Ch 3 Soil Organic Matter continued Pools of Organic Matter (OM) in Soils • ACTIVE (labile, ever-changing, mutable) – Plant litter – Light fraction – Microbial biomass – Water soluble organics • STABLE (Humus) recalcitrant, long term, products of weathering of labile OM – Humic acid – Fulvic acid – Humin What Does Organic Matter Do? http://www.soils.umn.edu/academics/classes/soil5611/content/OrganicMatter/ : soilslab.cfr.washington.edu/.../DOMSorption.html http://www.chm.bris.ac.uk/ogu/images/carboncycle.jpg http://www.chem1.com/CQ/Carbonate.png 0.25 to 1 Mg C/ha/y sequestered in soils as carbonate Losses due to cultivation are 60-80 Mg C/ha/y http://www.climatescience.gov/Library/stratplan2003/final/graphics/images/SciStratFig 7-5.jpg www.farmscape.cse.csiro.au/.../mod1/fig1-05.gif The Changing Forms of Soil Organic Matter Additions. When roots and leaves die, they become part of the soil organic matter. Transformations. Soil organisms continually change organic compounds from one form to another. They consume plant residue and other organic matter, and then create by-products, wastes, and cell tissue. Microbes feed plants. Some of the wastes released by soil organisms are nutrients that can be used by plants. Organisms release other compounds that affect plant growth. Stabilization of organic matter. Eventually, soil organic compounds become stabilized and resistant to further changes. http://www.extension.umn.edu/distribution/cropsystems/components/7402_02.html http://www.ar.wroc.pl/~weber/kwasy2.htm Composition of SOM • SOM = humic + nonhumic substances • Mostly C, H, O ~ 90% on a dry weight basis • Remaining 8-10% is mostly N, S and Cations • C/N ratio ~ 10 Proposed structure of humic acid http://www.rsc.org/ej/gt/2000/b001869o/ Computer generated model of humic acid http://www.rsc.org/ej/gt/2000/b001869o/b001869o-f3.gif