Air Pollution Control Engineering Prof. Jiakuan Yang Huazhong University of Science and Technology Questions for the Last Lecture 1. Please give examples of primary particulates and secondary particulates. 2. For particles too large or too small, how to modify the Stokes’ law. Answer Primary particles are found in the atmosphere in the form in which they were emitted. Fly ash Coal dust ZnO Fume Cement dust Answer (3) secondary particles Secondary particles are formed in the atmosphere from gaseous pollutants which are called as the precursors. Secondary particles precursors Tobacco smoke CxHy sulfuric Mist SO2 Black smoke of car CxHy Particles too large for Stokes’ Law 4 D part g Vt 3 Cd fluid when Rp <0.3, When 0.3≤ Rp ≤1000 1 2 24 Cd Rp 24 0.7 Cd 1 0.14R p Rp Particles too Small for Stokes’ Law gD part 2 V 18 gD partC 2 V 1 A D 18 Lecture 9 Control of Primary Particulates Most of fine particles in the atmosphere are secondary particles, <2.5 μm. They are difficult to be collected by a control device. The best way to control secondary particles is process change. Lecture 9 Control of Primary Particulates The control of primary particles is a major part of air pollution control engineering. For the particulates in size range 1 µm ~ 70 µm. The control device can be designed on the basis of Stokes’ law. Lecture 9-1 The nature of Particulate Pollutants Ⅰ Types of Particles collection devices Ⅱ Gravity Settlers Ⅲ Centrifugal Separators Ⅳ Electrostatic Precipitators (ESP) Ⅴ Summary Ⅰ Types of Particles collection devices gravity settlers (重力沉降式室) wall collection device (壁式收集设备) cyclone separator (旋风除尘器) electrostatic precipitators (静电除尘器) Ⅰ Types of Particles collection devices surface filter (表面式过滤器) dividing collection device (分离式收集设备) depth filter (纵深式过滤器) scrubber (气体洗涤器) The general idea of wall collection device Driving the particles to wall ① Particles adhere to each other to ② agglomerate ③ Removed from the wall 2.Gravity settlers (1) Schematic of typical gravity settler chamber Inlet duct outlet duct W H L Cross-sectional area (WH) is much larger than that of inlet duct, or that of outlet duct. Some baffles: inlet baffles and out baffles reducing the velocity of gas in gravity setter. (2) Block flow model Assumptions ① Average horizontal gas velocity in chamber Vavg Q WH ② The horizontal velocity of the gas in the chamber everywhere = Vavg (2) Block flow model ③ The horizontal component of the velocity of the particles =Vavg ④ The vertical component of the velocity is equal to Vt ⑤ If a particle settles to the floor, it stays there and is not re-entrained. Separation of the particles from the dirty air (2) Block flow model collection efficiency ① The time the gas will take to pass through the chamber in the flow direction. L t Vavg ② During that time, the particle fall down a distance by gravity. L Vertical Setting Distance(VSH) = t Vt = Vt Vavg (2) Block flow model collection efficiency L Vertical Setting Distance(VSH) = t Vt = Vt Vavg If VSD<H, the particles will pass through the chamber and will not be captured by the bottom wall of chamber. If VSD>H, the particles will be captured on the bottom wall of chamber. (2) Block flow model collection efficiency ③ Efficiency η= Fractional captured = LVt HVavg Substituting Stokes’ law equation in the above equation. LgD part 2 HVavg 18 η D2 (3) Mixed flow model Assumptions, Page 252 Totally mixing in the z direction but not in the x direction. mixed LgD 2 part 1 exp HV 18 avg mixed 1 exp( blowflow) Collection efficiency, % Mixed flow model and Block flow model block mixed Diameter of the particles, μ Shortcoming of Gravity settlers This type of device would be useful for collecting particles with diameters of perhaps 100μm, but not for smaller particles of air pollution interest. <100μm LgD 2 part HVavg 18 L Long and expensive H Subdividing the chamber with horizontal plates, difficult to clean up Vavg Cross sectional area, cost g Substituting some other force for gravity. Ⅲ Centrifugal Separators (1) centrifugal force and terminal setting velocity (终极沉降速度). Fd’ Vc Fd Centrifugal force Vt Vt gravity Ⅲ Centrifugal Separators gravity mg 6 part D g Fd 3DVt 3 Vt Centrifugal force gD part 2 18 V 3V m part D Fd 3DVt r 6 r 2 c 2 c Vc D part 2 Vt 2 18r Ⅲ Centrifugal Separators Page 255, Example 9.2 Centrifugal force is two orders of magnetic larger than the gravity force. Centrifugal force is more powerful than the gravity force, so centrifugal particle separators are higher efficiency than gravity settlers. In the cyclone, gravity can be ignored. Questions for the Last Lecture What is the general idea of wall collection device? The general idea of wall collection device 1. Driving the particles to wall. 2. Particles adhere to each other to agglomerate. 3. Particles are removed from the wall. Ⅲ Centrifugal Separators (2) Schematic of a cyclone separator D0 S De Wi H ① H1 , D 0 vertical cylindrical body ②H2, Dd conical bottom H1 ③Wi, H: rectangular inlet ④S, De: H2 Dd cylindrical outlet Ⅲ Centrifugal Separators (3) gas flow and efficiency Because rectangular inlet is arranged tangentially to the circular body of cyclone, so that the entering gas flows around the circumference of the cylindrical body, not radically inward. Ⅲ Centrifugal Separators (3) gas flow and efficiency ① Outer helix around the outer part of the cylindrical body with downward component. Contributing to collection ② Inner helix is at the center of cylindrical body, flowing upward to the gas outlet. Particles are not collected. Outer helix is equivalent to the gravity settler. 旋风除尘器 Ⅲ Centrifugal Separators (3) gas flow and efficiency L=NπD0 L Vt Centr. force Wi W H Vc Fd Fd H Vt gravity Vavg Ⅲ Centrifugal Separators (3) gas flow and efficiency L = NπD0 L — the length of the flow path N — the number of turns that the gas makes the traversing the outer helix of the cyclone D0 — the outer diameter of the cyclone Ⅲ Centrifugal Separators (3) gas flow and efficiency cyclone separator LVt HVavg LVt WiVc ND0 V D part 2 c 2 WiVc 18r NVc D part 2 Gravity settlers 9Wi LgD part 2 HVavg 18 Ⅲ Centrifugal Separators (4) Cut diameter Cut diameter is the diameter of a particle for which the efficiency curve has the value of 0.50. 1/ 2 Dcut 9Wi 2NV c part Ⅲ Centrifugal Separators (4) Cut diameter Efficiency can be derived from experimental data , expressed as the following Empirical Data-fitting Equation. D / Dcut 2 1 D / Dcut 2 A Multiclone Page 261, Fig. 9.5 (5) Pressure drop of cyclone Pressure drop Pin Pout K ρg V /2 2 i ρg — the gas density. Vi — the velocity at the inlet to the cyclone. K — constant, K=8 for most cyclone separators. (6) Location of cyclone Before the blower, air will be sucked in cyclone, degrading the overall collecting efficiency. After the blower, bearing and collecting on the blower’s blades. Ⅳ Electrostatic Precipitators (ESP) (1)The basic idea The basic idea of all ESPs is to give the Particles an electrostatic charge and then put them in an electrostatic field that drives them to a collecting wall. ESP includes two steps: charging the particles. Collecting the particles. (2) The charge on the particles by field charging 2 q 3 0 D E0 2 ε — dielectric constant of the particle,1 for vacuum, 4-8 for typical solid particles. ε0 — the permittivity of free space, 8.85×10-12 C/(V·m) D — particle diameter. E0 — the local field strength. (3) Electrostatic force F qE p Ep — the local electric field strength causing the force. Using an average E E = E0=Ep (3) Electrostatic force 2 F 3 0 D E0 E p 2 2 2 3 0 D E 2 (4) drift velocity (静电拖曳速度) Fd 3DVt 2 2 electrostatic force 3 0 D E 2 D 0 E 2 Vt 2 电除尘器外观图 宽间距卧式电除尘器 HHD型宽间距卧式电除尘器 电除尘器 Dust-collection plate High –voltage wire for corona discharge 集尘板 L 2H h Dirty gas 烟气 Corona discharge along the length of wire 电晕线长度 Clean gas Dust removed from plates to hoppers 清洁气体 Collected dust on plate 收集在集尘板上的尘 电除尘器 电除尘器 烟道气 风板的 距离 烟道气 清洁气体 详图:严密的放电极 收集的粉尘 (5) Diagrammatic sketch of a simplified ESP Page 267 Fig. 9.7 With two plates, four wires, and one flow channel. H H From A direction Vavg A ES force Vt Highvoltage wires for corona discharge Dustcollection plates Fd h L (5) Diagrammatic sketch of a simplified ESP ESP is two gravity settlers back to back. LVt L Lh Vavg H Vavg H Vavg Hh Area of plate A Lh Q HhVavg Volumetric flow A Q (5) Diagrammatic sketch of a simplified ESP A For block flow Q 1 exp( A Q ) For mixed flow Page 269 Fig. 9.8 Modern ESP Summary Driving forces Terminal settling velocity Efficiency Cut diameter Centr. force figure Vt ES force ω Vt gravity Gravity Driving force 6 Terminal settling velocity efficiency Vt Cut diameter part D g 3 gD 2 part 18 LgD 2 part HVavg 18 50 μ For small particles ineffective Suitable for particles’ size >100 μ Centrifugal force ES force 2 2 qE 3 0 D E 2 2 2 2 D E 0 Vc D part 2 Vt 18r Vc2 m r NVc D 2 part 9Wi 5μ effective 15~100 μ A Q 0.5 μ More effective 5~15 μ This Lecture and the Next Lecture This Lecture: Chapter 9 Page 249~280 The Next Lecture: Chapter 9 page 280~314 Exerciser Page 315 9.7 9.10 DISCUSSION Topics about Air pollution: Introducing yourself Interesting news or information about air pollution your having read or heard Your opinions on this Air Pollution course Your suggestions for Chinese Air Pollution Other familiar issues about Air Pollution