydrogen carbonate bonds it requires energy from the environment. Sodium hydrogen carbonate + citric acid → sodium citrate + water + carbon dioxide NaHCO3(aq) + H+(aq) → Na+(aq) + H2O(l) + CO2(g) Experiment three CuSO4 was a blue liquid because of the cupper and Zn(s) is a grey color. Once you mix the two by stirring the mixture forms bubbles due to the chemical reaction happen. The end the liquid is a white color and the solid is now more of a brown color showing the Copper and Zinc had switched places causing a displacement reaction. This is an exothermic for the temperature increases. CuSO4(aq) + Zn(s) → ZnSO4(aq) + Cu(s) Questions: 1. Which reactions are exothermic and which are endothermic? A. Both experiments 1 and 3 are exothermic, experiment 2 is endothermic 2. How could you tell you had an endothermic or exothermic reaction? A. The change in temperature from the before and after reaction reading 3. If you were making a cold pack, which substances would you use? A. Citric acid and sodium hydrogen carbonate, experiment 2. 4. Now if you making a hot pack, which experiment(s) would you use? Why? A. Experiment 1 or 3 because they are exothermic and give off heat. 5. What do you think are some signs of a chemical change? A. A change in Temperature B. Bubbles forming C. Color change Goals / Objectives: - Further explanations of endothermic and exothermic reactions are. Able to collect and interrupt data A connection between science and their daily lives. (when will I ever need this?) Lab safety Source -http://www.rsc.org/learn-chemistry/resource/res00000468/heats-of-reaction-exothermic-orendothermic-reactions?cmpid=CMP00000538 Boyd, P.10 200312436 Explain Activity A class discussion with the following questions, I would write their words instead of mine. This is just roughly what I expect them to say. As I would be doing this I would be using control questions, by adding a student’s name to the beginning or end of the questions. 1. What is a chemical reaction? - A chemical reaction when a new substance is formed and energy is absorbed or released into the environment. 2. How can you tell a Chemical change has occurred? (Name 4 ways) - Change in temperature Change in color Gas is formed Change in smell 3. Where can you see everyday chemical reactions? - Baking cooking Your own body 4. In which activity did we see a change in temperature? - In all the activities. 5. In which activity did we see change in color? What color change occurred? - Elephant toothpaste Experiment three CuSO4(aq) + Zn(s) → ZnSO4(aq) + Cu(s) blue white Experiment one white/clear blue 6. What is an endothermic reaction? - An endothermic reaction absorbs energy/heat from the environment. 7. What are few examples of endothermic reactions we observed in this class? - Quick Freeze experiment Experiment two Sodium hydrogen carbonate + citric acid 8. What is an exothermic reaction? - A endothermic reaction releases energy/heat from the environment 9. What are few examples of endothermic reactions we observed in this class? Boyd, P.11 200312436 - Experiment 1 Experiment 3 10. Using your knowledge of endothermic and exothermic reactions. Which type of reaction do you think the elephant toothpaste is and why? - It is an exothermic reaction because it released a lot of energy by forming so many bubbles. 11. What endothermic reactions would you see outside this classroom? - melting ice mixing sugar into coffee baking cookies Ice packs 12. What endothermic reactions would you see outside this classroom? - Heat packs Making ice Car rusting Lighter/ candle flame Background Information that students need to know from the discussion 1. What is a chemical reaction? - A chemical reaction when a new substance is formed and energy is absorbed or released into the environment. 2. How can you tell a Chemical change has occurred? (Name 4 ways) - Change in temperature Change in color Gas is formed Change in smell 6. What is an endothermic reaction? - An endothermic reaction that absorbs energy/heat from the environment. 8. What is an exothermic reaction? - An endothermic reaction that releases energy/heat from the environment. As well they should know the chemical reactions happen in their daily lives and not just in the science classroom. Boyd, P.12 200312436 Extend Activity Reaction in a Bag (NaHCO3/HC2H3O2 and NaHCO3/CaCl2) Materials: 1. Baking Soda 2. CaCl2 3. Vinegar 4. Phenol red 5. 2 large Ziploc freezer baggies 6. Two 150 mL Beakers 7. 50 mL Graduated cylinder 8. 20mL graduated cylinder Safety: -Make sure the students are wearing lab coats and glasses. The materials may be common household products but it is always better to be safe than sorry and it is always a way to make sure they are conditioned to practice lab safety Procedure: Bag #1: 1. 2. 3. 4. 5. Used the 20mL graduated cylinder to measure 15mL of NaHCO3 into a large Ziploc baggy. Using a graduated cylinder measure out and add 10 mL and of phenol red into the Ziploc bag. Close the bag most of the way leaving a small hole to pour the vinegar in. Add 50 mL of vinegar into the bag and seal the bag immediately. Record your observations. Bag #2 1. Using the graduated cylinder measure out 15 mL of NaHCO3 (baking soda) and add it to the other clean Ziploc bag. 2. Add 30mL CaCl2 into the Ziploc bag containing baking soda. 3. Close the bag most of the way leaving a small hole to pour the phenol red in. 4. Add 25 mL of the phenol red into the bag and immediately seal the bag. 5. Record what happens. Boyd, P.13 200312436 What Happens: Bag one: The solution should produce yellow bubbles but the solution itself will be red once the NaHCO3 and phenol red comes in contact with the vinegar. This reaction will feel a cold. The bag needed to be closed for bubbles will form resulting in gas. This reaction was a little slower than bag two. Bag two: When the baking soda and CaCl2 come in contact with the red phenol yellow bubbles will form. The bag will get warm. The solution will be yellow and there will be a yellow solid (precipitate) will be at the bottom. Why it Happens: 1. The formation of bubbles/gas shows a chemical reaction is occurring. NaHCO3 and vinegar produce an endothermic reaction. It gives off cold, the bag shall be cool. As well the solution is red showing it is basic. Now the reason the bubble are yellow is showing that the gas (CO2) released is acidic. If students are interested about how CO2 gas is always acidic you may want try out this lesson (http://www.middleschoolchemistry.com/lessonplans/chapter6/lesson10) 2. Baking soda and CaCl2 produce an exothermic reaction. It gives off heat, the bag shall be warm. This reaction is quick. The solution is yellow meaning it is acidic. The formation of the yellow gas indicates the presence of CO2. CO2 is always acidic. A solid is formed at the bottom bag is CaCO3 (also known as chalk). 2NaHCO3(aq) + CaCl2(aq) CO2(g) + CaCO3(s) + 2NaCl(aq) + H2O(l) As you can see there is NaCl is formed in this reaction. NaCl is salt. In Chemistry a salt is an ionic compound that results from the neutralization reaction of an acid and a base. Questions: 1.What does phenol red indicate? -it indicated if the solution was acid or base 2. Which solution was an acid? What color did the phenol red change to? -The baking soda and CaCl2 was an acid and the phenol red changed to a yellow color. 3. Which solution was a base? What color did the phenol red change to? Boyd, P.14 200312436 -NaHCO3 and vinegar was a base and the phenol red stayed red. 4. Was there an endothermic or exothermic reaction present in this experiment? If there was indicate which bag was what reaction. - Both were present. Bag 1 was endothermic and Bag 2 was exothermic. 5. How can you tell a chemical reaction happened in this experiment? -Bubbles formed and there was color change. Goals / Objectives: - Students can confidently decide when an endothermic or exothermic reaction has occurred. Students know the warning signs of if a chemical reaction has occurred This lab will introduce the new topic of acid and base reactions That there are different indicators used for acids and bases (phenol red in this lab and litmus paper in Quick Freeze) Source: http://webfinder.hol.es/look/Reaction_in_a_Bag_Experiment/Reaction_In_A_Bag_NaHCO3_HC2H3O2_ And_NaHCO3_CaCl2/aHR0cDovL3dlYi5jaGVtLnVjc2IuZWR1L35mZWxkd2lubi9EZW1vTGlicmFyeS9EZW1v UERGcy9EZW1vMDIzLnBkZg==_blog Evaluation 1) Exit slips aim/s for the assessment -To be completed at the end of each class and handed in -To see what students are learning from each class -To inquire if they want/need to know more information The questions would be 2 factual questions that were asked that day and one question if they want more information. This allows the teacher to see if the students understood the lab and what concepts should be re-explained or developed further. For example for the exit slip for the Extend Activity Reaction in a Bag (NaHCO3/HC2H3O2 and NaHCO3/CaCl2) would be What color does phenol red turn when it comes in contact with a base Boyd, P.15 200312436 It stays red What is an exothermic reaction? An endothermic reaction that releases energy/heat from the environment. Is there anything you wish to explore a bit more in depth from this experiment? Nope Why is CO2 always basic? Criteria Exit Slip handed in Inquiry Questions Understand Key Concepts 0 Has not handed any exit slips in Student has not response to inquiry questions 1 One Exit slip handed in Student asked questions that have already been brought up in class Is unable to answer the factual questions on the Exit slips Is able to answer 1 question correctly on each exit slip 2 Two to Three Exit slips handed in Has a mixture of class questions and new questions that were not brought up in class. Has answered all faction questions, and gotten 1 or 2 questions wrong. 3 Four or Five Exit slips handed in New questions on the activities that were not already asked in class by the teacher. Has answered all factual questions correctly 2)Comic life Students will be warned when they are doing a comic life summary so they can take pictures of the lab. Aim/s for the assessment -Students are able to use their own words to summarize activities. -A more creative way to assess over a formal lab report -Allows students to see science is also creative and not only factual (the art in science) Boyd, P.16 200312436 Rubric Criteria Summary 0 No summary is written. Pictures of Experiment No pictures are present Creativity and Appearance Blank, not creative and poor appearance Graphics are untrimmed OR of inappropriate size and/or shape. It appears no attention was given to designing the comic. Design 1 Summary describes the information learned but is difficult to read through. 2 Summary describes the information learned and has a few grammatical errors but information is understandable. 1 picture of the 2 pictures of the experiment is used experiment are used. Little creativity Some creativity and poor overall and good overall appearance appearance Graphics have Graphics are been trimmed to trimmed to an an appropriate appropriate size size and shape, and interesting but the shape and are arrangement of arranged with items is not very some items in attractive. It front and others appears there was behind. The comic, not a lot of however does not planning of the appear balanced. item placement. 3 Summary describes the skills learned, the information learned and easy to read and has no grammatical errors. 3 or more pictures of the experiment are used. Very creative and eye pleasing appearance Graphics are trimmed to an appropriate size and interesting shape and are arranged well, some in front and some behind. Care has been taken to balance the comic Comments This assignment was difficult at the beginning because I did not have a clear focus and was going in many different directions. Once I understood what the assignment was asking me to do. I narrowed my focus and found suitable experiments. It really helped me see how lessons should line up and act as scaffolding to one another. That one lesson leads to another, so you do not get confused. I really liked taking this opportunity to find a real life application of exothermic and endothermic reactions (the heating and cooling packs). I will consider doing learning cycles in my unit plans. Once you understand how to use it, it makes planning easier. It also shows how much planning you have to do for only a week of classes, pre-internship shall be fun, stressful and a learning experience.