symmetry symmetry LAVAL LAVAL SHINZOX SHINZOX ININI ININI ININI ININI bd pq Dyslexia… bd pq • Symmetry: • From greak (sun) ‘’with" (metron) "measure" • Same etymology as "commensurate" • Until mid-XIX: only mirror symmetry Definitions • Transformation, Group • Évariste Galois 1811, 1832. Symmetry: Property of invariance of an objet under a space transformation Definitions Symmetric: Invariant under at least two transformations Asymmetric: Invariant under one transformation. Dissymetric: Lost of symmetry… Transformation • Bijection which maps a geometric set in itself M f(M)=M’ • Affine transformation maps two points P and P’ such that: f(M) = P’ + O(PM) P P P’ f : positions O : vectors Affine transformation preserves lines, planes, parallelism • Translation: O identity P P P P P P P’ • Homothety: O(PM)=k.PM • Affinité: Homothety in one direction • Isometry: preserves distances P P • Simililarity: preserves ratios P P Translation • Infinite periodic lattices Homothety • Self-similar objects • Infinite fractals Similitude Infinite fractal Logarithmic spiral (r=aebq) q -> q+q’ r -> re-bq’ e-bq’ q’ Isometries f(M) = P’ + O(PM) • Isometry ||O(u)||=||u|| distance-preserving map • Two types of isometry: • Affine isometry: f(M) • Transforms points. • Microscopic properties of crystals (electronic structure) • Helix of pitch P • Translation • Rotations • Reflections (a, Pa /2p) • Linear isometry O(PM) • Transforms vectors (directions) • Macroscopic properties of crystals (response functions) 60° • Rotations • Reflections E ? Linear isometry- 2D ||O(u)|| = ||u|| • In the plane (2D) • Rotations q • Determinant +1 • Eigenvalues eiq, e-iq • Reflections (reflections through an axis) q/2 • Determinant -1 • Eigenvalues -1, 1 Linear isometry - 3D • ||O(u)|| = |l| ||u|| Eigenvalues |l | = 1 • l : 3rd degree equation (real coefficients) ±1, eiq, e-iq (det. = ± 1) • In space (3D) : • det. = 1 • Direct symmetry • det. = -1 • Indirect symmetry 𝟏 𝟎 𝟎 −𝟏 𝟎 𝟎 𝟎 cos 𝜽 sin 𝜽 𝟎 − sin 𝜽 cos 𝜽 Rotations a) Rotation by angle q b) Roto-reflection q Improper rotation c) Inversion (p) d) Roto-inversion (p+q ) c) Reflection (0) 𝟎 cos 𝜽 sin 𝜽 𝟎 − sin 𝜽 cos 𝜽 Rotoreflections q q q Stereographic projection • To represent directions preserves angles on the sphere NN Direction OM M P’ O P P’ M’ P S P, projection of OM : Intersection of SM and equator • Conform transformation (preserves angles locally) but not affine Main symmetry operations • Conventionally • Direct • Rotations (An) • Reflections (M) • Inversion (C) • Rotoinversion (An) • n-fold rotation An (2p/n) • Represented by a polygon of same symmetry. . . . . . A2 vertical A2 horizontal • Indirect • • • • M vertical M horizontal . . . A3 A4 . . . A5 • Symmetry element • Locus of invariant points _ . . . . Rotoreflections (An) Reflection (M) Inversion (C) Rotoinversions (An) . . . ~ _ . . M . . Inversion . . A4 Difficulties… • Some symmetry are not intuitive • Reflection (mirrors) • Rotoinversion ‘’The ambidextrous universe’’ Why do mirrors reverse left and right but not top and bottom Composition of symmetries • Two reflections with angle a = rotation 2a M’M=A M 2a a M’ • Euler construction AN3 AN1 p/N1 Composition of two rotations = rotation AN2AN1=AN3 • No relation between N1, N2 et N3 AN2 p/N2 Point group: definition • The set of symmetries of an object forms a group G • • • • • A and B G, AB G (closure) Associativity (AB)C=A(BC) Identity element E (1-fold rotation) Invertibility A, A-1 No commutativity in general (rotation 3D) 1 2 2 1 • Example: point groupe of a rectangular table (2mm) Mx My A2 * E Mx My A2 E E Mx My A2 Mx Mx E A2 My My My A2 E Mx A2 A2 My Mx E • Multiplicity: number of elements 2mm Composition of rotations Constraints AN1 p/N1 AN3 AN2 p/N2 234 Spherical triangle, angles verifies: 22N (N>2), 233, 234, 235 Dihedral groups Multiaxial groups Curie’s groups Cubic Hexagonal Tetragonal Trigonal Orthorhombic Monoclinic Triclinic ... An 1 2 3 4 6 32 422 622 2 An A2 222 _ Points groups • Sorted by Symmetry degree • Curie‘s limit groups • Chiral, propers An _ 1 _ 2=m _ 3 _ 4 _ 6=3/m • Impropers An/M /m 2/m 4/m 6/m 4mm 6mm • Centrosymmetric An M 2mm 3m m _ An M _ 3m _ _ _ _ 42m (4m2) 62m (6m2) /mm An /MM’ mmm 4/mmm 6/mmm An An’ 23 432 _ m3 _ 43m _ An An’ _ m3m /m/m 23 _ m3 Multiaxial groups 532 432 _ _ __ 43m m3m 53m Tétraèdre Octaèdre Icosaèdre Cube Dodécaèdre Points group: Notations • Hermann-Mauguin (International notation - 1935) • Generators (not minimum) • Symmetry directions • Reflection ( - ): defined by the normal to the plane Primary Direction: higher-order symmetry Secondary directions : lower-order 4 2 2 mmm Notation réduite 4 mm m Tertiary directions : lowest-order • Schönflies : Cn, Dn, Dnh Les 7 groupes limites de Pierre Curie Cône tournant Vecteur axial + polaire Cylindre tordu Tenseur axial d’ordre 2 Cylindre tournant Vecteur axial (H) Cône Vecteur polaire (E, F) Cylindre Tenseur polaire d’ordre 2 (susceptibilité) Sphère tournante Scalaire axial (chiralité) Sphère Scalaire polaire (pression, masse) 2 /m m /mm /m /m