Introduction to Nomenclature Rules and Practice PPT

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Naming and

Formula Writing for

Ionic and Covalent

Compounds

1

Objectives…

 List differences among ionic and covalently bonded compounds

 Identify polyatomic and monatomic ions and name them properly

 Write the chemical formulas and names for ionic compounds

 Write the chemical names and formulas of acids

 Write the chemical names and formulas of molecules

2

Review of Ionic Compounds (Crystals)

 Transfer of electrons

 Made from a metal and a non-metal

 Metals lose electrons, nonmetals gain electrons

 Chemical formula is arranged in the smallest whole number ratio (empirical formula)

 Formula unit: the smallest repeating pattern within a crystal

 Even though ionic compounds are made up of ions, they ARE ELECTRICALLY

NEUTRAL!

3

Ions can be monatomic or polyatomic:

 Monatomic:

Made up of a single atom

 Polyatomic:

Made up of multiple atoms

Remember…

Group #: 1 2 13 14 15 16 17 18

Charge: +1 +2 +3 X -3 -2 -1 X

4

 Monatomic cations have the same name as the element

 Example: Na +1 = Sodium ion, Ca +2 =

Calcium ion

 Monatomic anions have the ending of the element name changed to“-ide”

 Example: Cl -1 =chloride ion, O -2 =oxide ion

5

Polyatomic ions:

(See polyatomic ion sheet) are made up of two or more elements covalently bonded together with an overall positive or negative charge.

6

Review Molecular Compounds (Molecules)

 Sharing of electrons

 Made from nonmetals only

 Molecules of the same compound are

IDENTICAL and INDEPENDENT of each other

 Chemical formula indicates the exact makeup of one molecule (molecular formula)

7

Rules for Formula Writing

(Ionic Compounds)

Since all compounds are neutral, figure out how many of each ion is needed to make a neutral compound.

(Neutral means having a net zero charge.)

8

Mg and Cl

Mg +2 Cl -1

Cl -1

Examples

MgCl

2

Al and O

Al +3 O -2

Al +3 O -2

O -2

Al

2

O

3

9

More Examples

Ca and S

Ca +2 S -2

CaS

Ca and (AsO

4

)

Ca +2 (AsO

4

) -3

Ca +2 (AsO

4

) -3

Ca +2

Ca

3

(AsO

4

)

2

Parentheses are needed if there is more than one of the polyatomic ions!

10

Chemical Name to Formula

Aluminum Sulfite

Al +3 (SO

3

) -2

Al +3 (SO

3

) -2

(SO

3

) -2

Al

2

(SO

3

)

3

11

More Examples

Silver Sulfate

Ag ?

+1 (SO

4

) -2

Ag +1

Ag

2

(SO

4

)

Use your Periodic Table to determine the charge on transition metals!

12

More Examples

Nickel (II) Nitrate

Ni +2 (NO

3

) -1

(NO

3

) -1

Ni(NO

3

)

2

The Roman Numeral will always tell you the charge and it will always be positive

13

More Examples

Iron (III) Chloride

Fe +3 Cl -1

Cl -1

Cl -1

FeCl

3

14

Chemical Formula to Name

Recall the format for chemical formulas…

(name of cation – metal) (name of anion – nonmetal)

Examples:

KBr Potassium Bromide

CaI

2

Na(SO

4

)

Calcium Iodide

Sodium Sulfate

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For elements with more than one possible charge (transition metals)…

Use the charge on the anion to determine the charge on the cation!

Example:

Fe

2

(CrO

4

)

3

+6/2=+3 -2(3)=-6

Iron (III) Chromate

16

Example:

Sn(CO

+4

3

)

-2(2)=-4

2

Tin (IV) Carbonate

17

Example:

Cu

3

P

+3/3=+1 -3

Copper (I) Phosphide

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Criss Cross Short Hand Method

Just use the number of the charge (not the charge itself) and criss cross as shown below. You will note that the overall charge is neutral, as the total positive charge of the metals offsets the total negative charge of the nonmetal.

Naming Acids

Acids are ionic compounds that contain H +1 as their cation.

Acids are named based on their anion .

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If the anion ends in…

“-ide”  hydro ___ ic acid

The root name of the anion goes here

(remove-ide)

Example: H

2

S Sulfide (S -2 ) is the anion!

Hydrosulfuric acid

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If the anion ends in…

“-ate”  ___ ic acid

Example: H

2

SO

4

Sulfate (SO

4

-2 ) is the anion!

Sulfuric acid

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If the anion ends in…

“-ite”  ___ ous acid

Example: H

2

SO

3

Sulfite (SO

3

-2 ) is the anion!

Sulfurous acid

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Mnemonic devices to help you remember Acid

Nomenclatire

#1) “eight is great”er number of oxygens

“ite” is slight” less number of oxygens

#2) Chemistry “Diseases” (joke..I am suffering from eight-ic-ite-ous or)....

“ate” -ic “ite”-ous

SO

4

= sulfate

H

2

SO

4

Sulfuric Acid

SO

3

= sulfite

H

2

SO

3

Sulfurous Acid or lessous

NO

2

= nitrite icmore

NO

3

= nitrate

HNO

2 nitrous acid HNO

3 nitric acid

H

3

PO

3

PO

3

= phosphite PO

4

= phosphate

= phoshporous Acid H

3

PO

4

= phosphoric Acid

Formula Writing

Use the reverse to determine the anion and balance out the charges for a neutral compound.

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Examples

Hydrophosphoric acid All acids contain a H +1 charge as the cation!

H +1 P -3

H +1

H +1

H

3

P

Original ending “ide”

Ask yourself, “What was the original ending?”

26

Examples

Chromic acid

Original ending “ate”

H +1 (CrO

4

) -2

H +1

H

2

CrO

4

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Naming Molecular Compounds

Recall, covalently bonded molecules are made up of nonmetals only.

28

Prefixes

mono – 1 hexa – 6 di – 2 hepta – 7 tri – 3 tetra – 4 penta – 5 octa – 8 nona – 9 deca - 10

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Rules

 Use the prefixes to indicate how many of each element is in one molecule.

 Change the ending on the second element to “-ide”

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Examples

N

2

O

4 dinitrogen tetraoxide

CO carbon monoxide

SiO

2 silicon dioxide

If there is only one of the first element, do not write mono.

31

Formula Writing

 Use the prefixes to determine the subscripts

Examples: trisulfur hexafluoride

S

3

F

6 carbon pentaoxide CO

5

P

4

O

2 tetraphosphrous dioxide

DO NOT REDUCE!

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