Chemistry 1 HT Warm up Atomic structure Atomic structure In an atom the number of electrons is equal to the number of protons in the nucleus Atomic mass and atomic number Mass Number = Number of protons + Number of neutrons Atomic Number = Number of protons Number of electrons 9 4 Be Beryllium has: 4 protons 4 electrons How many neutrons? Electronic structure 1st shell holds a maximum of 2 electrons 2nd shell holds a maximum of 8 electrons 3rd shell holds a maximum of 8 electrons • Each level/shell has a maximum number of electrons it can hold • Electrons will fill the levels nearer to the nucleus first Bonding How does electron structure affect reactivity? The reactivity of alkali metals increases going down the group. What is the reason for this? increase in reactivity Li Na The atoms of each element get larger going down the group. This means that the outer shell electron gets further away from the nucleus and is shielded by more electron shells. The further an electron is from the positive nucleus, the easier it can be lost in reactions. K This is why the reactivity of the alkali metals increases going down group 1. Ionic and covalent bonding • When elements react, their atoms join with other atoms to form molecules and/or compounds. This is Bonding. • Bonding involves giving, taking or sharing electrons to form ions or molecules Conservation of mass No atoms are lost or made during a chemical reaction so the mass of products equals the mass of the reactants Limestone Limestone cycle Pros and cons of quarrying Extracting metals How does reactivity affect extraction? increasing reactivity The reactivity of a metal determines how it is extracted. potassium sodium calcium magnesium aluminium (carbon) zinc iron lead (hydrogen) copper silver gold platinum Metals above carbon in the reactivity series must be extracted using electrolysis. Electrolysis can also be used to purify copper. Metals less reactive than carbon can be extracted from their ores by reduction using carbon, coke or charcoal. Platinum, gold, silver and copper can occur native and do not need to be extracted. Electrolysis of copper salts Copper can be obtained from solutions of copper salts by electrolysis or by displacement using scrap iron Alloys can be designed to have properties for specific uses Stainless steel Low carbon steel High carbon steel Low carbon steels are easily shaped, high carbon steels are hard and stainless steels are resistant to corrosion Hydrocarbons Hydrocarbons • Most of the compounds in crude oil consist of molecules made up of hydrogen and carbon atoms only (hydrocarbons) Alkanes • Most of these are saturated hydrocarbons called alkanes which have the general formula CnH2n+2 Fractional distillation • The many hydrocarbons in crude oil maybe separated into fractions by evaporating the oil and allowing it to condense at a number of different temperatures. • Each fraction contains molecules with similar number of carbon atoms. •This process is called fractional distillation Problems with burning hydrocarbons Burning fuels Acid rain • Sulphur dioxide and oxides of nitrogen cause acid rain Burning fuels Global warming Carbon dioxide causes global warming Burning fuels Global dimming • Solid particulates cause global dimming Burning fuels Removing sulphur • Sulphur can be removed from fuels before they are burned, for example in vehicles. • Sulphur dioxide can be removed from waste gases after combustion for example in power stations Cracking Cracking • The vapours are either passed over a hot catalyst or mixed with steam and heated to a very high temperature so that thermal decomposition reactions then occur Alkenes • Alkenes are unsaturated hydrocarbon molecules: contain at least one C=C double bond • Alkenes have the general formula CnH2n Testing for double bonds Testing for alkenes • Alkenes react with bromine water, turning it from orange to colourless Polymers Polymerisation • Alkenes can be used to make polymers such as poly(ethene) and poly(propene). • In these reactions many small molecules (monomers) join together to form very large molecules (polymers) Polymers- plastic bags Advantages of plastic bags Disadvantges of using plastic bags Reuse & recycle- saves raw materials Non biodegradable / crude oil Fills up land fills and land fills are an Reuse & recycle- saves energy eyesore Reuse & recycle- cuts down on CO2 emissions Reuse & recyle- Less global warming Burning- can use them to make energy Burning can increase CO2 Burning can increase global warming Producing ethanol - steam • Ethanol can be produced by hydration of ethene with steam in the presence of a catalyst Vegetable oils Plant oils • The plant material is crushed and the oil removed by pressing or in some cases by distillation. • Water and other impurities are removed Plant material Crushed Pressed or distilled Water & impurities removed What are the differences between fats? Saturated fats contain no carbonto-carbon double bonds. The straight fatty acids chains pack closely together. Unsaturated fats contain at least one carbon-to-carbon double bond. This bends the fatty acid chains and they cannot pack closely together. Saturated fats are less healthy than unsaturated fats because the dense packing makes them harder for the body to digest. Making margarine • Hydrogen adds to the carbon=carbon double bonds. • The hydrogenated oils have higher melting points so they are solids at room temperature, making them useful as spreads and in cakes and pastries Oil and water • Oils do not dissolve in water • They can be used to produce emulsions Emulsifier molecule - Higher tier • Emulsifiers have hydrophilic and hydrophobic properties Earth’s structure The Earth’s structure The Earth’s movement • The Earth’s crust and the upper part of the mantle are cracked into a number of large pieces (tectonic plates) Evidence for Wegener’s theory... • Continents fit together like a jigsaw puzzle • Similar fossils and rocks found on coastlines of continents How do tectonic plates move? • Radioactive processes in earth’s core release heat... • ...Heat creates a convection current in mantle... • ...which moves the plates Why can scientists not accurately predict when earthquakes will occur? • Earthquakes involve sudden movements between plate boundaries so... • ...so don’t know where or when the force/ pressure is building up – and reaches its limit The Earth’s atmosphere today How was our atmosphere formed? • • • • First billion years - there was intense volcanic activity. This activity released the gases that formed the early atmosphere and water vapour that condensed to form the oceans. There may also have been water vapour and small proportions of methane and ammonia. Plants produced the oxygen that is now in the atmosphere Tips for the exam Long exam questions – 6 marks For 6 marks: 3 advantages/ disadvantages Use of key scientific words Excellent spelling Excellent grammar and punctutation No bullet points! Some extra stuff... Reliable Repeating tests, checking results, having a bigger sample Valid Keep everything the same except the independent & dependent variables Precision Smaller scale division on equipment Claims You decide if it is true or false by looking at evidence , independent organisations avoid bias Ethical issues Religious reasons, suffering, human rights Environmental issues How does it affect the atmosphere / global warming, habitat destruction Key words • Range = from smallest to biggest values • Interval = what the values go up by Eg: 2, 4, 6, 8, 10: Interval = 2 Don’t forget... Describe a graph Refer to the pattern e.g. as……...increases………increases etc Explain Describe & give a reason “because…….” Evaluate For & against Compare What is the same & what is different Calculate Show calculations & give units Suggest a reason This should be scientific Some final tips... • Read the whole Q – 33% of the Qs can be answered from information given to you in text, diagrams, graphs & tables • Follow instructions – “tick one box” “tick two boxes” “use info from the table” • Don’t write “it” – “the concentration increases” NOT “it increases” • What is the Q asking you to do? Remember... • 1 mark per minute – you have 45 minutes to answer 45 marks • Use bullet points – 3 marks should mean 3 bullet points Good luck!