Unit 1 Introduction to Chemistry Internet web site: http://old.unit5.org/roller/ Material Safety Data Sheet (MSDS) -- gives information about a chemical -- lists “Dos” and “Don’ts;” emergency procedures Chemical Exposure acute exposure vs. a one-time exposure that causes damage e.g. reaction to drugs or medication chronic exposure damage occurs after repeated exposure e.g. smoking, asbestos How Toxic is “Toxic?” Chemicals may cause harm in many different ways: • • • • • • • • Flammable Explosive Radioactive Corrosive Irritant Carcinogenic Mutagenic Teratogenic LD50 the lethal dosage for 50% of the animals on which the chemical is tested There are various ways an LD50 can be expressed. For example, acetone has the following LD50s: ORL-RAT LD50: 5,800 mg/kg IHL-RAT LD50: 50,100 mg/m3h SKN-RBT LD50: 20 g/kg LD50 Example Chemical A: LD50 = 3.2 mg/kg Chemical B: LD50 = 48 mg/kg Which is more toxic? Chemical A is more toxic because LESS is necessary to kill half of a given population Science The Functions of Science pure science applied science the search for knowledge; facts using knowledge in a practical way e.g., properties of aluminum strong lightweight good conductor Corning Glass NASA’s Problem Design a material that is clear and can withstand extreme differences in temperature without failing (cracking). Corning Glass Company FAILED…but SUCCEEDED at making great cookware that can withstand extremes in temperature. Design a face shield to protect and provide clear vision. Aluminum Mining 4-6 pounds bauxite • 1850s: aluminum sold for $500 / lb • Charles Martin Hall • Developed method to extract aluminum from bauxite • Hall’s method – As a result, $0.30/lb + current = 1 lb Al Science attempts to establish cause/effect relationships Science can NEVER prove a cause/effect relationship, only make a correlation… risk-benefit analysis weigh pros and cons before deciding Because there are many considerations for each case, “black/white thinking” rarely applies. It is usually shades of grey. How does scientific knowledge advance? 1. curiosity 2. determination 3. persistence 4. good observations The Scientific Method ** Key: Be a good observer. observation uses the five senses inference involves a judgment or an assumption Types of Data Observations are also called data. qualitative data -- descriptions e.g., colorless liquid (vs. clear liquid) quantitative data -- measurements e.g., 17 mL; 83oC Candle Observation Activity A Description of a Burning Candle A photograph of a burning candle is shown1 in the upper right corner. The candle is cylindrical2 and has a diameter3 of about 3 cm. The length of the candle was initially about 16 centimeters4, and it changed slowly5 during observation, decreasing about 1 cm in one hour6. The candle is made of a translucent7, white8 solid9 which has a slight odor10 and no taste11. It is soft enough to be scratched with the fingernail12. There is a wick13 which extends from top to bottom14 of the candle along its central axis15 and protrudes about 5 mm above the top of the candle16. The wick is made of three strands of string braided together17. A candle is lit by holding a source of flame close to the wick for a few seconds. Thereafter the source of flame can be removed and the flame sustains itself at the wick18. The burning candle makes no sound19. While burning, the body of the candle remains cool to the touch20 except near the top. Within about 1.5 cm of the top the candle is warm21 (but not hot) and sufficiently soft to mold easily22. The flame flickers in response to air currents23 and tends to become quite smoky while flickering24. In the absence of air currents, the flame is of the form shown in the photograph, though it retains some movement at all times25. The flame begins about 2 mm above the top of the candle26, and at its base the flame has a blue tint27. Immediately around the wick in a region about 2 mm wide and extending about 5 mm above the top of the wick28 the flame is dark29. This dark region is roughly conical in shape30. Around this zone and extending about 1 cm above the dark zone is a region which emits yellow light31, bright but not blinding32. The flame has rather sharply defined sides33 but a ragged top34. The wick is white where it emerges from the candle35, but from the base of the flame to the end of the wick36 it is black, appearing burnt, except for the last 0,5 cm, where it glows red37. The wick curls over about 3 mm from its end38. As the candle becomes shorter, the wick shortens too, so as to extend roughly a constant length above the top of the candle39. Heat is emitted by the flame40, enough so that it becomes uncomfortable in 10 to 20 seconds if one holds his finger 10 cm to the side of the quiet flame41 or 10 – 12 cm above the flame42. Parts of the Scientific Method Identify an unknown. Make a hypothesis: a testable prediction Repeatedly experiment to test hypothesis. procedure: order of events in experiment (i.e., a recipe of what was done) variable: any factor that could influence the result A Scientific Experiment Experiments must be controlled: Only one variable can change at a time Independent variable: a variable you control and manipulate (x-axis) Dependent variable: the variable you measure as you change I.V. (y-axis) conclusion: must be supported with evidence from the data collected A Controlled Experiment? Make observation Scientific Method Ask question Develop hypothesis Test hypothesis with further experiments Test hypothesis with an experiment Revise hypothesis Analyze data and draw conclusions Hypothesis IS supported Wysession, Frank, Yancopoulos, Physical Science Concepts in Action, 2004, page 8 Hypothesis is NOT supported Develop theory Scientific Law vs. Scientific Theory law: states what happens, i.e., a relationship between various quantities -- Laws are often written in G m1 m2 Fg 2 the form of… an equation. r -- e.g., Newton’s law of gravity, laws of conservation theory: tries to explain WHY or HOW something happens -- based on current evidence -- e.g., Theory of Gravity, Atomic Theory a scanning tunneling microscope (STM) images of nickel atoms taken by an STM Phlogiston Theory of Burning 1. Flammable materials contain phlogiston 2. During burning, phlogiston is released into the air 3. Burning stops when… …object is out of phlogiston, or …the surrounding air contains too much phlogiston. (superceded by combustion theory of burning) Rob L. Brown, Sr. or Mary H. Brown 1007 Shady Lane Normal, Illinois 61761 _________ Date Pay to the Order of $ ________________________________Dollars NATIONAL CITY BANK OF MICHIGAN/ILLINOIS SPRINGFIELD, ILLINOIS Memo________________ ___________________________ :085936750: 4900861734 Rob L. Brown, Sr. 1437 Tampa Avenue, Apt. J-432 Bloomington, Illinois 61761 _________ Date Pay to the Order of $ ________________________________Dollars Illinois State Bank CHICAGO , ILLINOIS Memo________________ :085936750: 4900861734 ___________________________ Chemistry The Beginning Early practical chemistry: household goods, weapons, soap, wine, basic medicine The Greeks believed there were four elements ___ ___ D D earth wind fire ~ water D Alchemy (~500 – 1300 C.E.) the quest for the Philosopher’s Stone (the elixir, the Sorcerer’s Stone) Allegedly, this substance would turn cheap metals into gold Alchemical symbols for substances… GOLD SILVER COPPER IRON . .. ... .... ..... SAND transmutation: changing one substance into another Philosopher’s Stone COPPER GOLD In ordinary chemical reactions… we cannot transmute elements into different elements Alchemy was practiced in many regions of the world, including China and the Middle East. Alchemy arrived in western Europe around the year 500 C.E. Modern chemistry evolved from alchemy. Contributions of alchemists: • experimental techniques • new glassware • information about elements • developed several alloys What is chemistry? the study of matter and its changes Areas of Chemistry organic the study of carbon containing compounds inorganic studies everything except carbon e.g., compounds containing metals biochemistry the chemistry of living things physical measuring physical properties of substances e.g., the melting point of gold Careers in Chemistry • • • • • • research (new products) production (quality control) development (manufacturing) chemical sales software engineering teaching The skills you will develop by an earnest study of chemistry will help you in any career field. The Scope of Chemistry bulk chemical manufacturing acids, bases, fertilizers **sulfuric acid (H2SO4) = #1 chemical petroleum products fuels, oils, greases, asphalt pharmaceuticals 1 in 10,000 new drugs gets FDA approval synthetic fibers nylon, polyester, rayon , spandex Chemistry impacts: everyone all fields of endeavor Government Regulation of Chemicals The various levels of government regulate chemicals to protect the: environment EPA worker OSHA consumer FDA USDA CPSC Manipulating Numerical Data Graphs Bar Graph shows how many of something are in each category Chemistry Grades # of students 10 8 6 4 2 0 A B C D F Pie Graph shows how a whole is broken into parts Percentage of Weekly Income Entertainment (40%) Food (25%) Clothing (20%) Savings (15%) Line Graph shows continuous change Stock Price over Time Share Price ($) 60 50 40 30 20 10 0 Jan Feb Mar Apr Month In chemistry…you will always use a line graph. Elements of a “good” line graph Temp. v. Vol. for a Gas at Constant Pressure 2. axes labeled, with units 3. neat 4. use the available space Volume (L) 1. title 10 9 8 7 6 5 4 3 2 1 0 120 140 160 180 200 Temp. (K) 220 240 Graphing HW Total Distance Cycled (km) 9 a.m. 12 10 a.m. 23 11 a.m. 33 noon 42 1 p.m. 50 2 p.m. 57 3 p.m. 63 4 p.m. 68 Time 80 Distance Cycled (km) 8 a.m. Total Dist. cycled (km) 0 70 60 50 40 30 20 10 0 8 a.m. 9 a.m. 10 a.m. 11 a.m. noon 1 p.m. 2 p.m. 3 p.m. 4 p.m. Time (h) Extrapolation: predicting a pattern outside of a data set using the graph Interpolation: estimating a data point within the set of data using the pattern of the graph Essential Math of Chemistry Scientific Notation …used to express very large or very small numbers. Also used to maintain correct SF. (# from 1 to 9.999) x 10exponent = 8 x 10 x 10 = 8 x 102 2531 = 2.531 x 10 x 10 x 10 = 2.531 x 103 0.0014 = 1.4 10 10 10 = 1.4 x 10–3 Form: 800 (-) exponent = number < 1 (+) exponent = number > 1 Put in standard form 1.87 x 10–5 = 0.0000187 3.7 x 108 = 370,000,000 7.88 x 101 = 78.8 2.164 x 10–2 = 0.02164 Change to scientific notation 12,340 = 1.234 x 104 0.369 = 3.69 x 10–1 0.008 = 8 x 10–3 1,000,000,000 = 1 x 109 6.02 x 1023 = 602,000,000,000,000,000,000,000 Using the Exponent Key EE EXP The EE or EXP or E key means “times 10 to the…” How How to to type type out out 6.02 6.02 xx10 102323:: 6 0 . 2 EE 2 3 not… WRONG! 6 0 . yx 2 2 3 or… 6 WRONG! . 0 2 x 1 and not… 6 . 0 EE 2 3 TOO MUCH WORK. 0 2 x 1 0 yx 2 3 Also, know when to hit your (–) sign. (before the number, after the number, or either one) 1.2 x 105 2.8 x 1019 Type this calculation in like this: 1 . 2 EE 5 2 . 8 EE 1 9 = Calculator gives… 4.2857143 –15 or… 4.2857143 E–15 This is NOT written… 4.3–15 But instead is written… 4.3 x 10–15 or 4.3 E –15 7.5 x 10–6 (–8.7 x 10–14) = –6.5 x 10–19 4.35 x 106 (1.23 x 10–3) = 5.35 x 103 or 5350 5.76 x 10–16 9.86 x 10–4 = 5.84 x 10–13 8.8 x 1011 x 3.3 x 1011 = 2.9 x 1023 Accuracy and Precision All numerical data are the result of uncertain measurements. precision: a measure of the degree of fineness of a measurement; it depends on the extent to which the instrument is calibrated e.g., 8m vs. 8.00 m vs. 8.00000 m When repeated, precise measurements yield similar answers each time. e.g., precise… 0.653 m 0.652 m 0.654 m imprecise… 0.7 m 0.8 m 0.6 m A good rule of thumb is… It is the % difference that is important. accuracy: how close a measured value is to the true value Three types of error can affect accuracy. human error: mistake in reading instrument or recording results -- minimize with repeated measurements method error: using measuring instrument improperly e.g., parallax in measuring with a meter stick instrument error: measuring device is improperly calibrated e.g., bathroom scale that always reads 5 lbs. too heavy Significant Figures about… A student is combining separate water samples, all of differing volumes, into one large bucket. Samples A, B and C are 25.5 mL, 16.37 mL and 51 mL, respectively. Once combined, what is the total volume of all the samples? 92.87 mL NO! Because the samples were each measured with a different level of precision, we must factor that into our calculations by identifying what are called significant figures. Measurement and Precision • The last digit of any measured number is assumed to be an estimate (uncertain) • The second to last digit is assumed to be known with certainty(think dashes…) A (25.5 mL) B (16.37 mL) C (51 mL) 26 60 50 25 16.4 16.3 Identifying Significant Figures Counting SF in a number Non-zero numbers: ALWAYS count as SF Zeroes Relative to the non-zero numbers Left: NEVER count as SF (0.000345) Middle: ALWAYS count as SF (5001) Right: sometimes… w/ decimal point: count as SF (25.10) w/o decimal point: DO NOT count as SF (8200) Exact Numbers: IGNORE SF (assumed to have an infinite number of SF) Counts (28 students in this class) Constants (1 mol = 6.022 x 1023) Conversions (1 in = 2.54 cm) How many Sig Figs? Measurement Number of SF Measurement Number of SF 25 g 2 0.12 kg 2 0.030 kg 2 1240560. cm 7 1.240560 x 106 mg 7 6000000 kg 1 6 x 104 sec 1 6.00 x 106 kg 3 246.31 g 5 409 cm 3 20.06 cm 4 29.200 dm 5 1.050 m 4 0.02500 g 4 Now, determine the # of SF in Part A and B of the Sci. Not. HW (5 min) Sig Figs with Calculations Note: For any calculations, always perform the entire calculation without rounding, and then round the final answer. Addition/Subtraction • Round the answer to the LEAST number of decimal places found (least precise) 11.31 + 33.264 + 4.1 = 48.674 → rounded to 48.7 Multiplication/Division • Round the answer to the smallest number of SF found 5.282 x 3.42 = 18.06444 → rounded to 18.1 (3.42 only has 3 SF) Back to the original question… A student is combining separate water samples, all of differing volumes, into one large bucket. Samples A, B and C are 25.5 mL, 16.37 mL and 51 mL, respectively. Once combined, what is the total volume of all the samples? 25.5 mL + 16.37 mL + 51 mL = 92.87 mL 93 mL Could I write that as 93.0? NO! Round to the correct number of significant figures. Calculator says… 2 sig. figs. 3 sig. figs. 5 sig. figs. 75.6 76 75.6 75.600 0.528396 0.53 0.528 0.52840 387600 390,000 388,000 * 3.8760 x 105 4200 4,200 * 4.20 x 103 4.2000 x 103 8.4845E-4 8.5 x 10–4 8.48 x 10–4 8.4845 x 10–4 * = requires scientific notation Units must be carried into the answer, unless they cancel. 5.2 kg (2.9 m) = 0.64 kg*m (18 s)(1.3 s) s2 4.8 g (23 s) (18 s)(37 s) = 0.17 g s Solve for x. x+y=z x and y are connected by addition. Separate them using subtraction. In general, use opposing functions to separate things. x+y=z –y –y The +y and –y cancel on the left, leaving us with… x=z–y Numerical Example Solve for x. x – 24 = 13 x and 24 are connected by subtraction. Separate them using the opposite function: addition. x – 24 = 13 +24 +24 The –24 and +24 cancel on the left, leaving us with… x = 37 Solve for x. x and k are connected by multiplication. Separate them using the opposite function: division. The two k’s cancel on the right, leaving us with… F=kx () () __ 1 __ 1 F=kx k k (or) F=kx k k __ F x= k Numerical Example Solve for x. x and 7 are connected by multiplication. Separate them using the opposite function: division. The two 7’s cancel on the right, leaving us with… 8=7x () () __ 1 __ 1 8=7x 7 7 (or) 8=7x 7 7 __ 8 x= 7 Solve for x. One way to solve this is to cross-multiply. Then, divide both sides by TR. The answer is… ___ BA = ___ TR x H BAH = xTR ( ) ( ) ___ 1 BAH = xTR ___ 1 TR TR BAH x = ___ TR Solve for T2, where… P 1V1 ____ = P1 = 1.08 atm T1 P2 = 0.86 atm ____ 1 PVT = V1 = 3.22 L P1V1 1 1 2 V2 = 1.43 L P2V2T1 T1 = 373 K ( ) P 2V 2 ____ T2 ( ) ____ 1 P1V1 P2V2T1 ______ T2 = P1V1 (0.86 atm)(1.43 L)(373 K) _____________________ T2 = = 130 K (1.08 atm)(3.22 L) SI Prefixes kilodecicentimilli- (k) (d) (c) (m) 1000 1/ 10 1/ 100 1/ 1000 Also, 1 mL = 1 cm3 and 1 L = 1 dm3 You will be responsible for knowing these! Conversion Factors and Unit Cancellation How many cm are in 1.32 meters? equality: 1 m = 100 cm (or 0.01 m = 1 cm) conversion factors: ______ 1m 100 cm or 1.32 m 100 cm 1m 100 cm ______ 1m = 132 cm We use the idea of unit cancellation to decide upon which one of the two conversion factors we choose. How many m is 8.72 cm? equality: 1 m = 100 cm conversion factors: ______ 1m 100 cm 8.72 cm or 1m 100 cm 100 cm ______ 1m = 0.0872 m Again, the units must cancel. How many kilometers is 15,000 decimeters? 15,000 dm 1m 10 dm 1 km 1,000 m = 1.5 km How many seconds is 4.38 days? ( )( 24 h 4.38 d ____ 1d )( ) 60 min _____ 1h 60 s ____ = 378,432 s 1 min If we are accounting for significant figures, we would change this to… 3.78 x 105 s 4. Convert 41.2 cm2 to mm2 Recall that… (1 cm)2 = (10 mm )2 41.2 cm2 102 mm2 = 1 cm2 4,120 mm2 SI-US Conversion Factors Equality Conversion Factors Length 2.54 cm = 1 in. 2.54 cm 1 in and 1 m = 39.4 in. 39.4 in 1m and 946 mL = 1 qt 946 mL 1 qt and 1 qt 946 mL 1 L = 1.06 qt 1.06 qt 1L and 1L 1.06 qt and 1 lb 453.6 g and 1 kg 2.20 lb 1 in 2.54 cm 1m 39.4 in. Volume Mass 453.6 g = 1 lb 1 kg = 2.20 lb 453.6 g 1 lb 2.20 lb 1 kg Simple Math with Conversion Factors Find area of rectangle. 4.6 cm A=L.W = (4.6 cm)(9.1 cm) = 42 9.1 cm 2. cm cm Convert to m2. cm.cm 1m 42 cm2 ______ 100 cm ( ) = 0.0042 m2 ( ) = 4200 mm2 10 mm Convert to mm2. 42 cm2 ______ 1 cm 2 2 For the rectangular solid: Length = 14.2 cm Width = 8.6 cm Height = 21.5 cm Find volume. V=L.W.H = (14.2 cm)(8.6 cm)(21.5 cm) = 2600 cm3 Convert to mm3. 2600 cm3 ( ) 10 mm ______ 1 cm 3 = 2,600,000 mm3 = 2.6 x 106 mm3 mm and cm differ by a factor of………. 10 mm2 “ cm2 “ “ “ “ “ ………. 100 mm3 “ cm3 “ “ “ “ “ ………. 1000 Density how tightly packed the particles are mass Density = volume m D V m D Typical units: g/cm3 for solids V g/mL for fluids liquids and gases Glass: liquid or solid? To find volume, use… 1. a formula V = p ∙ r2 ∙ h V = l∙w∙h 2. water displacement Vinitial Vfinal V = ? Vobject = Vfinal – Vinitial ** Density of water = 1.0 g/mL = 1.0 g/cm3 Things that are “less dense” float in things that are “more dense.” (And things that are “more dense” sink in things that are “less dense.” D < 1 g/cm3 D > 1 g/cm3 D < 1 g/cm3 D < 1 g/cm3 The density of a liquid or solid is nearly constant, no matter what the sample’s temperature Density of gases is highly dependent on temperature Will Bowling Balls sink or float in If DBB > 1, it will sink H2O? If DBB < 1, it will float 21.6 cm in diameter Vsphere = 4/3 p r3 V = 4/3 p (10.8 cm)3 V = 5,276.7 cm3 m D m=DV V m = (1.00 g/cm3)(5276.7 cm3) m = 5276.7 g Since the mass of a BB varies, let’s figure out at what mass it will sink v. float …or 11.6 lbs Density Calculations 1. A sample of lead (Pb) has mass 22.70 g and volume 2.000 cm3. Find sample’s density. m D V m 22.7 g g D 3 = 11.35 V 2.0 cm cm3 2. Another sample of lead occupies 16.2 cm3 of space. Find sample’s mass. V g 3 = 184 g 11.35 16.2 cm m=DV 3 cm Indiana Jones Density • Watch the famous opening scene to Indiana Jones and the Raiders of the Lost Ark • The “pure gold” idol has a density of 19.3 g/cm3. How much would it mass? 19,300 g • Indy replaces the idol with a bag of sand (density = 2.5 g/cm3). Why did he activate the booby trap? How much sand should he have used? 7,720 cm3 or 7.72 L! • Did you see that toss at the end!? How much would the idol weigh in lbs? (2.2 lb per kg) 42.5 lbs! m 3. A 119 g solid cylinder has radius 1.80 cm and height 1.50 cm. Find sample’s density. 1.8 cm 1.5 cm m D V V = p r2 h = p (1.8 cm)2(1.5 cm) 3 m = 15.268 cm D V g 119.5 g 3 = 7.79 cm3 15.268 cm m 8.2 cm 4. A 153 g rectangular solid has edge lengths 8.20 cm, 5.10 cm, and 4.70 cm. Will this object sink in water? 5.1 cm 4.7 cm (Find the object’s density and compare it to water’s density.) V=lwh m D = 8.20 cm (5.10 cm)(4.70 cm) V = 196.55 cm3 153 g m g D 3 = 0.778 3 < 1 No; it floats. V 196.55 cm cm Galilean Thermometer Problem On a cold morning, a teacher walks into a cold classroom and notices that all bulbs in the Galilean thermometer are huddled in a group. Where are the bulbs? At the top of the thermometer, at the bottom or elsewhere? D1 1. Bulbs have essentially fixed masses D2 D3 D4 D5 and volumes. Therefore, each bulb has a fixed density. 2. The surrounding liquid has a fixed mass, but its volume is extremely temperature-dependent. 3. The density of the liquid can be written as… D1 mliq Dliq Vliq …if the liquid is cold: mliq Vliq = Dliq D2 so… D3 …but if it’s hot: mliq Vliq = On a cold morning, where are the bulbs? AT THE TOP Dliq D4 D5 Osmium 76Os Basic Concepts in Chemistry chemical: any substance that takes part in, or occurs as a result of, a chemical reaction *All matter can be considered to be chemicals or mixtures of chemicals. chemical reaction: a rearrangement of atoms such that… “what you started with” reactants differs from “what you end up with” products Products Reactants carbon methane + oxygen + water dioxide CH4(g) + 2 O2(g) CO2(g) + 2 H2O(g) Products Reactants sodium + water hydrogen + sodium hydroxide 2 Na(s) + 2 H2O(l) H2(g) + 2 NaOH(aq) Law of Conservation of Mass: total mass total mass = of products of reactants Pmass = Rmass 2 Cu + H2O + CO2 + O2 CuCO3 + Cu(OH)2 Copper “patina” is a mixture of copper(II) carbonate and copper(II) hydroxide. It has a characteristic green color. Losing weight? • Keeping the Law of onservation of mass in mind… • When you lose weight, where does it go? • Three ways, all of which involve excretion synthesis: putting simpler substances together, usually in many steps, to make something more complex A proposed organic synthesis of tetrahydrocannabinol (THC)