Training Session on Energy Equipment Boilers & Thermic Fluid Heaters Presentation from the “Energy Efficiency Guide for Industry in Asia” www.energyefficiencyasia.org 1 © UNEP 2006 Training Agenda: Boiler Introduction Type of boilers Assessment of a boiler Energy efficiency opportunities 2 © UNEP 2006 Introduction What is a Boiler? • Vessel that heats water to become hot water or steam • At atmospheric pressure water volume increases 1,600 times • Hot water or steam used to transfer heat to a process 3 © UNEP 2006 Introduction STEAM TO PROCESS EXHAUST GAS STACK VENT DEAERATOR PUMPS ECONOMIZER VENT BOILER BURNER BLOW DOWN SEPARATOR WATER SOURCE FUEL BRINE CHEMICAL FEED SOFTENERS Figure: Schematic overview of a boiler room 4 © UNEP 2006 Training Agenda: Boiler Introduction Type of boilers Assessment of a boiler Energy efficiency opportunities 5 © UNEP 2006 Types of Boilers What Type of Boilers Are There? 1. Fire Tube Boiler 2. Water Tube Boiler 3. Packaged Boiler 4. Fluidized Bed (FBC) Boiler 5. Stoker Fired Boiler 6. Pulverized Fuel Boiler 7. Waste Heat Boiler 8. Thermic Fluid Heater (not a boiler!) 6 © UNEP 2006 Type of Boilers 1. Fire Tube Boiler (Light Rail Transit Association) • Relatively small steam capacities (12,000 kg/hour) • Low to medium steam pressures (18 kg/cm2) • Operates with oil, gas or solid fuels 7 © UNEP 2006 Type of Boilers 2. Water Tube Boiler (Your Dictionary.com) • Used for high steam demand and pressure requirements • Capacity range of 4,500 – 120,000 kg/hour • Combustion efficiency enhanced by induced draft provisions • Lower tolerance for water quality and needs water treatment plant 8 © UNEP 2006 Type of Boilers 3. Packaged Boiler To Chimney Oil Burner (BIB Cochran, 2003) • Comes in complete package • Features • High heat transfer • Faster evaporation • Good convective heat transfer • Good combustion efficiency • High thermal efficiency • Classified based on number of passes 9 © UNEP 2006 Type of Boilers 4. Fluidized Bed Combustion (FBC) Boiler • Particles (e.g. sand) are suspended in high velocity air stream: bubbling fluidized bed • Combustion at 840° – 950° C • Capacity range 0,5 T/hr to 100 T/hr • Fuels: coal, washery rejects, rice husk, bagasse and agricultural wastes • Benefits: compactness, fuel flexibility, higher combustion efficiency, reduced SOx & NOx 10 © UNEP 2006 Type of Boilers 4a. Atmospheric Fluidized Bed Combustion (AFBC) Boiler • Most common FBC boiler that uses preheated atmospheric air as fluidization and combustion air 4b. Pressurized Fluidized Bed Combustion (PFBC) Boiler • Compressor supplies the forced draft and combustor is a pressure vessel • Used for cogeneration or combined cycle power generation 11 © UNEP 2006 Type of Boilers 4c. Atmospheric Circulating Fluidized Bed Combustion (CFBC) Boiler • Solids lifted from bed, rise, return to bed • Steam generation in convection section • Benefits: more economical, better space utilization and efficient combustion (Thermax Babcock & Wilcox Ltd, 2001) 12 © UNEP 2006 Type of Boilers 5. Stoke Fired Boilers a) Spreader stokers • Coal is first burnt in suspension then in coal bed • Flexibility to meet load fluctuations • Favored in many industrial applications 13 © UNEP 2006 Type of Boilers 5. Stoke Fired Boilers b) Chain-grate or traveling-grate stoker • Coal is burnt on moving steel grate • Coal gate controls coal feeding rate • Uniform coal size for complete combustion (University of Missouri, 2004) 14 © UNEP 2006 Type of Boilers 6. Pulverized Fuel Boiler • Pulverized coal powder blown with combustion air into boiler through burner nozzles • Combustion temperature at 1300 1700 °C • Benefits: varying coal quality coal, quick response to load changes and high preheat air temperatures Tangential firing 15 © UNEP 2006 Type of Boilers 7. Waste Heat Boiler • Used when waste heat available at medium/high temp • Auxiliary fuel burners used if steam demand is more than the waste heat can generate Agriculture and Agri-Food Canada, 2001 • Used in heat recovery from exhaust gases from gas turbines and diesel engines 16 © UNEP 2006 Type of Boilers 8. Thermic Fluid Heater • Wide application for indirect process heating • Thermic fluid (petroleum-based) is heat transfer medium • Benefits: • Closed cycle = minimal losses • Non-pressurized system operation at 250 °C • Automatic controls = operational flexibility • Good thermal efficiencies 17 © UNEP 2006 Type of Boilers 8. Thermic Fluid Heater 3. Heat transfer through heat exchanged User equipment 2. Circulated to user equipment 4. Fluid returned to heater Control panel Insulated outer wall 1. Thermic fluid heated in the heater Blower motor unit Fuel oil filter Exhaust (Energy Machine India) 18 © UNEP 2006 Training Agenda: Boiler Introduction Type of boilers Assessment of a boiler Energy efficiency opportunities 19 © UNEP 2006 Assessment of a boiler 1. Boiler 2. Boiler blow down 3. Boiler feed water treatment 20 © UNEP 2006 Assessment of a Boiler 1. Boiler performance • Causes of poor boiler performance -Poor combustion -Heat transfer surface fouling -Poor operation and maintenance -Deteriorating fuel and water quality • Heat balance: identify heat losses • Boiler efficiency: determine deviation from best efficiency 21 © UNEP 2006 Assessment of a Boiler Heat Balance An energy flow diagram describes geographically how energy is transformed from fuel into useful energy, heat and losses Stochiometric Excess Air Un burnt Stack Gas FUEL INPUT STEAM OUTPUT Convection & Radiation Blow Down Ash and Un-burnt parts of Fuel in Ash 22 © UNEP 2006 Assessment of a Boiler Heat Balance Balancing total energy entering a boiler against the energy that leaves the boiler in different forms 12.7 % 8.1 % 1.7 % 100.0 % BOILER Fuel 0.3 % 2.4 % 1.0 % 73.8 % Heat loss due to dry flue gas Heat loss due to steam in fuel gas Heat loss due to moisture in fuel Heat loss due to moisture in air Heat loss due to unburnts in residue Heat loss due to radiation & other unaccounted loss Heat in Steam 23 © UNEP 2006 Assessment of a Boiler Heat Balance Goal: improve energy efficiency by reducing avoidable losses Avoidable losses include: - Stack gas losses (excess air, stack gas temperature) - Losses by unburnt fuel - Blow down losses - Condensate losses - Convection and radiation 24 © UNEP 2006 Assessment of a Boiler Boiler Efficiency Thermal efficiency: % of (heat) energy input that is effectively useful in the generated steam BOILER EFFICENCY CALCULATION DIRECT METHOD: 2) INDIRECT METHOD: The energy gain of the working fluid (water and steam) is compared with the energy content of the boiler fuel. The efficiency is the different between losses and energy input 1) 25 © UNEP 2006 Assessment of a Boiler Boiler Efficiency: Direct Method Boiler efficiency () = Heat Input x 100 Q x (hg – hf) x 100 = Heat Output Q x GCV hg -the enthalpy of saturated steam in kcal/kg of steam hf -the enthalpy of feed water in kcal/kg of water Parameters to be monitored: - Quantity of steam generated per hour (Q) in kg/hr - Quantity of fuel used per hour (q) in kg/hr - The working pressure (in kg/cm2(g)) and superheat temperature (oC), if any - The temperature of feed water (oC) - Type of fuel and gross calorific value of the fuel (GCV) in 26 kcal/kg of fuel © UNEP 2006 Assessment of a Boiler Boiler Efficiency: Direct Method Advantages • • • • Quick evaluation Few parameters for computation Few monitoring instruments Easy to compare evaporation ratios with benchmark figures Disadvantages • • No explanation of low efficiency Various losses not calculated 27 © UNEP 2006 Assessment of a Boiler Boiler Efficiency: Indirect Method Efficiency of boiler () = 100 – (i+ii+iii+iv+v+vi+vii) Principle losses: i) Dry flue gas ii) Evaporation of water formed due to H2 in fuel iii) Evaporation of moisture in fuel iv) Moisture present in combustion air v) Unburnt fuel in fly ash vi) Unburnt fuel in bottom ash 28 vii) Radiation and other unaccounted losses © UNEP 2006 Assessment of a Boiler Boiler Efficiency: Indirect Method Required calculation data • Ultimate analysis of fuel (H2, O2, S, C, moisture content, ash content) • % oxygen or CO2 in the flue gas • Fuel gas temperature in ◦C (Tf) • Ambient temperature in ◦C (Ta) and humidity of air in kg/kg of dry air • GCV of fuel in kcal/kg • % combustible in ash (in case of solid fuels) • GCV of ash in kcal/kg (in case of solid fuels) 29 © UNEP 2006 Assessment of a Boiler Boiler Efficiency: Indirect Method Advantages • • Complete mass and energy balance for each individual stream Makes it easier to identify options to improve boiler efficiency Disadvantages • • Time consuming Requires lab facilities for analysis 30 © UNEP 2006 Assessment of a Boiler 2. Boiler Blow Down • Controls ‘total dissolved solids’ (TDS) in the water that is boiled • Blows off water and replaces it with feed water • Conductivity measured as indication of TDS levels • Calculation of quantity blow down required: Blow down (%) = Feed water TDS x % Make up water Maximum Permissible TDS in Boiler water 31 © UNEP 2006 Assessment of a Boiler Boiler Blow Down Two types of blow down • Intermittent • Manually operated valve reduces TDS • Large short-term increases in feed water • Substantial heat loss • Continuous • Ensures constant TDS and steam purity • Heat lost can be recovered • Common in high-pressure boilers 32 © UNEP 2006 Assessment of a Boiler Boiler Blow Down Benefits • Lower pretreatment costs • Less make-up water consumption • Reduced maintenance downtime • Increased boiler life • Lower consumption of treatment chemicals 33 © UNEP 2006 Assessment of a Boiler 3. Boiler Feed Water Treatment • Quality of steam depend on water treatment to control • Steam purity • Deposits • Corrosion • Efficient heat transfer only if boiler water is free from deposit-forming solids 34 © UNEP 2006 Assessment of a Boiler Boiler Feed Water Treatment Deposit control • To avoid efficiency losses and reduced heat transfer • Hardness salts of calcium and magnesium • Alkaline hardness: removed by boiling • Non-alkaline: difficult to remove • Silica forms hard silica scales 35 © UNEP 2006 Assessment of a Boiler Boiler Feed Water Treatment Internal water treatment • Chemicals added to boiler to prevent scale • Different chemicals for different water types • Conditions: • Feed water is low in hardness salts • Low pressure, high TDS content is tolerated • Small water quantities treated • Internal treatment alone not recommended 36 © UNEP 2006 Assessment of a Boiler Boiler Feed Water Treatment External water treatment: • Removal of suspended/dissolved solids and dissolved gases • Pre-treatment: sedimentation and settling • First treatment stage: removal of salts • Processes a) Ion exchange b) Demineralization c) De-aeration d) Reverse osmoses 37 © UNEP 2006 Assessment of a Boiler External Water Treatment a) Ion-exchange process (softener plant) • Water passes through bed of natural zeolite of synthetic resin to remove hardness • Base exchange: calcium (Ca) and magnesium (Mg) replaced with sodium (Na) ions • Does not reduce TDS, blow down quantity and alkalinity b) Demineralization • Complete removal of salts • Cations in raw water replaced with hydrogen ions 38 © UNEP 2006 Assessment of a Boiler External Water Treatment c) De-aeration • Dissolved corrosive gases (O2, CO2) expelled by preheating the feed water • Two types: • Mechanical de-aeration: used prior to addition of chemical oxygen scavangers • Chemical de-aeration: removes trace oxygen 39 © UNEP 2006 Assessment of a Boiler External Water Treatment Mechanical de-aeration Vent Spray Nozzles Boiler Feed Water Stea m Scrubber Section (Trays) • O2 and CO2 removed by heating feed water • Economical treatment process • Vacuum type can reduce O2 to 0.02 mg/l Storage Section De-aerated Boiler Feed Water ( National Productivity Council) • Pressure type can reduce O2 to 0.005 mg/l 40 © UNEP 2006 Assessment of a Boiler External Water Treatment Chemical de-aeration • Removal of trace oxygen with scavenger • Sodium sulphite: • Reacts with oxygen: sodium sulphate • Increases TDS: increased blow down • Hydrazine • Reacts with oxygen: nitrogen + water • Does not increase TDS: used in high pressure boilers 41 © UNEP 2006 Assessment of a Boiler External Water Treatment d) Reverse osmosis • Osmosis • Solutions of differing concentrations • Separated by a semi-permeable membrane • Water moves to the higher concentration • Reversed osmosis • Higher concentrated liquid pressurized • Water moves in reversed direction 42 © UNEP 2006 Assessment of a Boiler External water treatment d) Reverse osmosis Pressure Fresh Water Feed Water More Concentrated Solution Concentrate Flow Water Flow Semi Permeable Membrane 43 © UNEP 2006 Training Agenda: Boiler Introduction Type of boilers Assessment of a boiler Energy efficiency opportunities 44 © UNEP 2006 Energy Efficiency Opportunities 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Stack temperature control Feed water preheating using economizers Combustion air pre-heating Incomplete combustion minimization Excess air control Avoid radiation and convection heat loss Automatic blow down control Reduction of scaling and soot losses Reduction of boiler steam pressure 45 Variable speed control © UNEP 2006 Energy Efficiency Opportunities 1. Stack Temperature Control • Keep as low as possible • If >200°C then recover waste heat 2. Feed Water Preheating Economizers • Potential to recover heat from 200 – 300 oC flue gases leaving a modern 3-pass shell boiler 3. Combustion Air Preheating • If combustion air raised by 20°C = 1% improve thermal efficiency 46 © UNEP 2006 Energy Efficiency Opportunities 4. Minimize Incomplete Combustion • Symptoms: • Smoke, high CO levels in exit flue gas • Causes: • Air shortage, fuel surplus, poor fuel distribution • Poor mixing of fuel and air • Oil-fired boiler: • Improper viscosity, worn tops, cabonization on dips, deterioration of diffusers or spinner plates • Coal-fired boiler: non-uniform coal size 47 © UNEP 2006 Energy Efficiency Opportunities 5. Excess Air Control • Excess air required for complete combustion • Optimum excess air levels varies • 1% excess air reduction = 0.6% efficiency rise • Portable or continuous oxygen analyzers Fuel Kg air req./kg fuel %CO2 in flue gas in practice Solid Fuels Bagasse Coal (bituminous) Lignite Paddy Husk Wood 3.3 10.7 8.5 4.5 5.7 10-12 10-13 9 -13 14-15 11.13 Liquid Fuels Furnace Oil LSHS 13.8 14.1 9-14 9-14 48 © UNEP 2006 Energy Efficiency Opportunities 6. Radiation and Convection Heat Loss Minimization • Fixed heat loss from boiler shell, regardless of boiler output • Repairing insulation can reduce loss 7. Automatic Blow Down Control • Sense and respond to boiler water conductivity and pH 49 © UNEP 2006 Energy Efficiency Opportunities 8. Scaling and Soot Loss Reduction • Every 22oC increase in stack temperature = 1% efficiency loss • 3 mm of soot = 2.5% fuel increase 9. Reduced Boiler Steam Pressure • Lower steam pressure = lower saturated steam temperature = lower flue gas temperature • Steam generation pressure dictated by process 50 © UNEP 2006 Energy Efficiency Opportunities 10. Variable Speed Control for Fans, Blowers and Pumps • Suited for fans, blowers, pumps • Should be considered if boiler loads are variable 11. Control Boiler Loading • Maximum boiler efficiency: 65-85% of rated load • Significant efficiency loss: < 25% of rated load 51 © UNEP 2006 Energy Efficiency Opportunities 12. Proper Boiler Scheduling • Optimum efficiency: 65-85% of full load • Few boilers at high loads is more efficient than large number at low loads 13. Boiler Replacement Financially attractive if existing boiler is • Old and inefficient • Not capable of firing cheaper substitution fuel • Over or under-sized for present requirements • Not designed for ideal loading conditions 52 © UNEP 2006 Training Session on Energy Equipment Boilers & Thermic Fluid Heaters THANK YOU FOR YOUR ATTENTION 53 © UNEP GERIAP Disclaimer and References • This PowerPoint training session was prepared as part of the project “Greenhouse Gas Emission Reduction from Industry in Asia and the Pacific” (GERIAP). While reasonable efforts have been made to ensure that the contents of this publication are factually correct and properly referenced, UNEP does not accept responsibility for the accuracy or completeness of the contents, and shall not be liable for any loss or damage that may be occasioned directly or indirectly through the use of, or reliance on, the contents of this publication. © UNEP, 2006. • The GERIAP project was funded by the Swedish International Development Cooperation Agency (Sida) • Full references are included in the textbook chapter that is available on www.energyefficiencyasia.org 54 © UNEP 2006