The Periodic Table of Elements 1 1 18 1 H 2 13 14 15 16 17 1.008 2 3 6 4 5 6 7 8 9 10 Be B C N O F Ne 6.941 9.012 11 12 Na Mg 24.305 3 4 5 6 7 8 9 10 11 12 10.811 12.001 14.007 15.999 18.998 20.180 13 14 15 16 17 18 Al 26.982 Si 28.086 P 30.974 S 32.066 Cl 35.453 Ar 39.948 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc 44.956 V Cr Mn 40.078 Ti Fe Co Ni Cu Zn Ga Ge As Se Br Kr 47.87 50.942 51.996 54.938 37 38 39 40 41 42 43 Rb Sr Y Zr Nb Mo 85.468 87.62 92.906 95.94 Tc 55 88.906 91.224 56 71 72 73 Cs Ba Lu 137.327 174.967 Hf Ta 87 88 103 Fr Ra (223) (226) 132.905 7 4.003 3 39.098 5 He Li 22.990 4 2 Lr (262) 55.845 44 Ru 72.61 74.922 78.96 79.904 83.80 45 46 47 48 49 50 51 52 53 54 Rh Pd Ag Cd In Sn Sb Te I Xe 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 74 75 76 77 78 79 80 81 82 83 84 85 86 Tl Pb Bi Po At Rn 116 Uuh 117 118 Uus Uuo Os 104 105 106 107 Rf Db Actinides 69.723 106.42 Re Lanthanides 65.39 102.906 W (262) 63.546 101.07 183.84 (261) 58.69 (98) 180.95 178.49 58.933 186.207 192.217 195.078 Pt Au Hg 108 109 110 111 Mt 112 Uub 190.23 Sg Bh Hs (266) (264) (269) Ir (268) 196.967 Ds Rg (269) (272) 200.59 (285) 204.383 207.2 208.980 113 114 115 Uut Uuq Uup (284) (289) (288) (209) (292) (210) (222) 57 58 59 60 61 62 63 64 65 66 67 68 69 70 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm 140.116 140.908 164.930 167.26 168.934 Yb 138.906 144.24 Pm 173.04 (145) 150.36 151.964 157.25 158.925 162.50 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No 232.038 231.036 238.029 (257) (258) (259) (227) (237) (244) (243) (247) (247) (251) (252) Periodic Periodic Law Periodic Table • Something periodic occurs at regular or at least generally predictable intervals • Periodic law - physical and chemical properties of the elements are periodic functions of their atomic numbers • Periodic Table of Elements – a table of the elements, arranged by atomic number, that shows the patterns in their properties; based on the periodic law Can you think of anything that is periodic? Element • A pure substance made up of one kind of atom that cannot be broken down into simpler substances by physical or chemical means • 90 occur naturally on earth • 25 were synthesized (made) by scientists http://www.privatehand.com/flash/elements.html Dmitri Mendeleev • In the 1860’s he devised a periodic table where the elements were ordered by their atomic masses • He did this by grouping elements together according to their similarities • Draft of Mendeleev's Periodic Table Image taken from: http://jscms.jrn.columbia.edu/cns/2006-04-18/fido-luxuriantflowinghair/mendeleev/ Mendeleev’s Published Periodic Table of Elements Why do you think there are question marks here? Image taken from: http://www.chemsoc.org/networks/learnnet/periodictable/post16/develop/mendeleev.htm Mendeleev’s Predictions • Although Mendeleev’s Periodic Table of Elements had missing elements or “gaps,” he was able to predict the characteristics of these missing elements because of Periodic Law. “Ekasilicon” Date Predicted Atomic Mass 1871 72 Germanium Date Discovered 1886 Atomic Mass 72.6 Density 5.5 g/cm3 Density 5.47 g/cm3 Bonding Power 4 Bonding Power 4 Color Dark Gray Color Grayish White Notice how Mendeleev’s predictions (orange column) were very accurate when compared to Germanium’s actual characteristics (green column) Henry Moseley • In 1914, his work led to a revision of the periodic table by rearranging the elements by their atomic numbers • He concluded that the number of protons in an atom is its atomic number • Sample X-ray Spectra Image taken from: http://dewey.library.upenn.edu/sceti/smith/ 3 Classes of Elements 1 1 1 H 2 1.008 2 3 3 4 Li Be 6.941 9.012 11 12 Na Mg 22.990 4 6 4 5 6 7 8 9 10 17 2 He 4.003 5 6 7 8 9 10 B C N O F Ne 10.811 3 15 16 11 12 20.180 12.001 14.007 15.999 18.998 13 14 15 16 17 18 Al Si P S Cl Ar 26.982 28.086 30.974 32.066 35.453 39.948 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc 44.956 V Cr Mn 40.078 Ti Fe Co Ni Cu Zn Ga Ge As Se Br Kr 47.87 50.942 51.996 54.938 37 38 39 40 41 42 43 Rb Sr Y Zr Nb Mo 85.468 87.62 92.906 95.94 Tc 88.906 91.224 (98) 55.845 44 Ru 101.07 58.933 58.69 63.546 65.39 69.723 72.61 74.922 78.96 79.904 83.80 45 46 47 48 49 50 51 52 53 54 Rh Pd Ag Cd In Sn Sb Te I Xe 102.906 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba Lu Ta 137.327 174.967 Hf W Re Os 190.23 Ir 192.217 Pt 195.078 Au Hg 200.59 Tl 204.383 Pb 207.2 Bi 208.980 Po At Rn 103 112 Uub 113 114 115 117 118 Uut Uuq Uup 116 Uuh Uus Uuo (284) (289) (288) 68 69 70 132.905 7 13 14 19 39.098 5 24.305 18 Classas a guide, Color color Using this Metal code your periodic table to Non-Metal show the three classes. Start Metalloid by highlighting the “zig-zag.” 87 88 Fr Ra (223) (226) Lr (262) 178.49 180.95 183.84 104 105 106 107 108 109 110 111 Rf Db Sg Bh Hs Mt Ds Rg (266) (264) (269) (269) (272) (261) Lanthanides Actinides (262) 57 58 186.207 59 60 Nd La Ce Pr 138.906 140.116 140.908 144.24 (268) 61 62 Pm Sm (145) 150.36 196.967 63 Eu 151.964 (285) 64 Gd 157.25 65 Tb 158.925 66 Dy 162.50 67 (209) (292) (210) (222) Er Tm 164.930 167.26 168.934 173.04 Ho Yb 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No 232.038 231.036 238.029 (257) (258) (259) (227) (237) (244) (243) (247) (247) (251) (252) Metals Location • Found on the left of the zigzag line/staircase on the periodic table (exception Hydrogen) Chemical Properties • Have few electrons in their outer energy level, thus lose electrons easily Physical Properties • ductile, good conductors, malleable, shiny, most are solid @ room temperature 79 Au 196.967 11 Na 22.990 Image taken from: http://chemistry.about.com/od/periodictableelements/ig/E lement-Photo-Gallery.--98/Sodium.htm What metal is not a solid @ room temperature? Atoms with Few Electrons in their Outer Energy Level Notice: only 1 electron in outer level - + - + + - ++ + + ++ + + ++ + - Notice: only 2 electrons in outer level - - Be 22.990 - - 9.012 Na - + 4 11 - - - Non-Metals Location • Most found to the right of the zigzag line/staircase on the periodic table Chemical Properties • Most have almost full outer energy levels, thus they tend to gain electrons; some have completely full outer level Physical Properties • not ductile or malleable, not shiny, poor conductors, most are solid, but some are gas at room temperature 17 Cl 35.453 Image taken from: http://nobel.scas.bcit.ca/resource/ptable/cl.htm 16 S 32.066 Image taken from: https://www.dmr.nd.gov/ndgs/rockandmineral/sulfur.asp Atoms with Full or Almost Full Outer Energy Level 8 - O - 15.999 - ++ + + + + + + - - - - Notice: 2 electrons in outer level – FULL - + + - 2 - He - 4.003 - Notice: 6 electrons in outer level – almost full +++ + + + ++ + - 9 F 18.998 - - Notice: 7 electrons in outer level – almost full Metalloids Location • Border the zigzag line/staircase on the periodic table Chemical Properties • Most atoms have ½ (≈) complete set of electrons in outer level Physical Properties • have properties of both metals and nonmetals 14 Si 28.086 Image taken from: http://library.thinkquest.org/C0113863/bios.shtml 5 B 10.811 Image taken from: http://library.thinkquest.org/C0113863/bios.shtml Atoms with ½ (≈) Complete Outer Energy Level Notice: only 4 electrons in outer level 5 B - - 10.811 ++ + + + - - - - Notice: only 3 electrons in outer level - + +++ + + ++ + + + + ++ - - - - 14 Si - 28.086 - - Important Features of the Periodic Table: Period (Row) • each horizontal row of elements on the periodic table 1 1 18 1 H 2 13 14 15 16 17 1.008 2 3 4 5 6 7 8 9 10 Li Be B C N O F Ne 6.941 9.012 11 12 Na Mg 4 5 6 7 8 9 10 11 12 14.007 15.999 18.998 13 14 15 16 17 18 Al Si P S Cl Ar 26.982 28.086 30.974 32.066 35.453 39.948 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 40.078 37 38 Rb Sr 87.62 44.956 47.87 50.942 51.996 54.938 39 40 41 42 43 Y Zr Nb Mo 92.906 95.94 Tc 88.906 91.224 (98) 55.845 44 Ru 101.07 58.933 58.69 63.546 65.39 69.723 72.61 74.922 78.96 79.904 83.80 45 46 47 48 49 50 51 52 53 54 Rh Pd Ag Cd In Sn Sb Te I Xe 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 102.906 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba Lu Ta 137.327 174.967 Hf W Re Os Ir Pt Au Hg 200.59 Tl 204.383 Pb 207.2 Bi 208.980 Po At Rn 103 112 Uub 113 114 115 117 118 Uut Uuq Uup 116 Uuh Uus Uuo (284) (289) (288) 132.905 7 3 20.180 12.001 K 85.468 6 24.305 10.811 19 39.098 5 4.003 3 22.990 4 2 He 87 88 Fr Ra (223) (226) Lr (262) 178.49 180.95 183.84 190.23 192.217 195.078 104 105 106 107 108 109 110 111 Rf Db Sg Bh Hs Mt Ds Rg (266) (264) (269) (269) (272) (261) Lanthanides Actinides (262) 186.207 (268) 196.967 (285) (209) (292) (210) (222) 57 58 59 60 61 62 63 64 65 66 67 68 69 70 La Ce Pr Nd Sm Dy Er 158.925 164.930 167.26 168.934 Yb 151.964 162.50 Ho 140.908 157.25 Tb 140.116 150.36 Gd 138.906 (145) Eu Tm 144.24 Pm 173.04 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No 232.038 231.036 238.029 (257) (258) (259) (227) (237) (244) (243) (247) (247) (251) (252) FROM LEFT TO RIGHT OR RIGHT TO LEFT How many periods (rows) are on the Periodic Table Of Elements? Period (Row) Properties • Seven periods on a periodic table (numbered from the top down) • Atomic numbers and atomic masses increase as you move from the left to the right in a period • All atoms of the elements in the same period have the same number of orbitals/levels • All atoms of the elements in a specific period have that respective number of orbitals/levels – Example • Period 1 = 1 orbital • Period 2 = 2 orbitals • Period 3 = 3 orbitals • Etc… Examples of Period (Row) elements having the same number of orbitals/levels in their atoms - - - In what period (row) do you think these atoms reside? - + +++ ++ + + - - - + ++ + - - - - - - In what period (row) do you think these atoms reside? - - - - - - +++ + ++ + + ++ + ++ + + +++ ++ + ++ ++ - - - - - - - - - - - Important Features of the Periodic Table: Group (Family) •each column of elements on the periodic table 1 1 1 H 2 1.008 2 3 4 3 4 Li Be 6.941 9.012 17 2 He 4.003 5 6 7 8 9 10 B C N O F Ne 10.811 20.180 12.001 14.007 15.999 18.998 13 14 15 16 17 18 Al Si P S Cl Ar 12 Mg 22.990 24.305 26.982 28.086 30.974 32.066 35.453 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 40.078 37 38 Rb Sr 87.62 3 44.956 4 47.87 5 50.942 6 51.996 7 54.938 39 40 41 42 43 Y Zr Nb Mo 92.906 95.94 Tc 88.906 91.224 (98) 8 55.845 44 Ru 101.07 9 58.933 10 58.69 11 12 63.546 65.39 69.723 72.61 74.922 78.96 79.904 39.948 83.80 45 46 47 48 49 50 51 52 53 54 Rh Pd Ag Cd In Sn Sb Te I Xe 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 102.906 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba Lu Ta 137.327 174.967 Hf W Re Os Ir Pt Au Hg 200.59 Tl 204.383 Pb 207.2 Bi 208.980 Po At Rn 103 112 Uub 113 114 115 117 118 Uut Uuq Uup 116 Uuh Uus Uuo (284) (289) (288) 132.905 7 15 16 11 85.468 6 13 14 Na 39.098 5 18 How many groups (families) are on the Periodic Table Of Elements? 87 88 Fr Ra (223) (226) Lr (262) 178.49 180.95 183.84 190.23 192.217 195.078 104 105 106 107 108 109 110 111 Rf Db Sg Bh Hs Mt Ds Rg (266) (264) (269) (269) (272) (261) Lanthanides Actinides (262) 186.207 (268) 196.967 (285) (209) (292) (210) (222) 57 58 59 60 61 62 63 64 65 66 67 68 69 70 La Ce Pr Nd Sm Dy Er 158.925 164.930 167.26 168.934 Yb 151.964 162.50 Ho 140.908 157.25 Tb 140.116 150.36 Gd 138.906 (145) Eu Tm 144.24 Pm 173.04 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No 232.038 231.036 238.029 (257) (258) (259) (227) (237) (244) (243) (247) (247) (251) (252) FROM TOP TO BOTTOM OR BOTTOM TO THE TOP Group (Family) Properties • Eighteen groups on the periodic table (numbered from left to right) • Atomic numbers and atomic masses increase as you move from the top down in a group (family) • Atoms of elements in the same group have the same number of electrons in the outer orbitals/levels of their atoms (known as valence electrons) – Exceptions: • Transition elements (3-12) • Hydrogen (could be 1 or 17) • Helium (actually has 2 valence electrons) • Elements in groups usually have similar physical and chemical properties Examples of Group Elements with the same # of valence electrons How many electrons do each of these atoms have in their outer orbital/level? - 1 H 1.008 + 3 Li 6.941 11 Na - 22.990 - - 19 - K - 39.098 - ++ + ++ + + + ++ + - + 37 Rb - + + - 85.468 55 Cs 132.905 87 - - Fr (223) - What group (family) do these elements reside in? Group (Family) Names Alkali Alkaline MetalsEarth Noble Boron Nitrogen Carbon Oxygen Gases GroupGroupGroupGroup Halogens Metals Transition Metals 1 1 1 H 18 2 13 14 15 16 17 1.008 2 3 3 4 5 6 7 8 9 10 Be B C N O F Ne 6.941 9.012 11 12 Na Mg 6 3 4 5 6 7 8 9 10 11 12 20.180 12.001 14.007 15.999 18.998 13 14 15 16 17 18 Al Si P S Cl Ar 26.982 28.086 30.974 32.066 35.453 39.948 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Ca Sc 44.956 V Cr Mn 40.078 Ti Fe Co Ni Cu Zn Ga Ge As Se Br Kr 47.87 50.942 51.996 54.938 37 38 39 40 41 42 43 Rb Sr Y Zr Nb Mo 85.468 87.62 92.906 95.94 Tc 88.906 91.224 (98) 55.845 44 Ru 101.07 58.933 58.69 63.546 65.39 69.723 72.61 74.922 78.96 79.904 83.80 45 46 47 48 49 50 51 52 53 54 Rh Pd Ag Cd In Sn Sb Te I Xe 102.906 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba Lu Ta 137.327 174.967 Hf W Re Os 190.23 Ir 192.217 Pt 195.078 Au Hg 200.59 Tl 204.383 Pb 207.2 Bi 208.980 Po At Rn 103 112 Uub 113 114 115 117 118 Uut Uuq Uup 116 Uuh Uus Uuo (284) (289) (288) 68 69 70 132.905 7 24.305 10.811 19 39.098 5 4.003 Li 22.990 4 2 He 87 88 Fr Ra (223) (226) Lr (262) 178.49 180.95 183.84 104 105 106 107 108 109 110 111 Rf Db Sg Bh Hs Mt Ds Rg (266) (264) (269) (269) (272) (261) Lanthanides Actinides (262) 57 58 186.207 59 60 Nd La Ce Pr 138.906 140.116 140.908 144.24 (268) 61 62 Pm Sm (145) 150.36 196.967 63 Eu 151.964 (285) 64 Gd 157.25 65 Tb 158.925 66 Dy 162.50 67 (209) (292) (210) (222) Er Tm 164.930 167.26 168.934 173.04 Ho Yb 89 90 91 92 93 94 95 96 97 98 99 100 101 102 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No 232.038 231.036 238.029 (257) (258) (259) (227) (237) (244) (243) (247) (247) (251) (252) Identify the Element 1 1 18 1 H 2 13 14 15 16 17 1.008 2 3 5 6 3 4 5 6 7 8 9 Be B 14.007 O 15.999 F 9.012 12.001 N 6.941 10.811 C 18.998 11 12 13 14 15 16 17 18 Na Mg Al Si P S Cl Ar 24.305 3 4 5 6 7 8 9 10 11 12 26.982 28.086 30.974 32.066 35.453 10 Ne 20.180 39.948 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Sc 40.078 44.956 Ti 47.87 V 50.942 Cr Mn 39.098 Ca 51.996 54.938 Fe Co Ni 58.69 Cu 63.546 Zn 65.39 Ga 69.723 Ge 72.61 As 74.922 Se 78.96 Br 79.904 Kr 37 38 39 40 41 42 43 45 46 47 48 49 50 51 52 53 54 Rb Sr Y Zr Nb Mo Pd Ag Cd In Sn Sb Te I Xe 87.62 95.94 Rh 85.468 92.906 Tc 102.906 106.42 107.868 112.4 114.818 118.710 121.760 127.60 126.904 131.29 88.906 91.224 (98) 55.845 44 Ru 101.07 58.933 83.80 55 56 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ba Lu Ta 137.327 174.967 Hf W Re Os Ir Pt Au Hg 200.59 Tl 204.383 Pb 207.2 Bi 208.980 Po At Rn 103 112 Uub 113 114 115 117 118 Uut Uuq Uup 116 Uuh Uus Uuo (284) (289) (288) 132.905 7 4.003 Li 22.990 4 2 He 87 88 Fr Ra (223) (226) Lr (262) 178.49 180.95 183.84 190.23 192.217 195.078 104 105 106 107 108 109 110 111 Rf Db Sg Bh Hs Mt Ds Rg (266) (264) (269) (269) (272) (261) Lanthanides Actinides (262) 186.207 (268) 196.967 (285) (209) (292) (210) (222) 57 58 59 60 61 62 63 64 65 66 67 68 69 70 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm 140.116 140.908 164.930 167.26 168.934 Yb 138.906 144.24 Pm 173.04 89 90 91 Ac Th 232.038 (227) (145) 150.36 92 93 Pa U Np 231.036 238.029 (237) 151.964 157.25 94 95 Pu Am (244) (243) 158.925 162.50 96 97 98 99 100 101 102 Cm Bk Cf Es Fm Md No (257) (258) (259) (247) (247) (251) (252) Carbon - C Strontium Astatine - At - Sr- Rf Period 4 Group 17 2 –––Period 5 Group Period2 14 76 Rutherfordium Using the Periodic Table • The boxes that make up the periodic table contain a significant amount of information. To understand this information, it is necessary to refer to the periodic table’s key(s) 8 Atomic Number O Element Symbol Oxygen Element Name 15.999 Class Metal Non-Metal Metalloid Color Which class does Oxygen fall into? (Number of protons) (Written with a capital letter or a capital followed by a lower case if two letters ) Atomic Mass (Rounded to a whole number, equals the number of protons and neutrons) State (@ Room Temp.) Solid Liquid Gas Symbol Color What is Oxygen’s physical state of matter?