Which salt will add the least warmth to melt an ice cube? Gözde Kaçmaz & Habibe Özcan Pieter Nieuwland College, The Netherlands June 2011 Summary Our research question is: which salt will add the least warmth to melt an ice cube? To answer the research question we have used the following solutions of: sodium chloride (NaCl), mono soda carbonate (Na2CO3∙H2O), ammonium chloride (NH4Cl) and sand (SiO2). We have chosen for these materials because all four are used to melt ice. We conducted the survey as following: first weight 10 grams (10 gram coated the surface.) of salt in a measuring cup filled with 100 grams of water(100 gram, because it’s a easy number to calculate with)Then we measured the temperature of the solution with and without the ice cube. With those results and data we could calculate the heat by using the formula: Q = c * m * dT. Introduction The aim of our study is to find out the amount of heat you will need to melt an ice cube. In this research we used the following salts: sodium chloride (NaCl), mono soda carbonate (Na2CO3∙H2O), ammonium chloride (NH4Cl) and sand (SiO2). Our hypothesis is that we have to add less NaCl because NaCl ensures that the melting of ice will decrease. NaCl on the ice cube provides pickle. And pickle provides for a lower melting point, which means the ice cube will melt faster. Preparation To conduct our research we have used the following materials: • 20 grams soda chloride • 20 grams soda carbonate • 20 grams ammonium chloride • 20 grams sand • Thermometer • Measuring cups • 10 ice cubes We have used 20 grams of each substance, because we carried out the survey twice. We added 10 grams of every salt because 10 grams coated the surface. Procedure First of all we weighed 100 grams water and 10 grams of each salt. Then we put those two together as one solution. We measured the temperature of the ice cub until it had a temperature of 0 degrees Celsius( so that the temperature of the ice would not affect our study) We have done it the following way: we placed the ice cube into a measuring glass and then we kept the thermometer against the ice cube. After that we putted the ice cube in the water with salt and waited until it had melted. We also measured the temperature of the water before and after the ice has melted. Results To calculate the heat that has been added from the endothermic reaction we used the following formula: Q = c * m * dT. Q: the heat, what was added during the endothermic reaction (kJ/kg x 10^3) c: the specific heat of the solutions (J / kg / K). We have read out the specific heat from tables and graphs (see bibliography for which they are) m: the mass in the formula is the mass of the solution (kg) dT: the temperature difference between the temperature of the water before and after the ice cubes had been molten. The results in the following table are in Kelvin: Solution H2O NaCl Na2CO3 NH4Cl SiO2 First measurement T start 293,2 290,2 290,2 289,2 293,2 Solution Specific heat (J/kg/K)103) H2O 4,18 NaCl 4,15 Na2CO3 4,03 NH4Cl 4,52 SiO2 5,01 Mass ( kg) 0,10 0,11 0,11 0,11 0,11 Second measurement T end 286,2 284,2 285,2 284,2 287,2 Average dT (K) 8,5 5,5 4,5 4,5 6 dT 7K 6K 5K 5K 6K T start 294,2 293,2 288,2 291,2 291,2 Calculation of the heat 4,18*0,10*8,5 4,15*0,11*5,5 4,03*0,11*4,5 4,52*0,11*4,5 5,01*0,11*6 T end 284,2 288,2 284,2 287,2 285,2 Average dT dT 10 K 5K 4K 4K 6K 8,5 5,5 4,5 4,5 6 Q ( kJ/kg)103 3,56 2,51 1,99 2,23 3,31 Conclusion From our results we conclude the following: you must add the least energy to soda ash. The energy in the form of heat was 1,99 kJ x 10^3. Which was not in settlement with our hypothesis. Evaluation As with any experiment, we also had to deal with measurement uncertainties. For example, we could use some better equipment to measure data. Especially for the reading of the temperature. This was very important because a thermometer is not that precise. What went well afterwards, was that we conducted all the experiments twice just to reduce the measurement uncertainty. A suggestion for the next time is to exclude to use demineralized water or tap water, which mostly could have had an influence on the reaction. You can use distilled water because it is made differently than tap water, and perhaps will it have a different effect than tap water. And whether the combination of salts can provide a better solution. We can reduce the amount of salt, because salt that is sprinkled in the winter never quite cover the surface of the road. Finally, we don’t know how reliable our data from the Internet is. Bibliography http://en.wikipedia.org/wiki/Nacl http://en.wikipedia.org/wiki/Salmiak http://en.wikipedia.org/wiki/Sio2 http://en.wikipedia.org/wiki/Na2co3 Binas http://www.genchem.com/pdf/SodaA shTech.pdf http://www.engineeringtoolbox.com/ water-thermal-propertiesd_162.html http://www.endmemo.com/convert/s pecific%20heat%20capacity.php http://www.jiskha.com/