Radioactivity – types of decays A presentation for Wed. in the last week of Physics 125 Atomic and nuclear structure • Atomic model – nucleus and electrons. • Nucleus – contains protons and neutrons. • Protons have charge Qp = +e, where e is defined as the magnitude of the electron charge. • e = 1.6 x 10-19 Coulombs = 1.6 x 10-19 C • Electrons have charge Qe = -e • Neutrons have charge Qn = 0 (zero, exactly) • The nucleons (protons and neutrons) are bound together by the strong nuclear force in a small nucleus which has a size of about 10-15 m. Nuclear notation • Z = atomic number or proton number, is the number of protons in the nucleus. • N = neutron number, is the number of neutrons in the nucleus. • A = Z + N = mass number, is the number of nucleons in the nucleus. A • In general, the notation is Z X N • For example, 12 6 C6 has atomic mass 12.000 Nuclear isotopes • Each element has a distinct proton number Z. • The neutron number may vary for different isotopes of the element. • The mass number A = Z + N will also vary for different isotopes. 12 6 C6 14 6 C8 • For example, and are two isotopes of carbon. These are also written C-12 and C-14. • The neutron number is usually omitted, but can easily be calculated, since N = A – Z . • Also, the proton number is often omitted: 14C Radioactivity – unstable nuclides • Each element may have several different isotopes, and some of these may be unstable. • Radioactive decay occurs when a nucleus of an unstable isotope decays into product particles. • Three common types of radiation are observed: • Alpha particles are doubly-charged He nuclei. • Beta particles are electrons (or positrons). • Gamma rays are high-energy photons. Alpha particles • Alpha particles are doubly-charged He nuclei. • The particle is a bare nucleus with 2 protons and 2 neutrons, and a charge of +2e • They are identical to the nucleus of helium atom, and once the alpha slows down, it will capture two electrons from surrounding material and become a neutral He atom. 4 • The nuclear notation for the alpha is a or 2He • Most of the helium in rocks is due to alpha decay of heavy elements in the Earth. Alpha decay • Alpha particles are emitted in alpha decay. • The parent nucleus is usually a heavy element. • For example, polonium-214 decays by alpha decay to lead-210 and an alpha particle: • 214 84Po 210 82Pb + 4 2He • Notice that this nuclear equation is balanced in both the proton number (84 = 82 + 2) and the nucleon number (214 = 210 + 4). Conservation laws in nuclear decay • The balance of the proton and mass numbers is due to conservation laws for nuclear decay: • Conservation of nucleons (the mass numbers). • Conservation of charge (the proton numbers). • Conservation of mass-energy is also observed. • The energy of the alpha particle from the decay of 214Po is about 7.7 MeV. This energy is due to a small difference between the mass of 214Po and the sum of the masses of 210Pb and 4He. • The difference in mass between parent and products is converted to energy by E = mc2. Beta decay • Beta particles are emitted in beta decay. • The parent nucleus is usually an isotope with an excessive number of neutrons. • For example, carbon-14 decays by beta decay to nitrogen-14 and a beta particle: • 14 6C 14 7N + 0 -1e (beta with Q = -e) • This equation is balanced in the charge number (6 = 7 + (-1)) and nucleon number (14 = 14 + 0). • Z increases by one, and N decreases by one. Beta decay of an isolated neutron. • Beta decay can be thought of as the decay of a neutron in the nuclide into a proton and electron. • An isolated neutron will also decay by beta decay to a proton and a beta particle: • 1 0n 1 1p + 0 -1e (neutron decay) • Notice that this nuclear equation is balanced in both the charge number (0 = 1 + (-1)) and the nucleon number (1 = 1 + 0). Two types of beta decay: b+ and b• Beta decay can also produce a positron, the anti-particle of the electron. • An example of positive beta decay is oxygen-15: • 15 8O 15 7N + 0 +1e (like a proton decay!) • This process occurs for some nuclides which have more protons than neutrons. However, the proton by itself is stable (we believe). Electron capture (EC) • Another type of decay is electron capture, where an electron of the atom is captured by the nucleus and a proton is converted into a neutron. • An example of electron capture is beryllium-7: • 7 4Be + 0 -1e 7 3Li (and an X-ray) • This process has the same resulting daughter nucleus, except that no beta particle is emitted. Gamma decay • Gamma decay occurs when a nucleus emits a gamma particle, a high-energy photon. • This only occurs when a nucleus has extra energy, perhaps because it was just created in a previous nuclear decay. • An example of gamma emission is barium-137m, which is a nucleus of Ba which has just been created in a beta decay of Cs-137: 137 137 0 • 56Ba* + -1e (a beta decay) 55Cs • 137 56Ba* 137 56Ba + g (a gamma decay) Energy levels in gamma decay • Barium-137m is an example of an isomer, which is a nucleus with excess energy. • In some ways this is similar to a neutral atom in an excited state, which can make a transition to a lower energy level by emitting a photon. (Fluorescence is one example of this.) • The nuclei have much larger energies than atoms, MeV instead of eV. 137 137 • 56Ba* 56Ba + g (661.66 keV) • This isomer lives long enough to be separated from it’s parent (Cs-137) and studied in the lab. Co-60: beta-gamma-gamma decay • Cobalt-60 is an example of a nuclide that decays by beta decay to an intermediate excited state. • The intermediate state then decays by emitting a gamma rays. Hence both beta and gamma rays are observed from this nuclide. • The energy level scheme for this is not too complicated, and is shown in an on-line database of nuclide data. (link to Korean database) • Co-60 decays with emission of a beta of energy less than 318 keV and two gamma photons of energies 1173 keV and 1332 keV (link to Lund)