AP® Chemistry Syllabus 2013-14 Ms. Maria Toner Room 317 maria.mastro3@gmail.com Curricular Requirements CR1 Students and teachers use a recently published (within the last 10 years) college-level chemistry textbook. CR2 The course is structured around the enduring understandings within the big ideas as described in the AP Chemistry Curriculum Framework. CR3a The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 1: Structure of matter. CR3b The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 2: Properties of matter-characteristics, states, and forces of attraction. CR3c The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 3: Chemical reactions. CR3d The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 4: Rates of chemical reactions. CR3e The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 5: Thermodynamics. CR3f The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 6: Equilibrium. CR4 The course provides students with the opportunity to connect their knowledge of chemistry and science to major societal or technological components (e.g., concerns, technological advances, innovations) to help them become scientifically literate CR5a Students citizens. are provided the opportunity to engage in investigative laboratory work integrated throughout the course for a minimum of 25 percent of instructional time. CR5b Students are provided the opportunity to engage in a minimum of 16 hands-on laboratory experiments integrated throughout the course while using basic laboratory equipment to support the learning objectives listed within the AP Chemistry Curriculum Framework. CR6 The laboratory investigations used throughout the course allow students to apply the seven science practices defined in the AP Chemistry Curriculum Framework. At minimum, six of the required 16 labs are conducted in a guided-inquiry format. CR7 The course provides opportunities for students to develop, record, and maintain evidence of their verbal, written, and graphic communication skills through laboratory reports, summaries of literature or scientific investigations, and oral, written, and graphic presentations. 1 Page(s) 1 1, 3 6 6 4 7 5 8 4 1 3, 4, 5, 6, 7, 8, 9 3, 4, 5, 6, 7, 8, 9 2 Course Description: The purpose of Advanced Placement Chemistry is to provide a college level course in chemistry and to prepare the student to seek credit and/or appropriate placement in college chemistry courses. Laboratory work and activities will average two to three days per week. Little time is spent on lecture. Students are engaged in hands-on laboratory work, integrated throughout the course that accounts for more than 25% of the class time. [CR5a] Emphasis is placed on depth of understanding of a topic, rather than breadth of topics. Students will be expected to read each chapter and take their own notes. Objectives: Students will: 1. Learn the inquiry process through numerous laboratory investigations. 2. Gain an understanding of the six big ideas as articulated in the AP Chemistry Curriculum Framework. [CR2] 3. Apply mathematical and scientific knowledge and skills to solve quantitative, qualitative, spatial, and analytic problems. 4. Apply basic arithmetic, algebraic, and geometric concepts. 5. Formulate strategies for the development and testing of hypotheses. 6. Use basic statistical concepts to draw both inferences and conclusions from data. 7. Identify implications and consequences of drawn conclusions. 8. Measure, compare, order, scale, locate, and code accurately. 9. Do scientific research and report and display the results of this research. 10. Learn to think critically in order to solve problems. Textbook: Zumdahl, Steven S., et. al., Chemistr y, 7th Edition. Boston, New York, Houghton Mifflin Company, 2007. [CR1] Lab Manual: Carolina Investigations for AP Chemistry 2 Laboratory Work: All of the laboratory experiments in this course are hands-on. Students will work in groups. They collect, process, manipulate, and graph data from both qualitative and quantitative observations. Inquiry is emphasized in many of the experiments that students complete. The laboratory work requires students to design, carry out, and analyze data using guided inquiry principles. For all labs, students are required to report the purpose, procedure, all data, data analysis, error analysis, results, and conclusions in a lab report that is submitted for grading. [CR7] Laboratory Notebook: A laboratory notebook is required for the course. All completed lab reports documenting all lab experiences must be included in the notebook. [CR7] The 10 Parts of a Laboratory Report [CR7] A specific format will be given to the student for each lab. Students must follow that format and label all sections very clearly. AP Chemistry lab reports are much longer and more in depth than the ones completed in the first year chemistry course. Therefore, it is important that students don't procrastinate when doing pre-lab and post-lab work. Late labs will not be accepted. Labs not completed in class must be done at lunch or before/ after school by appointment. Pre-Lab Work Pre-lab work is to be completed and turned in on the day the lab is performed. 1. Title The title should be descriptive. For example, "pH Titration Lab" is a descriptive title and "Experiment 5"is not a descriptive title. 2. Date This is the date the student performed the experiment. 3. Purpose A purpose is a statement summarizing the "point" of the lab. 4. Procedure Outline Students need to write an outline of the procedure. They should use bulleted statements or outline format to make it easy to read. If a student is doing a guided inquiry lab, they may be required to write a full procedure that they develop. 5. Pre-Lab Questions Students will be given some questions to answer before the lab is done. They will need to either rewrite the question or incorporate the question in the answer. The idea here is that when someone (like a college professor) looks at a student's lab notebook, they should be able to tell what the question was by merely looking at their lab report. It is important to produce a good record of lab work. 3 6. Data Tables Students will need to create any data tables or charts necessary for data collection in the lab. During the Lab 7. Data Students need to record all their data directly in their lab notebook. They are NOT to be recording data on their separate lab sheet. They need to label all data clearly and always include proper units of measurement. Students should underline, use capital letters, or use any device they choose to help organize this section well. They should space things out neatly and clearly. Post-Lab Work 8. Calculations and Graphs Students should show how calculations are carried out. Graphs need to be titled, axes need to be labeled, and units need to be shown on the axis. To receive credit for any graphs, they must be at least half a page in size. 9. Conclusions This will vary from lab to lab. Students will usually be given direction as to what to write, but it is expected that all conclusions will be well thought out and well written. 10. Post Lab Error Analysis Questions Follow the same procedure as for Pre-Lab Questions. Tests: A chapter test is assigned for each chapter. A comprehensive, standardized semester exam is administered at the end of 1st semester and a final exam at the end of the year. AP Exam Review: The final ten full class days before the AP Chemistry Exam are used for exam review and practice tests using old AP Chemistry exam materials. Students work in cooperative groups to solve a packet of free response problems from previous exams. Students practice net ionic equations and are quizzed on their progress. Several practice AP Exams are administered as part of the two-week review prior to the AP Chemistry Exam. 4 Course Outline: [CR2] Chapters in Zumdahl Chemistry 1. Chemical Foundations AP Chemistry Topic Covered None 2. Atoms, Molecules, and Ions Atomic Theory & Atomic Structure (BI 1 & 2) 3. Stoichiometry Stoichiometry (BI 3) 4. Solution Stoichiometry & Chemical Analysis Reaction Types & Stoichiometry (BI 3) 5. Gases Gases (BI 1 & 2) 6. Thermochemistry Thermodynamics (BI 5) 7. Atomic Structure and Periodicity Atomic Theory & Atomic Structure (BI 1 & 2) 8. Bonding -- General Concepts Chemical Bonding (BI 1 & 2) 9. Covalent Bonding: Orbitals Chemical Bonding (BI 1 & 2) 10. Liquids and Solids Liquids & Solids (BI 1 & 2) 11. Properties of Solutions Solutions (BI 2) 12. Chemical Kinetics Kinetics (BI 4) 13. Chemical Equilibrium Equilibrium (BI 6) 14. Acids and Bases Equilibrium (BI 6) 15. Applications of Aqueous Equilibria Equilibrium (BI 6) 16. Spontaneity, Entropy, and Free Energy Thermodynamics (BI 5) 17. Electrochemistry Reaction Types (BI 3) Nuclear Chemistry 18. The Nucleus -- A Chemist’s View 19. The Representative Elements: Groups 1A Descriptive Chemistry (BI 2) Through 4A 20. The Representative Elements: Groups 5A Descriptive Chemistry (BI 2) Through 8A Descriptive Chemistry 22. Organic Chemistry All AP Chemistry Exam Review (BI) refers to Big Ideas. Big Idea 1 – Structure of matter, Big Idea 2 – Properties of matter- characteristics, states and forces of attraction, Big Idea 3 – Chemical reactions, Big Idea 4 – Rates of chemical reactions, Big Idea 5 – Thermodynamics, Big Idea 6 – Equilibrium. Assignments: Chapter 1: Chemical Foundations Read and take notes: Pages 1-28 Key Terms: Page 29 For Review: Page 29-30 Problems: 6, 29, 30, 42, 57, 88. Labs:Safety/Lab Skills/Lab Preparation Kool Aid Chromatography (SP 1.4, 6.4; LO 2.13) [CR5b] & [CR6] 5 Week 1 9/3 Chapter 2: Atoms, Molecules, and Ions Read and take notes: Pages 39-67 Key Terms: Page 67-68 For Review: Page 67-68 Problems: 3, 41, 65, 69, 72, 74 Labs: Inquiry Chemical and Physical Changes (SP5.1, 5.3; LO3.1) [CR5b] Activity: Rutherford PhET simulation Week 2 9/9 Chapter 3: Stoichiometry Week 3 9/16 Read and take notes: Pages 77-113 Problems: 25, 29, 33, 57, 65, 68, 73, 83, 87, 94, 96, 99, 104 Key Terms: Page 113-115 For Review: Page 113-115 Labs: Guided Inquiry: Determination of the Formula of a Compound (SP 4.2, 5.1, 6.4; LO 3.5) [CR5b] & [CR6] Stoichiometry of Chemical Reactions (SP 2.1, 2.2, 4.2, 5.1, 6.4; LO 3.3, 3.5) [CR5b] & [CR6] Activity: LO 3.6: Use data from synthesis or decomposition of a compound to confirm the conservation of matter and the law of definite proportions. The students present problems to the class in which they demonstrate how to find the empirical formula of a compound from data on the percent composition by mass. [CR3c] Chapter 5: Gases TBD…. Read: Pages 179-214 Key Terms: Page 215 For Review: Pages 215-216 Problems: 23, 31, 36, 43, 46, 48, 52, 55, 57, 60, 63, 66, 69, 71, 73, 75, 79, 81 Labs: Gas Laws: Reaction of Zinc with Hydrochloric Acid (SP 1.3, 1.4, 6.4, 7.2; LO 2.4, 2.5) [CR5b] & [CR6] Activity: Gas Properties Gas Laws Quantitative [CR 4] Chapter 6: Thermochemistry Read and take notes: Pages 229-263 Key Terms: Page 264 For Review: Pages 264-265 Problems: 29, 32, 37, 39, 41, 42, 43, 45, 46, 48, 50, 44, 47, 53-55, 56-58, 84, 86 Labs: Fundamentals of Calorimetry (SP 4.2, 5.1, 6.4; LO 5.6, 5.7) [CR5b] & [CR6] Guided Inquiry: Molar Heat of Fusion of Ice (SP 4.2, 5.1, 6.4; LO 5.6, 5.7) [CR5b] & [CR6] Activity: LO 5.2: Energy Forms and Changes Simulation [CR3e] Chapter 12: Chemical Kinetics Read and notes: Pages 527-563 Key terms: Page 564 For review: Pages 564-566 Problems: 19-21, 23-25, 26-28, 29-43 odd, 65, 66, 71, 73 Labs: Factors Affecting Reaction Rates (SP 4.2, 6.4; LO 4.1, 4.2) [CR5b] & [CR6] Chemical Kinetics (SP 5.1, 6.4; LO 4.1, 4.2, 4.4) [CR5b] & [CR6] Guided Inquiry: Factors that affect reaction rates and determining reaction rates and reaction mechanisms (SP 6.2, 7.2; LO 4.5, 4.9) [CR5b] & [CR6] Activity: LO 4.8: Translate among reaction energy profile representations, particulate representations, and symbolic representations (chemical equations) of a chemical reaction occurring in the presence and 6 absence of a catalyst. Students create energy diagrams to explain why catalysts and raising the temperature can increase the rate of a chemical reaction. [CR3d] Chapter 13: Chemical Equilibrium Read and take notes: Pages 578-610 Key Terms: Pages 610-611 For Review: Pages 610-612 Problems: 19, 21, 25, 29, 32, 34, 37, 39, 44, 45, 46, 49, 54, 55, 57, 59, 61, 63, 66, 67, 71 Lab: Le Chatelier's Principle and Equilibrium Shifts (SP 4.2; LO 6.9) [CR5b] & [CR6] Guided Inquiry: Factors Affecting Reaction Rates Activity: LO 6.1: Given a set of experimental observations regarding physical, chemical, biological, or environmental processes that are reversible, student is able to construct an explanation that connects the observations to the reversibility of the underlying chemical reactions or processes. CR5b—Students are provided the opportunity to engage in a minimum of 16 hands-on laboratory experiments integrated throughout the course while using basic laboratory equipment to support the learning objectives listed within the AP Chemistry Curriculum Framework. CR6—The laboratory investigations used throughout the course allow students to apply the seven science practices defined in the AP Chemistry Curriculum Framework. CR3d—The course provides students with opportunities outside the laboratory environment to meet the learning objectives within Big Idea 4: Rates of chemical reactions. Students view the NO2/N2O4 Equilibrium simulation available on the General Equilibria Animations Index page at Iowa State University and verbally report and discuss their answers to teacher supplied questions regarding the number of reactant and product molecules present at a particular point in the equilibrium process, the breaking and forming of bonds during the process, and how the reactant and product molecules are changing in order to illustrate the dynamic nature of equilibrium. [CR3f] Dueling Graduted Cylinders ****NEEDS CR AND SP Chapter 4: Types of Chemical Reactions and Solution Stoichiometry Read and take notes: Pages 127-154 (Up to Oxidation-Reduction Reactions) Key Terms: Page 168-169 (Up to Section 4.9) For Review: Pages 169-170 (1-8) Problems: 36, 45, 71, 17, 19, 25, 37, 39, 41, 44, 51, 53, 55, 74, 87 Labs: Observe a Decomposition Reaction [CR5b] & [CR6] Guided Inquiry: Identification of Chemical Reactions (SP 1.5, 2.2, 4.2, 5.1, 6.4; LO 1.19, 2.10, 3.2, 3.3) [CR5b] & [CR6] Activity: Net Ionic Reactions *** NEEDS LO Chapter 14: Acids and Bases Read and take notes: Pages 623-667 Key Terms: Page 668 For Review: Pages 668-672 Problems: 28, 30, 37, 44, 47, 50, 54, 81, 84, 59, 63, 66, 71, 73, 76, 87, 90, 95, 100, 103, 109, 111, 116, 117, 119, 121 Labs: Guided Inquiry: What is the Concentration of the Acid in this Drink? (SP 6.4; LO 6.20) [CR5b] & [CR6] Activity: Acid-Base Macro Particulate Symbolic Acid Base Solutions - Concentration and Strength 7 Chapter 15: Applications of Aqueous Equilibria Read and take notes: Pages 681-736 Key Terms: 736-737 For Review: 736-738 Problems: 13, 24, 26, 27, 29, 33, 35, 37, 39, 42, 43, 44, 55, 59, 61, 63, 70, 78, 82, 85, 90, 93, 96, 97, 100, 102, 115, 121 Labs: Preparation of a Buffered Solution (SP 4.2, 5.1, 6.4; LO 1.20) [CR5b] & [CR6] Guided Inquiry: Evaluating Lemonade as a Buffer (SP 4.2, 5.1, 6.4; LO 1.20) [CR5b] & [CR6] Activity: Titration Curves of Strong and Weak Acids and Bases (SP 1.4, 6.2, 6.4; LO 1.18, 6.12) [CR5b] Determination of a Solubility Product Constant (SP 2.1, 2.2, 2.3, 3.1, 3.2, 3.3, 4.1, 5.1; LO 1.4, 3.3, 6.12, 6.20) [CR5b] Buffered Solutions (SP 2.3, 4.2, 6.4; LO 1.4, 6.18, 6.20) [CR5b] Chapter 16: Spontaneity, Entropy, and Free Energy Read and take notes: Pages 749-779 Key Terms: Page 780 For Review: 780-782 Problems: 17, 21, 24, 28, 31, 32, 35, 37, 39, 41, 43, 46, 48, 51, 53, 55, 58, 62, 65 Labs: Complexometric Titration of Calcium in Milk (SP 4.2, 5.1, 6.4; LO 1.19) [CR5b] & [CR6] Chapter 4.9-4.1 and 17: Oxidaton-Reduction and Electrochemistry Read and take notes: Pages 154-168 and 791-829 Key Terms: Page 169 and 826-827 For Review: Page 170 (9-10) and 826-829 Problems: (Chapter 17 only) 25, 27, 29, 31, 35, 37, 39, 44, 49, 51, 54, 55, 57, 61, 66, 79-82, 88, 92, 94, 116 Labs: Vitamin C in Fruit Juices by Redox Titration (SP 3.1, 3.2, 3.3, 4.2, 4.3, 4.4, 5.1; LO 3.3) [CR5b] & [CR6] Corrosion (SP 3.1, 3.2, 3.3, 4.2, 4.3, 4.4, 5.1; LO 3.3) [CR5b] & [CR6] Activity: Voltaic Cell Lab Simulation Chapter 10: Liquids and Solids Read and take notes: Pages 425-471 Key Terms: Page 472 For Review: Page 472-474 Problems: 35, 36, 37, 39, 42, 79-83, 84-87, 89, 91, 92, 104 Labs: Vapor Pressure and Enthalpy of Vaporization of Water (SP 6.4, 7.1; LO 2.3) [CR5b] & [CR6] Chapter 11: Properties of Solutions Read and take notes: Pages 485-516 Key Terms: Pages 516-517 For Review: Pages 516-518 Problems: 27, 29, 31, 33, 36, 40, 43, 47-58, 59, 61, 63, 65, 67, 69 Lab: Freezing Point Depression (SP 1.1, 1.2, 6.4; LO 2.8) [CR5b] & [CR6] Chapter 7: Atomic Structure and Periodicity Read and take notes: Pages 275-318 Key Terms: Page 318-319 For Review: 318-320 Problems: 37, 43, 45, 47, 49, 51, 53, 55, 57, 60-64, 67, 68, 70, 73, 77, 79, 82, 83, 85, 87, 89, 91, 97, 126 Labs: Guided Inquiry: Molecular Spectroscopy (SP 4.1; LO 1.15) [CR5b] & [CR6] Beer’s Law (SP 4.2, 5.1; LO 3.4) [CR5b] & [CR6] 8 Activity: LO 1.10: Justify with evidence the arrangement of the periodic table and apply periodic properties to chemical reactivity. Students are given several elements pairing them by families or by period and are asked to rationalize the change in electronegativity of each group based on the electronic structure of the atom [CR3a] Chapter 8: Bonding: General Concepts Read: Pages 329-379 Key Terms: 380 For Review: 380-381 Problems: 19, 21, 26, 29, 34, 35, 36, 41-45, 46, 47-50, 54, 59, 63, 64, 67, 69, 72, 74, 77, 78, 79, 81, 83, 91, 92, 95, 109, 119 Lab: Guided Inquiry: Types of Chemical Bonds (SP 4.2, 6.4; LO 2.22) [CR5b] & [CR6] Activity: LO 2.21: Use Lewis diagrams and VSEPR to predict the geometry of molecules, identify hybridization, and make predictions about polarity. Students construct models of the arrangement of pairs of electrons around a central atom. They then draw 2D pictures of these arrangements and apply these to predicting the shapes of molecules. [CR3b] Chapter 9: Covalent Bonding: Orbitals Read: Pages 391-415 Key Terms: Page 416 For Review: Pages 416-417 Problems: 23, 24, 27, 28, 30 Lab: Determination of the Formula of a Hydrate (SP 2.1, 4.2, 6.4; LO 3.5) [CR5b] & [CR6] Chapter 19: The Representative Elements: Groups 1A Through 4A Read and take notes: Pages 875-895 Problems: 2, 8, 10, 16, 18, 19, 22, 24, 26, 28, 30, 32, 34, 36, 39, 42, 44, 46, 48, 51, 53, 56, 57, and 62. Chapter 20: The Representative Elements: Groups 5A through 8A Read and take notes: Pages 901-933 Problems: 2, 6, 8, 10, 12, 14, 16, 18, 20, 22, 23, 25, 28, 29, 32, 33, 38, and 46. 9 NAME: __________________________ _________ PERIOD: AP Chemistry Course Description and Safety Procedures Verification I acknowledge that I have read & reviewed the class syllabus and safety procedures with my parent/guardian. ______________________________________________________________________ (Student, Sign and Print Name) Date: ___________________________ Period: __________________________ I acknowledge that I have read & reviewed the class syllabus and safety procedures with my student. ______________________________________________________________________________ (Parent/ Guardian Sign and Print Name) Date: ___________________________ In order to maintain contact with the parents/guardians of the students, please list your telephone number & email address below. Please indicate which method of contact is preferred. Parent /Guardian Phone (Daytime): ______________________________________________ Parent /Guardian Phone (Evening): ______________________________________________ Parent /Guardian Email Address: _________________________________________________ 10