AP Chemistry Syllabus 2014 – 2015 Loy Norrix High School Instructor: Claudia Witt Contact Information: Email: wittcl@kalamazoo.k12.mi.us or witt1cl@gmail.com Phone: (269) 337-0220 x2271 Cell: (248) 321-5167 AP Course Description: This course is structures around six big ideas articulated in the AP Chemistry curriculum framework provided by the College Board. [CR2] A special emphasis will be placed on the seven SPs which capture important aspects of the work that scientists engage in, with learning objectives that combine content with inquiry and reasoning skills. AP Chemistry is open to all students that have completed Chemistry A and B who wish to take part in a rigorous and academically challenging course. Lab Requirement: Laboratory periods average two to three days each. Students are engaged in hands-on laboratory work, integrated through the course that accounts for more than 25% of the class time. [CR5a] Students will complete at least 16 hands-on laboratory experiments integrated throughout the course while using basic laboratory equipment to support the learning objectives listed within the AP Chemistry curriculum framework. [CR5b] After the AP exam, student will have an opportunity to connect their knowledge of Chemistry and science to major societal or technological components to help them scientifically literate citizens. [CR4] From the 2012-2013 course bulletin: Description: This course is designed to be a comprehensive college-level introductory course in physical chemistry. Strong emphasis is placed upon laboratory work. This course is recommended for Chemistry and Biology majors, and especially for students planning a career in any health-related or investigative science field including pre-medicine, pre-nursing, pre-dentistry, engineering (all types), and careers in biology, chemistry, pharmacology, or health care. Activities include special projects, field trips, in-depth preparation for the AP exam, and extended laboratory investigations. *Due to the rigor of AP courses, students are strongly encouraged to complete a summer assignment as suggested by the AP teacher. Content from summer assignments will be included on an assessment during the first trimester. Prerequisite: Honors Chemistry A and B or Chemistry A and B 1 Weighted Grade Value: All Advanced Placement courses have been designated as ‘weighted’. Students’ grades are not altered, but the point value (quality point) is increased and is reflected in a student’s GPA and class rank, and appears on the student’s transcript. Letter Grade A AB+ B BC+ C CD+ D DF Weighted Grade Values Quality points Percent Standard Weighted 93-100 4.0 5.0 90-92 3.7 4.7 87-89 3.3 4.3 83-86 3.0 4.0 80-82 2.7 3.7 77-79 2.3 3.3 73-76 2.0 3.0 70-72 1.7 2.7 67-69 1.3 2.3 63-66 1.0 2.0 60-62 0.7 1.7 0-59 0 0 Required Material – to be brought to class daily: Text: Chemistry, Eighth Edition by Zumdahl & Zumdahl (Holt McDougal, Publisher). 2012. Replacement Cost: $153 [CR1] Periodic Table Calculator (graphing if you have one) 3 Ring Binder (with dividers if possible) Planner Lab Notebook Grading: 10% Homework -The AP Chemistry teacher’s guide suggests 5 hours of homework per week. 50% Tests/Quizzes 40% Labs/Assignments Final Exam (each trimester): 20% of the final grade in the course 2 Homework: Homework will be given on a chapter basis (to be completed by the end of the chapter). Students will also be expected to complete work assigned during class. This may not necessarily occur daily but can include items like worksheets, AP practice questions, work not completed in class, and lab write ups. Homework is an essential part of AP Chemistry, as practice is imperative in understanding the process of doing problems. Students are encouraged to ask when they are having trouble or are stuck on a particular problem and/or concept. Attendance: If you are absent, it is your responsibility to find out what has been missed and make arrangements to make up the work. One day absence: Assignment(s) that were due the day you missed are due the day you return. If a test or quiz was scheduled for the day you missed, plan on taking it the day you return. It is EXTREMELY important that you do not get behind in this class. Remember you will then be responsible for getting work from that class period! Multiple absences: For every day you miss, you will have three days to make up work you missed. It is YOUR responsibility to turn in assignments on time. Once the make-up time has passed, you will no longer be able to make up work. You must also maintain the work currently being covered in class. Any tests or quizzes that were missed during multiple absences will be taken after school or during lunch. An alternate essay/short answer make-up version may be used. If you are absent from school, it is expected that you continue to complete the assigned homework on time unless alternative arrangements with the instructor are made. Missed Labs: If you are absent when a lab is scheduled, see the teacher on the day you return to school. You will either be instructed to make up the lab on a given date after school, be given data to write up a report, or be assigned another alternative assignment. It is EXTREMELY important that you make every effort to be in school during lab days – lab concepts show up on the AP exam and need to be experienced in class whenever possible. No Cheating/Copying: Cheating/copying is not allowed. Anyone caught cheating on a quiz, test, or exam will receive a zero for the score. Please remember that it takes two to cheat. If any collaboration on individual assignments is suspected, all parties involved will receive a zero on the assignment. Your parent(s)/guardian and your assistant principal may be notified. Homework, class work, and lab reports are to be done individually unless instructed otherwise. Be aware that copying and helping are different. Study groups are recommended and encouraged! 3 Tests/Quizzes: Tests and/or quizzes may consist of multiple choice, equations, freeresponse problems, and memorization. Tests will be given at least once comprehensively per chapter. Quizzes will always be given with at least one day’s notice. Labs: All labs will be kept in an organized lab notebook. Each will require that the purpose, procedure, data, observations, calculations, and analysis be recorded in a laboratory notebook, with carbon copies (which will be turned in). A final, typewritten report will be produced. These full reports are intended to give intensive practice in technical writing of publishable quality. [CR7] **Lab notebook: may be required to receive college credit Quadrille ruled with carbons Rules: no white out, tearing out, scribbling (printing strongly recommended), single line cross out, large data tables, permanent pen (not water soluble) Carbon copy of data sheet to be turned in at the end of each lab activity **Lab reports cannot be turned in late, unless arranged in advance. Note: Some lab reports will consist of one typewritten summary page with any required graphs attached. This is intended to introduce the model of an industry-based, summary report. 4 AP Chemistry Lab Report Format Prelab: Must be completed by the day of the lab! A. Beginning Questions or ideas B. Safety considerations C. Procedure a. If procedure is given – draw in picture form b. If procedure is not given – outline a possible procedure. Observations, Data Table, and Calculations: A. B. C. D. Observations of chemicals and the experiment in general Group data Class Data Calculations Claims: Make a statement that links the observation back to original question. They help you figure out what the lab actually means. Do not just repeat an observation. “This is what happened…” Evidence: Write an explanation to support your claim(s). Answers “How do I know?” and “Why am I making these claims?” Your explanation should address two specific things: a. Use data to defend your claim. b. The chemistry concepts must be included in your explanation and tied back to the data. Reading/Reflection: This section is meant to help you understand your results and interpretations of the activity in the context of the class data/information. The following things should be addressed in this section. a. What is the concept(s) learned or applied in this experiment? b. How does your groups work compare with other groups? The whole class? c. What is a possible source of error in this experiment? How was the final result affected by this source of error (increase or decrease)? Explain your reasoning. d. How does this compare to the information in your textbook or class notes? e. If predictions were made, were your predictions correct? Why or why not? f. What might be some real world applications related to this work? g. How have your ideas changed, what new questions do you have or what new things do you have to think about? 5 Questions: Questions should be rewritten in the lab notebook. Answers to each question should be immediately followed by the corresponding question. All answers should be written in complete sentences. General Rules and Hints: Write all reports in ink (no pencil). Use correct grammar, spelling and punctuation. Use a ruler for making lines Use headings on each section Use units on all data Single line out all errors and initial Sign and date all pages of your report at the bottom of the page Leave no open spaces Big Ideas Big Idea BIG IDEA 1: Structure of matter BIG IDEA 2: Properties of matter – characteristics, states, and forces of attraction BIG IDEA 3: Chemical reactions BIG IDEA 4: Rates of chemical reactions BIG IDEA 5: Thermodynamics BIG IDEA 6: Equilibrium Correlating Chapters Summer assignment (chapters 1 - 3), Chapter 5, 7, 8, 9, 10 Chapter 5, 7, 8, 9, 10, 11 Chapter 4, 18 Chapter 12 Chapter 6, 16, 17.3 Chapter 13, 14, 15 Course Objectives Chapters 1-3: Chemistry and Measurement; Atoms, Molecules, and Ions; Calculations with Chemical Formulas and Equations Know the basic units of measurement and their prefixes Be able to do mathematical work and express measurements accurately, with the proper number of significant figures Understand the principle of dimensional analysis and be able to use it to make unit conversions Be able to identify examples of the three laws in section 2.2 (Laws of Conservation of Mass, Definite Proportions, Multiple Proportions) Name and characterize the subatomic particles and determine the numbers of each for any atom and its isotopes 6 Distinguish the two types of bonding and show how each relates to atoms, molecules, ions, and formula units Identify the major parts of the periodic table and use it to determine the general characteristics of elements Memorize the table of polyatomic atoms – see textbook Be able to write names and formulas for binary ionic compounds, ionic compounds with polyatomic ions, binary covalent compounds, and the acids Use given data to calculate the average atomic mass for an element Be able to convert between moles, mass, and numbers of particles for a given sample of element or compound Be able to calculate molar mass Be able to determine the percent composition of a compound Calculate empirical and molecular formulas from mass percent data Interpret a balanced equation in four ways Be able to write and balance chemical equations Use the ratio of coefficients in a balanced equation to calculate the masses of reactants and products = definition of stoichiometry Know how to recognize a limiting reagent problem, calculate masses of product, excess reagent, and percent yield Chapter 4: Chemical Reactions Explain why water is such a good dissolver (solvent) Characterize a substance as a strong, weak, or non-electrolyte Be able to solve solution concentration and dilution problems using molarities Be able to recognize, balance, and predict the products of five types of reactions Be able to predict/identify the products of precipitate reactions Write solution reaction equations three ways Use everything you know to solve stoichiometry problems Understand the meaning of equivalence point and its use in the stoichiometry of titration problems Be able to assign oxidation states and identify the parts of a redox reaction Be able to balance redox equations by the half reaction method in both acidic and basic solutions Chapter 18: Electrochemistry Be able to balance redox equations by the half reaction method in both acidic and basic solutions Be able to identify the parts of a galvanic cell and their operation Calculate standard cell potentials, E°cell Completely describe a galvanic cell Use table 18.1 to predict the results of redox reactions Memorize and use the Nernst equation Use electrolysis conversion factors in stoichiometry problems Use E° values to predict the plating order of a mixture of ions Chapter 5: Gases Define and convert various units of pressure 7 Demonstrate how most gas laws follow from the ideal gas law Calculations for all gas laws (*including ideal) Solve stoichiometry problems with 22.42 L/mol at STP Given the density, calculate the molar mass of a gas Relate Dalton’s Law of Partial Pressures to mole fraction and vapor pressure Relate the principles of the Kinetic Molecular Theory to observed gas behavior Calculate root mean square velocity for any gas at any temperature Use Graham’s Law of Effusion Describe why real gas behavior deviates from the ideal and relate this behavior to experimental conditions Use Van Der Waal’s equation to compensate for real conditions Chapter 6: Thermochemistry Be familiar with the key terms of energy systems (language and concepts) Calculate ∆E for systems and the work done by expanding gases Define enthalpy (H) and calculate ∆H for a reaction Use calorimetry data to calculate changes in enthalpy Use Hess’s Law to calculate ∆H for a chemical reaction Use standard enthalpies of formation (∆H°f) to calculate ∆H°rxn Chapter 7-9: Atomic Theory, Structure, and Bonding Calculate wavelength, frequency, or speed of electromagnetic radiation Calculate the size of a quantum of energy Calculate the wavelength of a given particle Calculate the energy of an excited hydrogen electron Determine electron configuration from the periodic table Define the four quantum numbers and determine their reasonableness Predict how five characteristics of atoms change in a periodic way across periods and down groups Characterize ionic and covalent bonding Calculate ∆H°rxn using bond energies Be able to write Lewis structures for simple covalent molecules and polyatomic ions Show resonance; distinguish most likely structure with formal charge Know exceptions Use VSEPR to predict molecular structure, name shapes, determine polarity, and bond angles Relate VSEPR geometry to orbital hybridization Describe and identify the two main types of covalent bonds Be able to write the molecular electron configuration, calculate bond order, and predict magnetism in simple molecules Chapter 10-11: States of Matter and Solutions Describe the three intermolecular forces Relate the properties of molecular vs. ionic solids to the forces binding them together Describe the process of vaporization and use the Clausius-Clapeyron equation Interpret changes of state in terms of vapor pressure and relate them to the ClausiusClapeyron equation 8 Interpret a phase diagram Given data, express solution concentration five ways Describe three physical factors that affect solubility Explain why the addition of a non-volatile solute lowers the vapor pressure of the solvent Use Raoult’s Law to determine the vapor pressure of electrolytic, non-electrolytic and ideal solutions, and the molar mass of an unknown substance Explain the effect of a solute on the boiling point, freezing point, and osmotic pressure of a solvent Calculate molar mass from colligative properties Use the van’t Hoff factor in calculations with electrolytic solutions Chapter 12: Reaction Kinetics Appreciate the meaning of reaction rate Define reaction rate and write rate expressions from data Define two kinds of rate laws Use experimental data to establish zero, first, and second order rate laws, and values for k Understand and memorize table 12.6 Use the integrated rate laws to solve for k, t, or [A] Be able to judge the reasonableness of a proposed reaction mechanism in two ways Use collision theory to explain the effects of several factors on reaction rate Chapter 13: Chemical Equilibrium Write equilibrium expressions and calculate Keq Be able to convert Keq to Kp Use Keq to predict the direction in which a reaction will move to reach equilibrium Be able to calculate equilibrium concentrations Be able to predict the shifts in equilibrium positions that are stressed Chapter 14: Acids and Bases Recognize and write acid/base neutralization reactions Write equilibrium expressions for Ka, Kb, and Kw Distinguish between strong and weak acids/bases and relate terms to the equilibrium position Calculate pH, pOH, etc. for various solutions Calculate pH for a variety of acid/base solutions Chapter 15: Acid-Base Equilibria Calculate pH for solutions containing common ions and for buffers Calculate the pH at any point in any titration Be able to select the proper indicator for a titration Write expressions and solve problems using Ksp 9 Chapter 16, 17.3: Thermodynamics Understand the relationship of free energy to entropy, enthalpy, and temperature as a function of perspective Be able to calculate ∆G°, ∆S°, and ∆H° Calculate ∆G as a function of pressure, Ksp, and cell potential Chapter 22: Organic Chemistry Be able to name and write formulas for simple organic substances Course Outline Weeks: One – Three Chapters: 1 - 3 Labs: Percent Composition of Copper in a Penny: Inquiry Lab [CR6] SP 3, 4, 5, 6 Finding the Ratio of moles of Reactants in a Chemical Reaction [CR5b] SP 1, 6 Activities: Understanding the Meaning of a Balanced Chemical Equation [CR3a] LO 1.1 Book Questions: [CR3a] Chapter 1: 16, 21, 24, 25, 27, 28, 29, 31, 33, 34, 36, 37, 39, 43, 45, 49, 51, 53, 59, 63, 65, 67, 73, 75, 77, 80, 83, 90, 91 Chapter 2: 19, 21, 23, 25, 28, 31, 32, 33, 43, 45, 46, 47, 49, 51, 55, 57, 59, 61, 63, 65, 67, 69, 71, 73, 75, 77, 79 Chapter 3: 10, 11, 13, 16, 20, 21, 25, 27, 32, 36, 38, 42, 46, 47, 49, 51, 53, 56, 57, 61, 65, 68, 71, 74, 75, 77, 79, 81, 83, 85, 87, 91, 93, 95, 99, 103, 105, 107, 109, 112, 117, 121, 126, 129, 135, 139, 143 10 Weeks: Four - Five Chapters: 4 Labs: How much acid is in fruit juice and soft drinks?: Inquiry Lab [CR6] SP 3, 5, 6 How can we determine the actual percentage of H2O2 in a drugstore bottle of hydrogen peroxide?: Inquiry Lab [CR6] SP 4, 5 Activities: Book Questions: [CR3c] Chapter 4: 23, 24, 25, 27, 28, 29, 31, 33, 35, 40, 43, 45, 47, 55, 59, 61, 66, 69, 73, 74, 77, 79, 81, 83, 87bcd LO 1.1, 1.2, 1.3, 1.4, 1.14, 1.17, 1.18, 1.19, 3.1, 3.3, 3.4, 3.6 Weeks: Five – Seven Chapter: 18 Labs: Electrochemical Cells [CR5b] SP 3, 6 Activities: The energizer lab part B [CR3c] LO 3.12, 3.13, 5.16 Book Questions: [CR3c] Chapter 18: 16, 17, 29, 31, 33, 35, 37, 43, 45, 53, 55, 57, 59, 63, 67, 73ac 11 Weeks: Eight – Ten Chapter: 5 Labs: Determining the Molar Volume of a Gas [CR5b] SP 6, 7 Activities: Book Questions: [CR3a, CR3b] Chapter 5: 35, 39, 41, 42, 46, 48, 51, 53, 57, 58, 60, 62, 66, 72, 79, 80, 85, 90, 95, 97, 101, 104, 106, 107 LO 2.5, 2.6 Week: Ten and Eleven Chapter: 6 Labs: Specific Heat of a Metal: Inquiry Lab [CR6] SP 2, 5 The Hand Warmer Design Challenge: Where does heat come from?: Inquiry Lab [CR6] SP 4, 7 Activities: Energy and Phase Change [CR3e] Probability, Distinguishable Molecular Arrangements, and Mixing [CR3e] LO 6.24 Book Questions: [CR3e] Chapter 6: 16, 24, 28, 29, 35, 36, 37, 40, 44, 46, 50, 52, 53, 55, 57, 59, 63, 64, 68, 69, 74, 77, 82 12 Week: Twelve - Fifteen Chapter: 7, 8 and 9 Labs: VSEPR Theory Molecular Modeling Lab [CR5b] SP 1, 3 Activities: Book Questions: [CR3b] Chapter 7: 38, 40, 42, 43, 46, 68, 70, 73, 74, 76, 79, 81, 93, 94, 98, 120, 122, 125 LO 1.10, 1.11, 1.12 Chapter 8: 28, 29, 32, 34, 35, 38, 40, 42, 45, 46, 51, 52, 80, 81, 82, 87, 89, 104, 107, 108, 112, 113 LO 1.7, 1.8, 2.13 Chapter 9: 18, 23 LO 2.29, 2.30 Week: Sixteen – Eighteen Chapters: 10 and 11 Activities: Book Questions: [CR3a, CR3b] Chapter 10: 33, 38, 89, 90, 92, 97 LO 1.15, 2.3 Chapter 11: 29, 30, 33, 43, 51, 54, 58, 65, 66, 70, 76, 78, 80, 82, 86 LO 1.16, 1.19 13 Week: Nineteen and Twenty Chapter: 12 Labs: Kinetics of a Burning Candle: Inquiry Lab [CR6] SP 1, 7 How long wills that Marble Statue Lab?: Inquiry Lab [CR6] SP 3, 4 Activities: Iodine Clock Demo and Collins writing [CR3d] LO 4.1, 4.9 Catalyst Student Demo [CR3c] LO 4.1, 4.9 Book Questions: [CR3d] Chapter 12: 21, 28, 30, 32, 33, 34, 36, 37, 41, 42, 48, 50, 52, 53, 56, 59, 64, 69 Week: Twenty and Twenty one Chapter: 13 Activities: All Things Being Equal [CR3d] LO 2.2, 6.8 Book Questions: [CR3d] Chapter 13: 21, 22, 24, 28, 30, 32, 38, 44, 50, 51, 53, 54, 56, 60, 64, 66, 68 14 Week: Twenty two – Twenty four Chapter: 14 Labs: An introduction to the pH meter: strong acids and bases [CR5b] SP 1, 2 More titration curves [CR5b] SP 2,3 Weak acid vs. Strong base titration curve [CR5b] SP 2, 6 Identification of a polyprotic acid [CR5b] SP 2, 5 Acidimetry and alkalimetry lab [CR5b] SP 2, 5, 7 Activities: My Acid can beat up your acid [CR3f] LO 2.2, 6.11 Handout #2: Acid-Base neutralization reactions [CR3f] LO 6.11, 6.15 Book Questions: [CR3f] Chapter 14: 34, 36, 37, 39, 40, 41, 42, 43a-c, 44, 47, 48a-c, 49, 50, 51, 52, 53, 54, 55, 56, 58, 61, 62, 63, 64, 65, 67, 71a-c, 72, 73, 74, 79, 81, 82, 83, 87, 89, 90, 91, 92, 94, 95, 98, 104, 106, 107, 109, 111, 112, 116, 118, 134 15 Week: Twenty Four – Twenty Seven Chapter: 15 Activities: Book Questions: [CR 3f] Chapter 15: 18, 19, 22, 24, 30, 33, 34, 36, 49, 52, 54, 56, 62 LO 1.2, 6.20 Week: Twenty Seven – Twenty Nine Chapter: 16, 17.3 Activities: Book Questions: [CR 3e] Chapter 16: 22, 24, 28, 37, 40, 47, 54, 67 LO 6.21,6.22 Chapter 17: 30, 32, 34, 36, 37, 42, 44, 49, 51, 60, 62 LO 5.18 Week: Twenty Nine Chapter: 22 Week: Thirty – Thirty one Review for AP Chemistry Exam AP Exam: Monday May 5th 8 am ***After the AP exam, students will integrate their knowledge of pH and water quality to complete tests on the “healthiness” of local water sources. They will present their findings in poster format. [CR4] 16 Curricular Requirements CR1 Students and teachers use a recently published (within the last 10 years) college-level chemistry textbook. CR2 The course is structured around the enduring understanding within the big ideas as described in the AP Chemistry curriculum framework. CR3a The course provides students with opportunities outside of laboratory environment to meet the learning objectives within Big Idea 1: Structure of matter. CR3b The course provides students with opportunities outside of laboratory environment to meet the learning objectives within Big Idea 2: Properties of matter – characteristics, states, and forces of attraction CR3c The course provides students with opportunities outside of laboratory environment to meet the learning objectives within Big Idea 3: Chemical Reactions CR3d The course provides students with opportunities outside of laboratory environment to meet the learning objectives within Big Idea 4: Rates of chemical reactions CR3e The course provides students with opportunities outside of laboratory environment to meet the learning objectives within Big Idea 5: Thermodynamics CR3f The course provides students with opportunities outside of laboratory environment to meet the learning objectives within Big Idea 6: Equilibrium CR4 The course provides students with opportunity to connect their knowledge of chemistry and science to major technological components (e.g. concerns, technological advances, innovations) to help them become scientifically literate citizens. CR 5a Students are provided the opportunity to engage in investigative laboratory work integrated throughout the course for a minimum of 25 percent of the instructional time. CR 5b Students are provided the opportunity to engage in a minimum of 16 hands-on laboratory experiments integrated through the course while using basic laboratory equipment to support the learning objectives listed within the AP Chemistry Curriculum Framework. CR6 The laboratory investigations used throughout the course allow students to apply the seven SPs defined in the AP Chemistry Curriculum Framework. At least 6 of the required 16 labs are conducted in a guidedinquiry format. CR7 The course provides opportunities for students to develop, record, and maintain evidence of their verbal, written, and graphic communication skills through laboratory reports, summaries of literature or scientific investigations, and oral, written, and graphic presentations. 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